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Thermodynamic analysis of algal biocrude production

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  • Beal, C.M.
  • Hebner, R.E.
  • Webber, M.E.

Abstract

Although algal biofuels possess great potential, profitable production is quite challenging. Much of this challenge is rooted in the thermodynamic constraints associated with producing fuels with high energy, low entropy, and high exergy from dispersed materials. In this study, a preliminary thermodynamic analysis is presented that calculates the energy, entropy, and exergy of the intermediate products for algal biocrude production. These values are also used in an initial attempt to characterize the thermodynamic efficiency of that system. The production pathway is simplified by assuming ideal solutions throughout. Results for the energy and exergy efficiencies, and the first-order energy and exergy return on investment, of the system are given.

Suggested Citation

  • Beal, C.M. & Hebner, R.E. & Webber, M.E., 2012. "Thermodynamic analysis of algal biocrude production," Energy, Elsevier, vol. 44(1), pages 925-943.
    • Handle: RePEc:eee:energy:v:44:y:2012:i:1:p:925-943
    DOI: 10.1016/j.energy.2012.05.003
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    2. Kai Whiting & Luis Gabriel Carmona & Angeles Carrasco & Tânia Sousa, 2017. "Exergy Replacement Cost of Fossil Fuels: Closing the Carbon Cycle," Energies, MDPI, vol. 10(7), pages 1-21, July.
    3. Moreno-Sader, K. & Meramo-Hurtado, S.I. & González-Delgado, A.D., 2019. "Computer-aided environmental and exergy analysis as decision-making tools for selecting bio-oil feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 42-57.
    4. Diaz-Mendez, S.E. & Sierra-Grajeda, J.M.T. & Hernandez-Guerrero, A. & Rodriguez-Lelis, J.M., 2013. "Entropy generation as an environmental impact indicator and a sample application to freshwater ecosystems eutrophication," Energy, Elsevier, vol. 61(C), pages 234-239.
    5. Hu, Yan & Hall, Charles A.S. & Wang, Jianliang & Feng, Lianyong & Poisson, Alexandre, 2013. "Energy Return on Investment (EROI) of China's conventional fossil fuels: Historical and future trends," Energy, Elsevier, vol. 54(C), pages 352-364.

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