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Pyrolysis behavior and kinetic analysis of pine needles in CO2 atmospheres

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  • Cui, Zeguang
  • Zhang, Pan
  • Zhu, Haochen
  • Zhou, Yuqian
  • Wang, Lemeng
  • Anniwaer, Aisikaer
  • Zhao, Kun
  • Fu, Dong
  • Guan, Guoqing

Abstract

Current research on biomass pyrolysis in a CO2 atmosphere remains constrained, and there is still a lack of thorough investigation of its complex pyrolysis mechanism, which hinders further advancements in its utilization and development. This study investigates the thermogravimetric analysis, kinetics analysis, and pyrolysis product analysis of pine needles (PNs) pyrolysis under N2 and CO2 atmospheres. Thermogravimetric analysis identified three distinct stages in the PNs pyrolysis process: dehydration, thermal cracking, and carbon decomposition. The application of kinetic methods, including Coats-Redfern, Friedman, and Flynn-Wall-Ozawa, revealed that PNs exhibited a lower activation energy for pyrolysis in a CO2 atmosphere with the D6 kinetic model being the optimal fit. Additionally, pyrolysis product analysis revealed that the presence of CO2 promoted the cracking of volatile organic compounds (VOCs) released during the pyrolysis process and facilitated gas-phase reactions with VOCs to ultimately enhance syngas yield.

Suggested Citation

  • Cui, Zeguang & Zhang, Pan & Zhu, Haochen & Zhou, Yuqian & Wang, Lemeng & Anniwaer, Aisikaer & Zhao, Kun & Fu, Dong & Guan, Guoqing, 2025. "Pyrolysis behavior and kinetic analysis of pine needles in CO2 atmospheres," Renewable Energy, Elsevier, vol. 250(C).
    • Handle: RePEc:eee:renene:v:250:y:2025:i:c:s0960148125009589
    DOI: 10.1016/j.renene.2025.123296
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    References listed on IDEAS

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    1. Bahareh Vafakish & Amin Babaei-Ghazvini & Mahmood Ebadian & Bishnu Acharya, 2023. "Pyrolysis and Combustion Behavior of Flax Straw as Biomass: Evaluation of Kinetic, Thermodynamic Parameters, and Qualitative Analysis of Degradation Products," Energies, MDPI, vol. 16(19), pages 1-20, October.
    2. Hou, Yanmei & Gao, Qi & He, Yuyu & Ni, Liangmeng & Ren, Hao & Su, Mengfu & Rong, Shaowen & Liu, Zhijia, 2023. "Pyrolysis characteristics and gaseous products of bamboo shoot shells under N2 and CO2 atmospheres," Renewable Energy, Elsevier, vol. 215(C).
    3. Hong, Yu & Xie, Chengrui & Chen, Wanru & Luo, Xiang & Shi, Kaiqi & Wu, Tao, 2020. "Kinetic study of the pyrolysis of microalgae under nitrogen and CO2 atmosphere," Renewable Energy, Elsevier, vol. 145(C), pages 2159-2168.
    4. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    5. Raza, Mohsin & Abu-Jdayil, Basim & Al-Marzouqi, Ali H. & Inayat, Abrar, 2022. "Kinetic and thermodynamic analyses of date palm surface fibers pyrolysis using Coats-Redfern method," Renewable Energy, Elsevier, vol. 183(C), pages 67-77.
    6. Emmanuel Galiwango & Ali H. Al-Marzuoqi & Abbas A. Khaleel & Mahdi M. Abu-Omar, 2020. "Investigation of Non-Isothermal Kinetics and Thermodynamic Parameters for the Pyrolysis of Different Date Palm Parts," Energies, MDPI, vol. 13(24), pages 1-19, December.
    7. Panwar, N.L. & Kaushik, S.C. & Kothari, Surendra, 2011. "Role of renewable energy sources in environmental protection: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(3), pages 1513-1524, April.
    8. Wu, Xiaomei & Mao, Yuanhao & Fan, Huifeng & Sultan, Sayd & Yu, Yunsong & Zhang, Zaoxiao, 2023. "Investigation on the performance of EDA-based blended solvents for electrochemically mediated CO2 capture," Applied Energy, Elsevier, vol. 349(C).
    9. Lee, Taewoo & Jung, Sungyup & Kim, Ki-Hyun & Kwon, Eilhann E., 2021. "Catalytic pyrolysis of pine bark over Ni/SiO2 in a CO2 atmosphere," Energy, Elsevier, vol. 220(C).
    10. Debra J. Davidson, 2019. "Exnovating for a renewable energy transition," Nature Energy, Nature, vol. 4(4), pages 254-256, April.
    11. Xiao, Ruirui & Yang, Wei & Cong, Xingshun & Dong, Kai & Xu, Jie & Wang, Dengfeng & Yang, Xin, 2020. "Thermogravimetric analysis and reaction kinetics of lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 201(C).
    12. Wang, Yu & Ge, Zhiwei & Shang, Fei & Zhou, Chenchen & Guo, Shenghui & Ren, Changyifan, 2023. "Kinetic analysis of CO2 gasification of corn straw," Renewable Energy, Elsevier, vol. 203(C), pages 219-227.
    Full references (including those not matched with items on IDEAS)

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