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Advances in nuclear magnetic resonance (NMR) techniques for the investigation of clathrate hydrates

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  • Yang, Mingjun
  • Chong, Zheng Rong
  • Zheng, Jianan
  • Song, Yongchen
  • Linga, Praveen

Abstract

Over the years, clathrate hydrates have been investigated for its potential as an energy resource and other industrial applications. Nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI) are two powerful NMR technologies for both molecular level and microscopic measurement, which have been applied in gas hydrate research to provide fundamental and useful information. 1H and 13C NMR spectroscopy are the most commonly applied method to study cage occupancies of guest species and crystal structures. MRI technique, on the other hand, provides microscopic insights towards the gas hydrate formation and dissociation in porous media and the study of CH4/CO2 hydrate replacement. We also reviewed the state of the art application of NMR based technology in research on the gas-liquid multiphase flow and temperature mapping within porous media. Potential improvements in NMR technology to improve the fundamental understanding towards gas hydrates is also discussed in this review article.

Suggested Citation

  • Yang, Mingjun & Chong, Zheng Rong & Zheng, Jianan & Song, Yongchen & Linga, Praveen, 2017. "Advances in nuclear magnetic resonance (NMR) techniques for the investigation of clathrate hydrates," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 1346-1360.
  • Handle: RePEc:eee:rensus:v:74:y:2017:i:c:p:1346-1360
    DOI: 10.1016/j.rser.2016.11.161
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    Cited by:

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    2. Chi, Yuan & Xu, Yongsheng & Zhao, Changzhong & Zhang, Yi & Song, Yongchen, 2022. "In-situ measurement of interfacial tension: Further insights into effect of interfacial tension on the kinetics of CO2 hydrate formation," Energy, Elsevier, vol. 239(PB).
    3. Yuan Chi & Changzhong Zhao & Junchen Lv & Jiafei Zhao & Yi Zhang, 2019. "Thermodynamics and Kinetics of CO 2 /CH 4 Adsorption on Shale from China: Measurements and Modeling," Energies, MDPI, vol. 12(6), pages 1-13, March.
    4. Ma, Shihui & Zheng, Jia-nan & Tang, Dawei & Lv, Xin & Li, Qingping & Yang, Mingjun, 2019. "Experimental investigation on the decomposition characteristics of natural gas hydrates in South China Sea sediments by a micro-differential scanning calorimeter," Applied Energy, Elsevier, vol. 254(C).
    5. Mok, Junghoon & Choi, Wonjung & Seo, Yongwon, 2021. "The dual-functional roles of N2 gas for the exploitation of natural gas hydrates: An inhibitor for dissociation and an external guest for replacement," Energy, Elsevier, vol. 232(C).
    6. Zheng, Junjie & Loganathan, Niranjan Kumar & Zhao, Jianzhong & Linga, Praveen, 2019. "Clathrate hydrate formation of CO2/CH4 mixture at room temperature: Application to direct transport of CO2-containing natural gas," Applied Energy, Elsevier, vol. 249(C), pages 190-203.
    7. Chong, Zheng Rong & Yin, Zhenyuan & Tan, Jun Hao Clifton & Linga, Praveen, 2017. "Experimental investigations on energy recovery from water-saturated hydrate bearing sediments via depressurization approach," Applied Energy, Elsevier, vol. 204(C), pages 1513-1525.
    8. Chong, Zheng Rong & Zhao, Jianzhong & Chan, Jian Hua Rudi & Yin, Zhenyuan & Linga, Praveen, 2018. "Effect of horizontal wellbore on the production behavior from marine hydrate bearing sediment," Applied Energy, Elsevier, vol. 214(C), pages 117-130.

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