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Thermogravimetric kinetics and pyrolytic tri-state products analysis towards insights into understanding the pyrolysis mechanism of Spirulina platensis with calcium oxide

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  • Hu, Mian
  • Zhang, Haiyang
  • Ye, Zhiheng
  • Ma, Jiajia
  • Chen, Zhihua
  • Wang, Junliang
  • Wang, Cheng
  • Pan, Zhiyan

Abstract

Thermogravimetric kinetics and pyrolytic tri-state products analyses towards insights into understanding the pyrolysis mechanism of Spirulina platensis with calcium oxide were investigated using a thermogravimetric analyzer and a fixed bed reactor, respectively. The pyrolysis kinetics were studied by Friedman method and results indicated that the f(α)=(1-α)4 with A0 = 1.99E+10s−1 and f(α)=−1/ln(1−α) with A0 = 8.33E+11s−1 were suitable for Spirulina platensis and Spirulina platensis + CaO (stage II) pyrolysis, respectively. According to pyrolysis behaviors and kinetics analyzed, the potential reaction behaviors of CaO during the pyrolysis of Spirulina platensis were explored. Spirulina platensis pyrolytic tri-state products analyzed indicated that, when CaO as additive, the gas yield markedly increased with more H2, CO content and less CO2 content and the bio-oil yield significantly decreased. Moreover, the contents of aromatic compounds, aliphatic compounds, phenols and ketons obviously increased in bio-oil with the appreciably decreased in the contents of esters, N-containing compounds, O-containing compounds and acids. Based on the evolutionary mechanism of CaO and pyrolytic tri-state products, the pyrolysis mechanism of Spirulina platensis with calcium oxide was proposed.

Suggested Citation

  • Hu, Mian & Zhang, Haiyang & Ye, Zhiheng & Ma, Jiajia & Chen, Zhihua & Wang, Junliang & Wang, Cheng & Pan, Zhiyan, 2022. "Thermogravimetric kinetics and pyrolytic tri-state products analysis towards insights into understanding the pyrolysis mechanism of Spirulina platensis with calcium oxide," Renewable Energy, Elsevier, vol. 184(C), pages 498-509.
    • Handle: RePEc:eee:renene:v:184:y:2022:i:c:p:498-509
    DOI: 10.1016/j.renene.2021.11.085
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    3. Chen, Chunxiang & Wei, Yixue & Wei, Guangsheng & Qiu, Song & Yang, Gaixiu & Bi, Yingxin, 2023. "Microwave Co-pyrolysis of mulberry branches and Chlorella vulgaris under carbon material additives," Energy, Elsevier, vol. 284(C).

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