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Iron Phthalocyanine/Graphene Composites as Promising Electrocatalysts for the Oxygen Reduction Reaction

Author

Listed:
  • Jong S. Park

    (Department of Organic Material Science and Engineering, Pusan National University, Busan 46241, Korea)

  • Dong Wook Chang

    (Department of Industrial Chemistry, Pukyong National University, Busan 48513, Korea)

Abstract

Recently, the development of non-precious electrocatalysts for the oxygen reduction reaction (ORR) has become important in replacing currently employed platinum (Pt)-based catalysts. Although Pt-based catalysts exhibit satisfactory ORR performances, their high price, easy methanol/CO 2 poisoning, and poor long-term stability significantly hamper the forward movement of fuel cell technology. Among the various candidates, graphene-supported iron phthalocyanine (FePc) composites have attracted great attention because of their unique advantages, including low cost, good dimensional stability, high durability, and tunable catalytic activity. In the composite catalyst, FePc molecules are immobilized on graphene via noncovalent or covalent interactions. In addition, two-dimensional graphene substrates can improve not only the electrical conductivity of the composite, but also the dispersion of FePc molecules, triggering a significant improvement in the catalytic properties of the composite catalyst. Herein, we summarize the recent advances in FePc/graphene composite catalysts used for the ORR. Moreover, we discuss the challenges and future perspectives of this promising field.

Suggested Citation

  • Jong S. Park & Dong Wook Chang, 2020. "Iron Phthalocyanine/Graphene Composites as Promising Electrocatalysts for the Oxygen Reduction Reaction," Energies, MDPI, vol. 13(16), pages 1-17, August.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:16:p:4073-:d:395382
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    References listed on IDEAS

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    1. Rajesh Bashyam & Piotr Zelenay, 2006. "A class of non-precious metal composite catalysts for fuel cells," Nature, Nature, vol. 443(7107), pages 63-66, September.
    2. Takuro Ikeuchi & Ryota Kudo & Yu Kitazawa & Shogo Mori & Mutsumi Kimura, 2020. "3D Structural Optimization of Zinc Phthalocyanine-Based Sensitizers for Enhancement of Open-Circuit Voltage of Dye-Sensitized Solar Cells," Energies, MDPI, vol. 13(9), pages 1-8, May.
    3. Yazmín Yorely Rivera-Lugo & Kevin Isaac Pérez-Muñoz & Balter Trujillo-Navarrete & Carolina Silva-Carrillo & Edgar Alonso Reynoso-Soto & Julio Cesar Calva Yañez & Shui Wai Lin & José Roberto Flores-Her, 2020. "PtPd Hybrid Composite Catalysts as Cathodes for Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 13(2), pages 1-12, January.
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