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Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell

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  • Yin, Dezhong
  • Ma, Li
  • Liu, Jinjie
  • Zhang, Qiuyu

Abstract

MePCMs (microencapsulated phase change materials) with covalently bonded SiO2/polymer hybrid as shell were fabricated via Pickering emulsion polymerization stabilized solely by organically-modified SiO2 particles. Morphology and core–shell structure of these microcapsules were observed by scanning electron microscopy (SEM). Thermal properties of microencapsulated 1-dodecanol were determined using DSC (differential scanning calorimetry) and TGA (thermal gravimetric analysis). The results indicate that mass ratio of St (styrene)/DVB (divinylbenzene)/dodecanol has great effect on the morphology, inner structure, microencapsulation efficiency and durability of resultant MePCMs. When ratio of St/DVB/dodecanol was 5/1/12, dodecanol content of as much as 62.8% is obtained and the utility efficiency of dodecanol reaches 94.2%. The prepared MePCMs present good durability and thermal reliability. 2.2% of core material leached away the microcapsule after suspended in water for 10 days and 5.8% of core material leached after 2000 accelerated thermal cycling. Our study demonstrated that Pickering emulsion polymerization is a simple and robust method for the preparation of MePCMs with polymer–inorganic hybrids as shell.

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  • Yin, Dezhong & Ma, Li & Liu, Jinjie & Zhang, Qiuyu, 2014. "Pickering emulsion: A novel template for microencapsulated phase change materials with polymer–silica hybrid shell," Energy, Elsevier, vol. 64(C), pages 575-581.
    • Handle: RePEc:eee:energy:v:64:y:2014:i:c:p:575-581
    DOI: 10.1016/j.energy.2013.10.004
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