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Utilization of low-concentration coal-bed gas to generate power using a core-shell catalyst-modified solid oxide fuel cell

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  • Yuan, Xiuqi
  • Chen, Huili
  • Tian, Wenjuan
  • Shi, Jing
  • Zhou, Wei
  • Cheng, Fangqin
  • Li, Si-Dian
  • Shao, Zongping

Abstract

This paper reports a way to utilize low-concentration coal-bed gas(LC-CBG) to generate power using SOFC technology. Ni–BaO–CeO2@SiO2 (@NBC) porous nanoparticles with a core-shell structure were synthesized and applied as a protective layer on an anode consisting of Ni–yttria stabilized zirconia (Ni–YSZ). Catalytic activity of @NBC relative to methane partial oxidation was evaluated. Electrochemical performance and durability of the @NBC-modified cells (@NBC//Ni–YSZ) were tested fed with simulated LC-CBG (30% CH4–70% air). A conventional cell without a protective layer (Ni–YSZ) and a bare NBC-modified cell (NBC//Ni–YSZ) were used for a comparison. The pre- and post-mortem microstructures of cells were analyzed. Influence of porosity of the anode layer on polarization resistance was also investigated. The loading mode of catalysts was discussed as well. Using simulated LC-CBG as a fuel, peak power density of @NBC//Ni–YSZ showed 50% increase at 800 °C comparing with Ni–YSZ at the same conditions. The aging test in galvano-static mode demonstrated good durability of @NBC//Ni–YSZ lasting for over 160 h when exposed to LC-CBG. For comparison, NBC//Ni–YSZ showed rapid voltage drop after 60 h. Voltage of the Ni–YSZ dropped after 10 h. No coking was observed on the @NBC//Ni–YSZ anode surface after the durability tests.

Suggested Citation

  • Yuan, Xiuqi & Chen, Huili & Tian, Wenjuan & Shi, Jing & Zhou, Wei & Cheng, Fangqin & Li, Si-Dian & Shao, Zongping, 2020. "Utilization of low-concentration coal-bed gas to generate power using a core-shell catalyst-modified solid oxide fuel cell," Renewable Energy, Elsevier, vol. 147(P1), pages 602-609.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:602-609
    DOI: 10.1016/j.renene.2019.09.023
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    References listed on IDEAS

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    1. Jiao, Yong & Tian, Wenjuan & Chen, Huili & Shi, Huangang & Yang, Binbin & Li, Chao & Shao, Zongping & Zhu, Zhenping & Li, Si-Dian, 2015. "In situ catalyzed Boudouard reaction of coal char for solid oxide-based carbon fuel cells with improved performance," Applied Energy, Elsevier, vol. 141(C), pages 200-208.
    2. Qu, Jifa & Wang, Wei & Chen, Yubo & Deng, Xiang & Shao, Zongping, 2016. "Stable direct-methane solid oxide fuel cells with calcium-oxide-modified nickel-based anodes operating at reduced temperatures," Applied Energy, Elsevier, vol. 164(C), pages 563-571.
    3. Chen, Huili & Wang, Fen & Wang, Wei & Chen, Daifen & Li, Si-Dian & Shao, Zongping, 2016. "H2S poisoning effect and ways to improve sulfur tolerance of nickel cermet anodes operating on carbonaceous fuels," Applied Energy, Elsevier, vol. 179(C), pages 765-777.
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    Cited by:

    1. Yang, Yang & Li, Tian & Feng, Peizhong & Wang, Xinxin & Wang, Shaorong & Ling, Yihan & Shao, Zongping, 2022. "Highly efficient conversion of oxygen-bearing low concentration coal-bed methane into power via solid oxide fuel cell integrated with an activated catalyst-modified anode microchannel," Applied Energy, Elsevier, vol. 328(C).
    2. Mohamad Fairus Rabuni & Tao Li & Mohd Hafiz Dzarfan Othman & Faidzul Hakim Adnan & Kang Li, 2023. "Progress in Solid Oxide Fuel Cells with Hydrocarbon Fuels," Energies, MDPI, vol. 16(17), pages 1-36, September.
    3. Wang, Junkai & Zhou, Jun & Yang, Jiaming & Zong, Zheng & Fu, Lei & Lian, Zhongjie & Zhang, Xinchang & Wang, Xuan & Chen, Chengxiang & Ma, Wanli & Wu, Kai, 2020. "Nanoscale architecture of (La0.6Sr1.4)0.95Mn0.9B0.1O4 (BCo, Ni, Cu) Ruddlesden–Popper oxides as efficient and durable catalysts for symmetrical solid oxide fuel cells," Renewable Energy, Elsevier, vol. 157(C), pages 840-850.

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