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Thermodynamic frameworks of adsorption kinetics modeling: Dynamic water uptakes on silica gel for adsorption cooling applications

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  • Sun, Baichuan
  • Chakraborty, Anutosh

Abstract

This paper presents the thermodynamic frameworks to describe the dynamic uptakes of water vapor on various sizes and layers of silica gels for adsorption cooling applications. The proposed kinetic formulation is developed from the rigor of the partition function of each adsorptive sites and the kinetics theory of adsorbate molecules with the analogy of Langmuir kinetics. The simulation results calculated from the proposed formulation are compared with experimentally measured kinetics data of various single and multi layers configuration of silica gels–water systems. An interesting and useful finding has been established that the proposed model is thermodynamically consistent from the Henry's region to the saturated pressure, and also is connected with the surface structural heterogeneity factors of adsorbents.

Suggested Citation

  • Sun, Baichuan & Chakraborty, Anutosh, 2015. "Thermodynamic frameworks of adsorption kinetics modeling: Dynamic water uptakes on silica gel for adsorption cooling applications," Energy, Elsevier, vol. 84(C), pages 296-302.
    • Handle: RePEc:eee:energy:v:84:y:2015:i:c:p:296-302
    DOI: 10.1016/j.energy.2015.02.101
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    References listed on IDEAS

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    1. Aristov, Yuriy I. & Glaznev, Ivan S. & Girnik, Ilya S., 2012. "Optimization of adsorption dynamics in adsorptive chillers: Loose grains configuration," Energy, Elsevier, vol. 46(1), pages 484-492.
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    5. João M. S. Dias & Vítor A. F. Costa, 2021. "Modeling and Analysis of a Coated Tube Adsorber for Adsorption Heat Pumps," Energies, MDPI, vol. 14(21), pages 1-19, October.
    6. Fan, Wu & Chakraborty, Anutosh & Kayal, Sibnath, 2016. "Adsorption cooling cycles: Insights into carbon dioxide adsorption on activated carbons," Energy, Elsevier, vol. 102(C), pages 491-501.
    7. Teng, W.S. & Leong, K.C. & Chakraborty, A., 2016. "Revisiting adsorption cooling cycle from mathematical modelling to system development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 315-332.
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    10. Asfahan, Hafiz M. & Sultan, Muhammad & Miyazaki, Takahiko & Saha, Bidyut B. & Askalany, Ahmed A. & Shahzad, Muhammad W. & Worek, William, 2022. "Recent development in adsorption desalination: A state of the art review," Applied Energy, Elsevier, vol. 328(C).

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