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Solid-State NaBH 4 /Co Composite as Hydrogen Storage Material: Effect of the Pressing Pressure on Hydrogen Generation Rate

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Listed:
  • Olga V. Netskina

    (Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk 630090, Russia)

  • Elena S. Tayban

    (Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk 630090, Russia)

  • Anna M. Ozerova

    (Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk 630090, Russia)

  • Oxana V. Komova

    (Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk 630090, Russia)

  • Valentina I. Simagina

    (Laboratory of Hydrides Investigation, Boreskov Institute of Catalysis SB RAS (BIC SB RAS), Novosibirsk 630090, Russia)

Abstract

A solid-state NaBH 4 /Co composite has been employed as a hydrogen-generating material, as an alternative to sodium borohydride solutions, in the long storage of hydrogen. Hydrogen generation begins in the presence of cobalt-based catalysts, immediately after water is added to a NaBH 4 /Co composite, as a result of sodium borohydride hydrolysis. The hydrogen generation rate has been investigated as a function of the pressure used to press hydrogen-generating composites from a mechanical mixture of the hydride and cobalt chloride hexahydrate. The hydrogen generation rate was observed to increase with the increase of this pressure. Pre-reduction of the cobalt chloride, using a sodium borohydride solution, leveled this dependence with a two-fold decrease in the gas generation rate. According to TEM and XPS data, oxidation of the particles of the pre-reduced cobalt catalyst took place during preparation of the composites, and it is this oxidation that appears to be the main reason for its low activity in sodium borohydride hydrolysis.

Suggested Citation

  • Olga V. Netskina & Elena S. Tayban & Anna M. Ozerova & Oxana V. Komova & Valentina I. Simagina, 2019. "Solid-State NaBH 4 /Co Composite as Hydrogen Storage Material: Effect of the Pressing Pressure on Hydrogen Generation Rate," Energies, MDPI, vol. 12(7), pages 1-7, March.
    • Handle: RePEc:gam:jeners:v:12:y:2019:i:7:p:1184-:d:217417
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    References listed on IDEAS

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    1. Salvi, B.L. & Subramanian, K.A., 2015. "Sustainable development of road transportation sector using hydrogen energy system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1132-1155.
    2. Netskina, O.V. & Komova, O.V. & Simagina, V.I. & Odegova, G.V. & Prosvirin, I.P. & Bulavchenko, O.A., 2016. "Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts," Renewable Energy, Elsevier, vol. 99(C), pages 1073-1081.
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