IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v201y2022ip1p832-840.html
   My bibliography  Save this article

Hierarchically porous carbon derived from delignified biomass for high sulfur-loading room-temperature sodium-sulfur batteries

Author

Listed:
  • Tang, Kejian
  • Peng, Xiangqi
  • Chen, Shuijiao
  • Song, Fei
  • Liu, Zhichao
  • Hu, Jian
  • Xie, Xiuqiang
  • Wu, Zhenjun

Abstract

The commercial applications of room-temperature sodium-sulfur battery still suffers from low sulfur utilization and poor reaction kinetics. Here, we develop a novel carbon material with hierarchical pores from camellia oleifera seed cake as the host of sulfur by introducing a delignification process followed by KOH activation. The large specific surface area (1362 m2 g−1) and well-developed porosity produced by the two-step method make it possible to realize high sulfur content (61.9 wt%). By the physical confinement of micropores, the formation of Na2Sx (4 ≤ x ≤ 8) is effectively suppressed to avoid the side reactions. The mesopores and macropores optimize the electrolyte accessibility. The sulfur-loaded carbon cathode delivers a reversible capacity of 702 mAh g−1 after 100 cycles at 0.1 C (1 C = 1675 mAh g−1). Even at 1 C, a reversible capacity of 404 mAh g−1 has been achieved after 300 cycles. This work demonstrates a sustainable cathode with a high sulfur content for the practical application of room-temperature Na–S batteries.

Suggested Citation

  • Tang, Kejian & Peng, Xiangqi & Chen, Shuijiao & Song, Fei & Liu, Zhichao & Hu, Jian & Xie, Xiuqiang & Wu, Zhenjun, 2022. "Hierarchically porous carbon derived from delignified biomass for high sulfur-loading room-temperature sodium-sulfur batteries," Renewable Energy, Elsevier, vol. 201(P1), pages 832-840.
    • Handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:832-840
    DOI: 10.1016/j.renene.2022.10.102
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122016044
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.10.102?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Shuya Wei & Shaomao Xu & Akanksha Agrawral & Snehashis Choudhury & Yingying Lu & Zhengyuan Tu & Lin Ma & Lynden A. Archer, 2016. "A stable room-temperature sodium–sulfur battery," Nature Communications, Nature, vol. 7(1), pages 1-10, September.
    2. Quan Pang & Xiao Liang & Chun Yuen Kwok & Linda F. Nazar, 2016. "Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes," Nature Energy, Nature, vol. 1(9), pages 1-11, September.
    3. Thomas F. Fuller, 2016. "Batteries: Bigger and better," Nature Energy, Nature, vol. 1(2), pages 1-2, February.
    4. Jianwei Song & Chaoji Chen & Shuze Zhu & Mingwei Zhu & Jiaqi Dai & Upamanyu Ray & Yiju Li & Yudi Kuang & Yongfeng Li & Nelson Quispe & Yonggang Yao & Amy Gong & Ulrich H. Leiste & Hugh A. Bruck & J. Y, 2018. "Processing bulk natural wood into a high-performance structural material," Nature, Nature, vol. 554(7691), pages 224-228, February.
    5. Yang Xu & Chenglin Zhang & Min Zhou & Qun Fu & Chengxi Zhao & Minghong Wu & Yong Lei, 2018. "Highly nitrogen doped carbon nanofibers with superior rate capability and cyclability for potassium ion batteries," Nature Communications, Nature, vol. 9(1), pages 1-11, December.
    6. Muhammad Kashif Aslam & Ieuan D. Seymour & Naman Katyal & Sha Li & Tingting Yang & Shu-juan Bao & Graeme Henkelman & Maowen Xu, 2020. "Metal chalcogenide hollow polar bipyramid prisms as efficient sulfur hosts for Na-S batteries," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    7. Yongming Sun & Nian Liu & Yi Cui, 2016. "Promises and challenges of nanomaterials for lithium-based rechargeable batteries," Nature Energy, Nature, vol. 1(7), pages 1-12, July.
    8. Yuruo Qi & Qing-Jie Li & Yuanke Wu & Shu-juan Bao & Changming Li & Yuming Chen & Guoxiu Wang & Maowen Xu, 2021. "A Fe3N/carbon composite electrocatalyst for effective polysulfides regulation in room-temperature Na-S batteries," Nature Communications, Nature, vol. 12(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Liu, Ying & Lee, Dong Jun & Ahn, Hyo-Jun & Nam, Sang Yong & Cho, Kwon-Koo & Ahn, Jou-Hyeon, 2023. "Waste coffee grounds-derived carbon: Nanoarchitectured pore-structure regulation for sustainable room-temperature sodium–sulfur batteries," Renewable Energy, Elsevier, vol. 212(C), pages 865-874.
    2. Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    3. Shuo Wang & Jiamin Fu & Yunsheng Liu & Ramanuja Srinivasan Saravanan & Jing Luo & Sixu Deng & Tsun-Kong Sham & Xueliang Sun & Yifei Mo, 2023. "Design principles for sodium superionic conductors," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    4. Siyuan Fang & Xingyi Lyu & Tian Tong & Aniqa Ibnat Lim & Tao Li & Jiming Bao & Yun Hang Hu, 2023. "Turning dead leaves into an active multifunctional material as evaporator, photocatalyst, and bioplastic," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    5. Guoyu Qian & Yiwei Li & Haibiao Chen & Lin Xie & Tongchao Liu & Ni Yang & Yongli Song & Cong Lin & Junfang Cheng & Naotoshi Nakashima & Meng Zhang & Zikun Li & Wenguang Zhao & Xiangjie Yang & Hai Lin , 2023. "Revealing the aging process of solid electrolyte interphase on SiOx anode," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    6. Lee, Seung Jun & Theerthagiri, Jayaraman & Nithyadharseni, Palaniyandy & Arunachalam, Prabhakarn & Balaji, Dhandapani & Madan Kumar, Arumugam & Madhavan, Jagannathan & Mittal, Vikas & Choi, Myong Yong, 2021. "Heteroatom-doped graphene-based materials for sustainable energy applications: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    7. Li, Yong & Yang, Jie & Song, Jian, 2017. "Efficient storage mechanisms and heterogeneous structures for building better next-generation lithium rechargeable batteries," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1503-1512.
    8. Hongbo Ding & Jue Wang & Jiang Zhou & Chengxin Wang & Bingan Lu, 2023. "Building electrode skins for ultra-stable potassium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    9. Christian Prehal & Jean-Marc Mentlen & Sara Drvarič Talian & Alen Vizintin & Robert Dominko & Heinz Amenitsch & Lionel Porcar & Stefan A. Freunberger & Vanessa Wood, 2022. "On the nanoscale structural evolution of solid discharge products in lithium-sulfur batteries using operando scattering," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    10. Shuangyan Lang & Seung-Ho Yu & Xinran Feng & Mihail R. Krumov & Héctor D. Abruña, 2022. "Understanding the lithium–sulfur battery redox reactions via operando confocal Raman microscopy," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    11. Siheng Wang & Le Yu & Shanshan Wang & Lei Zhang & Lu Chen & Xu Xu & Zhanqian Song & He Liu & Chaoji Chen, 2022. "Strong, tough, ionic conductive, and freezing-tolerant all-natural hydrogel enabled by cellulose-bentonite coordination interactions," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    12. Xun Sun & Yue Qiu & Bo Jiang & Zhaoyu Chen & Chenghao Zhao & Hao Zhou & Li Yang & Lishuang Fan & Yu Zhang & Naiqing Zhang, 2023. "Isolated Fe-Co heteronuclear diatomic sites as efficient bifunctional catalysts for high-performance lithium-sulfur batteries," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    13. Mohanad Yaseen Abdulwahid & Isaac Galobardes & Hassan Radoine, 2021. "Understanding the Use of Timber in Semi-Arid Regions: Kurdistan Region of Iraq, a Case Study," Sustainability, MDPI, vol. 13(21), pages 1-14, October.
    14. Wanqing Song & Xinyi Yang & Tao Zhang & Zechuan Huang & Haozhi Wang & Jie Sun & Yunhua Xu & Jia Ding & Wenbin Hu, 2024. "Optimizing potassium polysulfides for high performance potassium-sulfur batteries," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    15. Beims, Ramon Filipe & Arredondo, Rosa & Sosa Carrero, Dennise Johanna & Yuan, Zhongshun & Li, Hongwei & Shui, Hengfu & Zhang, Yongsheng & Leitch, Mathew & Xu, Chunbao Charles, 2022. "Functionalized wood as bio-based advanced materials: Properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 157(C).
    16. Gong, Xuzhong & Zhang, Tong & Zhang, Junqiang & Wang, Zhi & Liu, Junhao & Cao, Jianwei & Wang, Chuan, 2022. "Recycling and utilization of calcium carbide slag - current status and new opportunities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    17. Fu Liu & Wenqing Lu & Jiaqiang Huang & Vanessa Pimenta & Steven Boles & Rezan Demir-Cakan & Jean-Marie Tarascon, 2023. "Detangling electrolyte chemical dynamics in lithium sulfur batteries by operando monitoring with optical resonance combs," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    19. Daniel Akinyele & Juri Belikov & Yoash Levron, 2017. "Battery Storage Technologies for Electrical Applications: Impact in Stand-Alone Photovoltaic Systems," Energies, MDPI, vol. 10(11), pages 1-39, November.
    20. Elizabeth A. Moore & Callie W. Babbitt & Brian Tomaszewski & Anna Christina Tyler, 2020. "Spatial perspectives enhance modeling of nanomaterial risks," Journal of Industrial Ecology, Yale University, vol. 24(4), pages 855-870, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:201:y:2022:i:p1:p:832-840. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.