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Hydrogen storage in TiVCrMo and TiZrNbHf multiprinciple-element alloys and their catalytic effect upon hydrogen storage in Mg

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  • Cermak, Jiri
  • Kral, Lubomir
  • Roupcova, Pavla

Abstract

Hydrogen storage performance of nearly equimolar alloys TiVCrMo and TiZrNbH (HEA's) was studied. The alloys were prepared by repeated arc-melting in the form of single-phase alloys and as their multi-phase analogues prepared either by high-energy ball milling (HEBM) of the arc-melted ingots or by HEBM of pure elements. Besides these four-component experimental materials, also their mixtures with Mg were investigated that were prepared by HEBM with Mg (composition in both cases was Mg – 10 wt % HEA). Hydrogen sorption experiments were carried out in temperature interval between 240 °C and 380 °C under hydrogen-gas pressure up to 50 bars. Kinetic curves, temperature-programmed desorption spectra and concentration-pressure isotherms were measured. It was found that activation energy of hydrogen desorption, |Ea|, for materials with Mg was significantly decreased compared to pure Mg. Hydride formation enthalpy, ΔH, observed for all the materials under study was about the same as that for pure MgH2. Hydrogen absorption capacity in pure four-component HEA's was negligible; only hydrogen surface adsorption was detected. The capacity of mixtures of HEA's with Mg was between 3.5 and 6 wt % H2.

Suggested Citation

  • Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2022. "Hydrogen storage in TiVCrMo and TiZrNbHf multiprinciple-element alloys and their catalytic effect upon hydrogen storage in Mg," Renewable Energy, Elsevier, vol. 188(C), pages 411-424.
    • Handle: RePEc:eee:renene:v:188:y:2022:i:c:p:411-424
    DOI: 10.1016/j.renene.2022.02.021
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    References listed on IDEAS

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    1. Li, Jigang & Guo, Yanru & Jiang, Xiaojing & Li, Shuan & Li, Xingguo, 2020. "Hydrogen storage performances, kinetics and microstructure of Ti1.02Cr1.0Fe0.7-xMn0.3Alx alloy by Al substituting for Fe," Renewable Energy, Elsevier, vol. 153(C), pages 1140-1154.
    2. Yong, Hui & Guo, Shihai & Yuan, Zeming & Qi, Yan & Zhao, Dongliang & Zhang, Yanghuan, 2020. "Catalytic effect of in situ formed Mg2Ni and REHx (RE: Ce and Y) on thermodynamics and kinetics of Mg-RE-Ni hydrogen storage alloy," Renewable Energy, Elsevier, vol. 157(C), pages 828-839.
    3. Zhang, Tiebang & Wu, Tiandong & Xue, Xiangyi & Hu, Rui & Kou, Hongchao & Li, Jinshan, 2017. "Hydrogen storage performance of a pseudo-binary Zr-V-Ni Laves phase alloy against gaseous impurities," Renewable Energy, Elsevier, vol. 103(C), pages 786-793.
    4. Renato Belli Strozi & Daniel Rodrigo Leiva & Guilherme Zepon & Walter José Botta & Jacques Huot, 2021. "Effects of the Chromium Content in (TiVNb) 100−x Cr x Body-Centered Cubic High Entropy Alloys Designed for Hydrogen Storage Applications," Energies, MDPI, vol. 14(11), pages 1-11, May.
    5. Matsunaga, T. & Buchter, F. & Miwa, K. & Towata, S. & Orimo, S. & Züttel, A., 2008. "Magnesium borohydride: A new hydrogen storage material," Renewable Energy, Elsevier, vol. 33(2), pages 193-196.
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    1. Cermak, Jiri & Kral, Lubomir & Roupcova, Pavla, 2022. "A new light-element multi-principal-elements alloy AlMg2TiZn and its potential for hydrogen storage," Renewable Energy, Elsevier, vol. 198(C), pages 1186-1192.

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