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Effect of Carbon Additives on the Electrochemical Performance of Li 4 Ti 5 O 12 /C Anodes

Author

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  • Irina Stenina

    (Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospekt 31, 119991 Moscow, Russia)

  • Ruslan Shaydullin

    (Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospekt 31, 119991 Moscow, Russia
    Department of Chemistry, Lomonosov Moscow State University, 119991 Moscow, Russia)

  • Tatiana Kulova

    (Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Leninsky prospekt 31-4, 119071 Moscow, Russia)

  • Anna Kuz’mina

    (Frumkin Institute of Physical Chemistry and Electrochemistry of the Russian Academy of Sciences, Leninsky prospekt 31-4, 119071 Moscow, Russia)

  • Nataliya Tabachkova

    (Prokhorov General Physics Institute of the Russian Academy of Sciences, 38, Vavilov Str., 119991 Moscow, Russia
    Department of Materials Science of Semiconductors and Dielectrics, National University of Science and Technology (MISIS), 119049 Moscow, Russia)

  • Andrey Yaroslavtsev

    (Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences, Leninsky prospekt 31, 119991 Moscow, Russia)

Abstract

The Li 4 Ti 5 O 12 /C composites were prepared by a hydrothermal method with in situ carbon addition. The influence of the morphology and content of various carbon materials (conductive carbon black, mesoporous carbon G_157M, and carbon replicas) on the electrochemical performance of the Li 4 Ti 5 O 12 /C composites was investigated. The obtained composites were characterized using X-ray diffraction, scanning electron microsopy, high-resolution transmission electron microscopy, thermogravimetric analysis, Raman spectroscopy, and N 2 sorption-desorption isotherms. Morphology of the Li 4 Ti 5 O 12 /C composites depends on the carbon matrix used, while both morphology and the amount of carbon material have a great impact on the rate capability and cycling stability of the obtained composites. At low current densities, the Li 4 Ti 5 O 12 /C composite with 5 wt.% G_157M exhibits the highest discharge capacity, while at high charge-discharge rates, the Li 4 Ti 5 O 12 /carbon black composites show the best electrochemical performance. Thus, at ~0.1C, 5C, and 18C rates, the discharge capacities of the obtained Li 4 Ti 5 O 12 /C composites are 175, 120, and 70 mAh/g for G_157M, 165, 126, and 78 mAh/g for carbon replicas, and 173, 128, and 93 mAh/g for carbon black. After 100 cycles, their capacity retention is no less than 95%, suggesting their promising application perspective.

Suggested Citation

  • Irina Stenina & Ruslan Shaydullin & Tatiana Kulova & Anna Kuz’mina & Nataliya Tabachkova & Andrey Yaroslavtsev, 2020. "Effect of Carbon Additives on the Electrochemical Performance of Li 4 Ti 5 O 12 /C Anodes," Energies, MDPI, vol. 13(15), pages 1-15, August.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:15:p:3941-:d:393182
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    References listed on IDEAS

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    1. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
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