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Reversible and Irreversible Potentials and an Inaccuracy in Popular Models in the Fuel Cell Literature

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  • Uday K. Chakraborty

    (Department of Mathematics and Computer Science, University of Missouri, St. Louis, MO 63121, USA)

Abstract

Modeling is an integral part of fuel cell design and development. This paper identifies a long-standing inaccuracy in the fuel cell modeling literature. Specifically, it discusses an inexact insertion, in popular models, of cell/stack current into Nernst’s equation in the derivation of output (load) voltage. The origin of the inaccuracy is traced to the nature of reversible and irreversible potentials (equilibrium and non-equilibrium states) in the cell. The significance of the inaccuracy is explained in the context of the electrochemistry and thermodynamics of the fuel cell.

Suggested Citation

  • Uday K. Chakraborty, 2018. "Reversible and Irreversible Potentials and an Inaccuracy in Popular Models in the Fuel Cell Literature," Energies, MDPI, vol. 11(7), pages 1-11, July.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:7:p:1851-:d:158102
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    References listed on IDEAS

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    Cited by:

    1. Arne L. Lazar & Swantje C. Konradt & Hermann Rottengruber, 2019. "Open-Source Dynamic Matlab/Simulink 1D Proton Exchange Membrane Fuel Cell Model," Energies, MDPI, vol. 12(18), pages 1-12, September.
    2. Hegazy Rezk & Rania M. Ghoniem & Seydali Ferahtia & Ahmed Fathy & Mohamed M. Ghoniem & Reem Alkanhel, 2022. "A Comparison of Different Renewable-Based DC Microgrid Energy Management Strategies for Commercial Buildings Applications," Sustainability, MDPI, vol. 14(24), pages 1-22, December.
    3. Maloberti, Luca & Zaccone, Raphael, 2025. "An environmentally sustainable energy management strategy for marine hybrid propulsion," Energy, Elsevier, vol. 316(C).
    4. Uday K. Chakraborty, 2019. "Proton Exchange Membrane Fuel Cell Stack Design Optimization Using an Improved Jaya Algorithm," Energies, MDPI, vol. 12(16), pages 1-26, August.

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