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Development and evaluation of Zn2+ ions hybrid supercapacitor based on ZnxMnO2-CNTs cathode

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  • Ren, Danhong
  • Li, Xuan
  • Zhao, Xinhao
  • Liu, Baocheng
  • Yang, Zhengchun
  • He, Jie
  • Li, Tong
  • Pan, Peng

Abstract

A hybrid supercapacitor exhibits excellent electrochemical properties due to its simultaneously high power and energy densities. However, the capacity under long hours will be greatly reduced. Therefore, this study develops a new type of Zn2+ ions hybrid supercapacitors (Zn-HSCs). The cathode of this device requires not only an ultra-high stability tunnel structure, but also high electrical conductivity. Thus, on the basis of the study of ZnxMnO2, an appropriate amount of carbon nanotubes (CNTs) was doped and a new material (i.e., ZnxMnO2-CNTs) is formed. Zn-HSCs are based on ZnxMnO2-CNTs as the cathode, activated carbon (ACC) as the anode, and an aqueous liquid electrolyte, which significantly improves the cycling performance of the device. In addition, the proposed ZnxMnO2-CNTs has a high electrical conductivity suitable for the development of rechargeable ZnxMnO2-CNTs //ACC Zn-HSCs devices.

Suggested Citation

  • Ren, Danhong & Li, Xuan & Zhao, Xinhao & Liu, Baocheng & Yang, Zhengchun & He, Jie & Li, Tong & Pan, Peng, 2022. "Development and evaluation of Zn2+ ions hybrid supercapacitor based on ZnxMnO2-CNTs cathode," Applied Energy, Elsevier, vol. 324(C).
    • Handle: RePEc:eee:appene:v:324:y:2022:i:c:s0306261922010200
    DOI: 10.1016/j.apenergy.2022.119730
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    References listed on IDEAS

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    1. Wentian Gu & Gleb Yushin, 2014. "Review of nanostructured carbon materials for electrochemical capacitor applications: advantages and limitations of activated carbon, carbide-derived carbon, zeolite-templated carbon, carbon aerogels,," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 3(5), pages 424-473, September.
    2. José Luis Sampietro & Vicenç Puig & Ramon Costa-Castelló, 2019. "Optimal Sizing of Storage Elements for a Vehicle Based on Fuel Cells, Supercapacitors, and Batteries," Energies, MDPI, vol. 12(5), pages 1-27, March.
    3. Mauro Pasta & Colin D. Wessells & Robert A. Huggins & Yi Cui, 2012. "A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage," Nature Communications, Nature, vol. 3(1), pages 1-7, January.
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