IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v202y2023icp1046-1053.html
   My bibliography  Save this article

Guanidine catalysts for biodiesel production: Activity, process modelling and optimization

Author

Listed:
  • Racar, Marko
  • Šoljić Jerbić, Ivana
  • Glasovac, Zoran
  • Jukić, Ante

Abstract

Since conventional catalysts for biodiesel production have problems with saponification, ten guanidine derivatives were investigated in this study for their catalytic activity in the production of biodiesel from rapeseed oil and methanol. The most active catalyst was selected for process optimization. The influence of process parameters (reaction time, mass percent of catalyst and alcohol to oil ratio) on the transesterification process was evaluated using a design of experiments following a 33 factorial Box-Behnken design of experiments in conjunction with response surface methodology. An accurate quadratic model was developed (p-value < 0.001, F-value 65.90, R2 0.990) and used for process optimization. The resulting optimal conditions were 1.8 wt% of catalyst, methanol to oil ratio of 6.2:1, and a reaction time of 80 min with a predicted yield of 99.2 mol%. The optimal conditions were verified on a larger scale (1 kg), obtaining a yield of 96.5 mol%, confirming the accuracy of the quadratic model. In addition, the obtained biodiesel was characterized with respect to the main physicochemical and application properties.

Suggested Citation

  • Racar, Marko & Šoljić Jerbić, Ivana & Glasovac, Zoran & Jukić, Ante, 2023. "Guanidine catalysts for biodiesel production: Activity, process modelling and optimization," Renewable Energy, Elsevier, vol. 202(C), pages 1046-1053.
    • Handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1046-1053
    DOI: 10.1016/j.renene.2022.11.044
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122016858
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.11.044?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Racar, Marko & Faraguna, Fabio & Glasovac, Zoran & Jukić, Ante, 2020. "Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2374-2379.
    2. Hájek, Martin & Vávra, Aleš & Skopal, František & Straková, Anna & Douda, Miroslav, 2020. "The description of catalyst behaviour during transesterification of rapeseed oil – Formation of micellar emulsion," Renewable Energy, Elsevier, vol. 159(C), pages 938-943.
    3. Xie, Wenlei & Xiong, Yunfei & Wang, Hongyan, 2021. "Fe3O4-poly(AGE-DVB-GMA) composites immobilized with guanidine as a magnetically recyclable catalyst for enhanced biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 758-768.
    4. Karavalakis, Georgios & Anastopoulos, Georgios & Stournas, Stamos, 2011. "Tetramethylguanidine as an efficient catalyst for transesterification of waste frying oils," Applied Energy, Elsevier, vol. 88(11), pages 3645-3650.
    5. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    6. Zhang, Pingbo & Liu, Yanlei & Fan, Mingming & Jiang, Pingping, 2016. "Catalytic performance of a novel amphiphilic alkaline ionic liquid for biodiesel production: Influence of basicity and conductivity," Renewable Energy, Elsevier, vol. 86(C), pages 99-105.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Racar, Marko & Faraguna, Fabio & Glasovac, Zoran & Jukić, Ante, 2020. "Experimental modeling and optimization of biodiesel production from waste cooking oil and ethanol using N,N′,N″-tris(3-dimethylaminopropyl)-guanidine as catalyst," Renewable Energy, Elsevier, vol. 146(C), pages 2374-2379.
    2. Xie, Wenlei & Li, Jiangbo, 2023. "Magnetic solid catalysts for sustainable and cleaner biodiesel production: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
    3. Wang, Yongqiang & Zhao, Dan & Chen, Guanyi & Liu, Shejiang & Ji, Na & Ding, Hui & Fu, Jianfeng, 2019. "Preparation of phosphotungstic acid based poly(ionic liquid) and its application to esterification of palmitic acid," Renewable Energy, Elsevier, vol. 133(C), pages 317-324.
    4. Panneerselvam, N. & Murugesan, A. & Vijayakumar, C. & Kumaravel, A. & Subramaniam, D. & Avinash, A., 2015. "Effects of injection timing on bio-diesel fuelled engine characteristics—An overview," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 17-31.
    5. Feng, Weiliang & Tie, Xinlong & Duan, Xiaoling & Yan, Su & Fang, Si & Sun, Peiyong & Gan, Lin & Wang, Tielin, 2023. "Covalent immobilization of phosphotungstic acid and amino acid on metal-organic frameworks with different structures: Acid-base bifunctional heterogeneous catalyst for the production of biodiesel from," Renewable Energy, Elsevier, vol. 210(C), pages 26-39.
    6. Roschat, Wuttichai & Siritanon, Theeranun & Yoosuk, Boonyawan & Sudyoadsuk, Taweesak & Promarak, Vinich, 2017. "Rubber seed oil as potential non-edible feedstock for biodiesel production using heterogeneous catalyst in Thailand," Renewable Energy, Elsevier, vol. 101(C), pages 937-944.
    7. Xie, Wenlei & Yang, Xinli & Fan, Mingliang, 2015. "Novel solid base catalyst for biodiesel production: Mesoporous SBA-15 silica immobilized with 1,3-dicyclohexyl-2-octylguanidine," Renewable Energy, Elsevier, vol. 80(C), pages 230-237.
    8. Hosseini, Shokoufe & Moradi, G.R. & Bahrami, Kiumars, 2019. "Synthesis of a novel stabilized basic ionic liquid through immobilization on boehmite nanoparticles: A robust nanocatalyst for biodiesel production from soybean oil," Renewable Energy, Elsevier, vol. 138(C), pages 70-78.
    9. Wang, Quan & Wenlei Xie, & Guo, Lihong, 2022. "Molybdenum and zirconium oxides supported on KIT-6 silica: A recyclable composite catalyst for one–pot biodiesel production from simulated low-quality oils," Renewable Energy, Elsevier, vol. 187(C), pages 907-922.
    10. Deeba, Farha & Kumar, Bijender & Arora, Neha & Singh, Sauraj & Kumar, Anuj & Han, Sung Soo & Negi, Yuvraj S., 2020. "Novel bio-based solid acid catalyst derived from waste yeast residue for biodiesel production," Renewable Energy, Elsevier, vol. 159(C), pages 127-139.
    11. Li, Lu & Zou, Changjun & Zhou, Lu & Lin, Lang, 2017. "Cucurbituril-protected Cs2.5H0.5PW12O40 for optimized biodiesel production from waste cooking oil," Renewable Energy, Elsevier, vol. 107(C), pages 14-22.
    12. Ananya Satapathy & Kankana Saikia & Samuel Lalthazuala Rokhum, 2023. "Biodiesel Production Using a Banana Peel Extract-Mediated Highly Basic Heterogeneous Nanocatalyst," Sustainability, MDPI, vol. 15(14), pages 1-21, July.
    13. Gholami, Ali & Pourfayaz, Fathollah & Hajinezhad, Ahmad & Mohadesi, Majid, 2019. "Biodiesel production from Norouzak (Salvia leriifolia) oil using choline hydroxide catalyst in a microchannel reactor," Renewable Energy, Elsevier, vol. 136(C), pages 993-1001.
    14. Gotovuša, Mia & Medić, Mihovil & Faraguna, Fabio & Šibalić, Matea & Konjević, Lucija & Vuković, Jelena Parlov & Racar, Marko, 2022. "Fatty acids propyl esters: Synthesis optimization and application properties of their blends with diesel and 1-propanol," Renewable Energy, Elsevier, vol. 185(C), pages 655-664.
    15. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    16. Yin, Xiulian & Ma, Haile & You, Qinghong & Wang, Zhenbin & Chang, Jinke, 2012. "Comparison of four different enhancing methods for preparing biodiesel through transesterification of sunflower oil," Applied Energy, Elsevier, vol. 91(1), pages 320-325.
    17. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    18. Foteinis, Spyros & Chatzisymeon, Efthalia & Litinas, Alexandros & Tsoutsos, Theocharis, 2020. "Used-cooking-oil biodiesel: Life cycle assessment and comparison with first- and third-generation biofuel," Renewable Energy, Elsevier, vol. 153(C), pages 588-600.
    19. Xie, Wenlei & Han, Yuxiang & Wang, Hongyan, 2018. "Magnetic Fe3O4/MCM-41 composite-supported sodium silicate as heterogeneous catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 125(C), pages 675-681.
    20. Tran, Dang-Thuan & Chang, Jo-Shu & Lee, Duu-Jong, 2017. "Recent insights into continuous-flow biodiesel production via catalytic and non-catalytic transesterification processes," Applied Energy, Elsevier, vol. 185(P1), pages 376-409.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:202:y:2023:i:c:p:1046-1053. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.