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Valorizing of weeds algae through the solar assisted pyrolysis: Effects of dependable parameters on yields and characterization of products

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  • Rahman, M.A.

Abstract

In this study, a novel technique is applied to recover the pyrolysis products (bio-oil, char, and non-condensable gas) from algal biomass (E. compressa) by utilizing solar energy. To observe the parametric effect on product distribution, the temperature was varied from 250 to 600 °C, heating rate of 20–100 °C/min, particles feed size of <0.5–2.5 mm and sweeping gas flow rate of 3–15 liter per minute (lpm). The maximum solar bio-oil yield of 38.12 wt% was obtained at 400 °C, 9 lpm, <0.5 mm and 20 °C/min. The non-condensable gas evolution rate increase with a rise in temperature except for CO2. The bio-oils were characterized and their economic feasibility was evaluated by proximate, ultimate and GC-MS analysis whereas char product was characterized by proximate and FTIR. The gaseous products were analyzed by micro-gas chromatography (GC). The products yield and their characteristics highly dependent on temperature variation. The products possess high energy contents which are a potential alternative fuel. The energy upgrading factor, and solar to chemical conversion efficiency was also calculated.

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  • Rahman, M.A., 2020. "Valorizing of weeds algae through the solar assisted pyrolysis: Effects of dependable parameters on yields and characterization of products," Renewable Energy, Elsevier, vol. 147(P1), pages 937-946.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:937-946
    DOI: 10.1016/j.renene.2019.09.046
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    References listed on IDEAS

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    1. Ly, Hoang Vu & Kim, Seung-Soo & Woo, Hee Chul & Choi, Jae Hyung & Suh, Dong Jin & Kim, Jinsoo, 2015. "Fast pyrolysis of macroalga Saccharina japonica in a bubbling fluidized-bed reactor for bio-oil production," Energy, Elsevier, vol. 93(P2), pages 1436-1446.
    2. Rahman, M.A., 2018. "Valorization of harmful algae E. compressa for biodiesel production in presence of chicken waste derived catalyst," Renewable Energy, Elsevier, vol. 129(PA), pages 132-140.
    3. Li, Rui & Zeng, Kuo & Soria, José & Mazza, Germán & Gauthier, Daniel & Rodriguez, Rosa & Flamant, Gilles, 2016. "Product distribution from solar pyrolysis of agricultural and forestry biomass residues," Renewable Energy, Elsevier, vol. 89(C), pages 27-35.
    4. Nzihou, Ange & Flamant, Gilles & Stanmore, Brian, 2012. "Synthetic fuels from biomass using concentrated solar energy – A review," Energy, Elsevier, vol. 42(1), pages 121-131.
    5. Hu, Zhiquan & Zheng, Yang & Yan, Feng & Xiao, Bo & Liu, Shiming, 2013. "Bio-oil production through pyrolysis of blue-green algae blooms (BGAB): Product distribution and bio-oil characterization," Energy, Elsevier, vol. 52(C), pages 119-125.
    6. Zeng, Kuo & Gauthier, Daniel & Li, Rui & Flamant, Gilles, 2015. "Solar pyrolysis of beech wood: Effects of pyrolysis parameters on the product distribution and gas product composition," Energy, Elsevier, vol. 93(P2), pages 1648-1657.
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    1. Hamed, A.S.A. & Yusof, N.I.F.M. & Yahya, M.S. & Cardozo, E. & Munajat, N.F., 2023. "Concentrated solar pyrolysis for oil palm biomass: An exploratory review within the Malaysian context," Renewable and Sustainable Energy Reviews, Elsevier, vol. 188(C).

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