IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v10y2017i8p1215-d108499.html
   My bibliography  Save this article

Studies on the Effect of Nano-Sized MgO in Magnesium-Ion Conducting Gel Polymer Electrolyte for Rechargeable Magnesium Batteries

Author

Listed:
  • Na Wu

    (Key Laboratory of Inorganic Nanomaterials of Hebei Province, College of Chemistry and Material Science, Hebei Advance Thin Films Laboratory, College of Physical Science and Information Engineering, National Demonstration Center for Experimental Chemistry Education, Hebei Normal University, Shijiazhuang 050024, China)

  • Wei Wang

    (Key Laboratory of Inorganic Nanomaterials of Hebei Province, College of Chemistry and Material Science, Hebei Advance Thin Films Laboratory, College of Physical Science and Information Engineering, National Demonstration Center for Experimental Chemistry Education, Hebei Normal University, Shijiazhuang 050024, China)

  • Yu Wei

    (Key Laboratory of Inorganic Nanomaterials of Hebei Province, College of Chemistry and Material Science, Hebei Advance Thin Films Laboratory, College of Physical Science and Information Engineering, National Demonstration Center for Experimental Chemistry Education, Hebei Normal University, Shijiazhuang 050024, China)

  • Taohai Li

    (Key Lab of Environment Friendly Chemistry and Application in Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan 411105, China)

Abstract

Magnesium-ion conducting gel polymer electrolytes (GPEs) with different contents of nano-sized MgO have been prepared and investigated by various electrical and electrochemical techniques. The Mg 2+ ion conduction in GPEs was confirmed from cyclic voltammetry and impedance analysis. It was found that doping appropriate nano-sized MgO in the GPE can induce significant improvements in both the electrochemical and the mechanical properties of GPEs. The composite GPE with 7% MgO shows a high ionic conductivity of 4.6 × 10 −3 S/cm with electrochemical stability up to 4.7 V versus Mg 2+ /Mg at room temperature. Furthermore, it is free-standing and flexible with high tensile strength (9.7 ± 0.1 MPa) and elongation at break (91.7 ± 0.2%), further ensuring their potential applications as GPEs for rechargeable Mg batteries.

Suggested Citation

  • Na Wu & Wei Wang & Yu Wei & Taohai Li, 2017. "Studies on the Effect of Nano-Sized MgO in Magnesium-Ion Conducting Gel Polymer Electrolyte for Rechargeable Magnesium Batteries," Energies, MDPI, vol. 10(8), pages 1-10, August.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:8:p:1215-:d:108499
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/10/8/1215/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/10/8/1215/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Mauro Pasta & Colin D. Wessells & Robert A. Huggins & Yi Cui, 2012. "A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage," Nature Communications, Nature, vol. 3(1), pages 1-7, January.
    2. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xiao Zhu & Tuan K. A. Hoang & Pu Chen, 2017. "Novel Carbon Materials in the Cathode Formulation for High Rate Rechargeable Hybrid Aqueous Batteries," Energies, MDPI, vol. 10(11), pages 1-17, November.
    2. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    4. Ren, Danhong & Li, Xuan & Zhao, Xinhao & Liu, Baocheng & Yang, Zhengchun & He, Jie & Li, Tong & Pan, Peng, 2022. "Development and evaluation of Zn2+ ions hybrid supercapacitor based on ZnxMnO2-CNTs cathode," Applied Energy, Elsevier, vol. 324(C).
    5. Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
    6. Ma, Mina & Wang, Yu & Duan, Qiangling & Wu, Tangqin & Sun, Jinhua & Wang, Qingsong, 2018. "Fault detection of the connection of lithium-ion power batteries in series for electric vehicles based on statistical analysis," Energy, Elsevier, vol. 164(C), pages 745-756.
    7. Li, Yong & Song, Jian & Yang, Jie, 2015. "Graphene models and nano-scale characterization technologies for fuel cell vehicle electrodes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 66-77.
    8. Guo-Rui Zhu & Qin Zhang & Qing-Song Liu & Qi-Yao Bai & Yi-Zhou Quan & You Gao & Gang Wu & Yu-Zhong Wang, 2023. "Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Navaratnarajah Kuganathan & Alexander Chroneos, 2020. "Lithium Storage in Nanoporous Complex Oxide 12CaO•7Al 2 O 3 (C12A7)," Energies, MDPI, vol. 13(7), pages 1-10, March.
    10. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    11. Suresh, C. & Awasthi, Abhishek & Kumar, Binit & Im, Seong-kyun & Jeon, Yongseok, 2025. "Advances in battery thermal management for electric vehicles: A comprehensive review of hybrid PCM-metal foam and immersion cooling technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 208(C).
    12. Zhu, Xiaoqing & Wang, Zhenpo & Wang, Yituo & Wang, Hsin & Wang, Cong & Tong, Lei & Yi, Mi, 2019. "Overcharge investigation of large format lithium-ion pouch cells with Li(Ni0.6Co0.2Mn0.2)O2 cathode for electric vehicles: Thermal runaway features and safety management method," Energy, Elsevier, vol. 169(C), pages 868-880.
    13. Wang, Wei & Wu, Yufeng, 2017. "An overview of recycling and treatment of spent LiFePO4 batteries in China," Resources, Conservation & Recycling, Elsevier, vol. 127(C), pages 233-243.
    14. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    15. Pinelopi Angelopoulou & Spyros Kassavetis & Joan Papavasiliou & Dimitris Karfaridis & Grzegorz Słowik & Panos Patsalas & George Avgouropoulos, 2021. "Enhanced Performance of LiAl 0.1 Mn 1.9 O 4 Cathode for Li-Ion Battery via TiN Coating," Energies, MDPI, vol. 14(4), pages 1-14, February.
    16. Zhang, Tao & Li, Hong-Zhou & Xie, Bai-Chen, 2022. "Have renewables and market-oriented reforms constrained the technical efficiency improvement of China's electric grid utilities?," Energy Economics, Elsevier, vol. 114(C).
    17. Zhixin Xu & Xiyue Zhang & Jun Yang & Xuzixu Cui & Yanna Nuli & Jiulin Wang, 2024. "High-voltage and intrinsically safe electrolytes for Li metal batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    18. Xinxin Wang & Jingjing Chen & Dajian Wang & Zhiyong Mao, 2021. "Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    19. Dong Hou & Zhengrui Xu & Zhijie Yang & Chunguang Kuai & Zhijia Du & Cheng-Jun Sun & Yang Ren & Jue Liu & Xianghui Xiao & Feng Lin, 2022. "Effect of the grain arrangements on the thermal stability of polycrystalline nickel-rich lithium-based battery cathodes," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    20. Beata Kurc & Xymena Gross & Ewelina Rudnicka & Łukasz Rymaniak, 2024. "Thermal Studies of Lithium-Ion Cells: Ensuring Safe and Efficient Energy Storage," Energies, MDPI, vol. 17(9), pages 1-17, April.

    More about this item

    Keywords

    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:10:y:2017:i:8:p:1215-:d:108499. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.