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A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries

Author

Listed:
  • Chao Ye

    (The University of Adelaide)

  • Huanyu Jin

    (The University of Adelaide)

  • Jieqiong Shan

    (The University of Adelaide)

  • Yan Jiao

    (The University of Adelaide)

  • Huan Li

    (The University of Adelaide)

  • Qinfen Gu

    (Australian Synchrotron (ANSTO))

  • Kenneth Davey

    (The University of Adelaide)

  • Haihui Wang

    (Tsinghua University)

  • Shi-Zhang Qiao

    (The University of Adelaide)

Abstract

Metal sulfides electrodeposition in sulfur cathodes mitigates the shuttle effect of polysulfides to achieve high Coulombic efficiency in secondary metal-sulfur batteries. However, fundamental understanding of metal sulfides electrodeposition and kinetics mechanism remains limited. Here using room-temperature sodium-sulfur cells as a model system, we report a Mo5N6 cathode material that enables efficient Na2S electrodeposition to achieve an initial discharge capacity of 512 mAh g−1 at a specific current of 1 675 mA g−1, and a final discharge capacity of 186 mAh g−1 after 10,000 cycles. Combined analyses from synchrotron-based spectroscopic characterizations, electrochemical kinetics measurements and density functional theory computations confirm that the high d-band position results in a low Na2S2 dissociation free energy for Mo5N6. This promotes Na2S electrodeposition, and thereby favours long-term cell cycling performance.

Suggested Citation

  • Chao Ye & Huanyu Jin & Jieqiong Shan & Yan Jiao & Huan Li & Qinfen Gu & Kenneth Davey & Haihui Wang & Shi-Zhang Qiao, 2021. "A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-27551-7
    DOI: 10.1038/s41467-021-27551-7
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    References listed on IDEAS

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