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Modeling and simulation of a multi-bed industrial reactor for renewable diesel hydroprocessing

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  • Tirado, Alexis
  • Alvarez-Majmutov, Anton
  • Ancheyta, Jorge

Abstract

The complexity of designing and optimizing vegetable oil hydrotreating reactors lies in describing multiple phenomena, including heat and mass transfer, hydrogen consumption, pressure drop, and a complicated network of highly exothermic reactions. This study intends to analyze the behavior of a vegetable oil hydroprocessing unit in a commercial environment via modeling and simulation techniques. In order to describe the three-phase (gas-liquid-solid) system in a detailed manner, a commercial-scale reactor model having multiple catalyst beds and inter-bed quench gas injections was constructed accounting for the heat and mass transfer between phases, the dynamic response of the system, the variation in gas phase velocity, and intraparticle effects. Based on dynamic reactor simulations, quench gas injection strategies were proposed to control the reactor temperature profile and yield of the desired products. Simulation results showed that the selection of a feed inlet temperature plays a major role in reactor overheating and quench injections must start as soon as the reactant stream reaches the inter-bed quench zone to stabilize reactor temperature more rapidly during start-up. In addition, the lengths of the catalyst beds need to be adjusted such that the heat released by chemical reactions is properly distributed along the reactor. The results overall provide useful information for the design and optimization of commercial-scale catalyst bed configurations for hydrotreating renewable feedstock. In particular, it is highlighted that by means of an appropriate gas quenching configuration, reactor temperature can be adequately controlled, allowing higher yields of green diesel.

Suggested Citation

  • Tirado, Alexis & Alvarez-Majmutov, Anton & Ancheyta, Jorge, 2022. "Modeling and simulation of a multi-bed industrial reactor for renewable diesel hydroprocessing," Renewable Energy, Elsevier, vol. 186(C), pages 173-182.
    • Handle: RePEc:eee:renene:v:186:y:2022:i:c:p:173-182
    DOI: 10.1016/j.renene.2021.12.143
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    References listed on IDEAS

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    1. Savvas L. Douvartzides & Nikolaos D. Charisiou & Kyriakos N. Papageridis & Maria A. Goula, 2019. "Green Diesel: Biomass Feedstocks, Production Technologies, Catalytic Research, Fuel Properties and Performance in Compression Ignition Internal Combustion Engines," Energies, MDPI, vol. 12(5), pages 1-41, February.
    2. Tirado, Alexis & Ancheyta, Jorge, 2020. "Modeling of a bench-scale fixed-bed reactor for catalytic hydrotreating of vegetable oil," Renewable Energy, Elsevier, vol. 148(C), pages 790-797.
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    1. Wu, Wei & Supankanok, Rasa & Chandra-Ambhorn, Walairat & Taipabu, Muhammad Ikhsan, 2023. "Novel CO2-negative design of palm oil-based polygeneration systems," Renewable Energy, Elsevier, vol. 203(C), pages 622-633.

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