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Formulation and phase change mechanism of Capric acid/Octadecanol binary composite phase change materials

Author

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  • Zuo, Peixian
  • Liu, Zhong
  • Zhang, Hua
  • Dai, Dasong
  • Fu, Ziyan
  • Corker, Jorge
  • Fan, Mizi

Abstract

Fatty acids and fatty alcohols have the advantages of high latent heat of phase change, good thermal stability, no corrosion, no supercooling and phase separation. They can be used as phase change energy storage materials for passive temperature control. However, their popularization and application are limited because of their high phase transition temperature and narrow phase transition range. This study develops a novel binary composite phase change materials (PCMs) of Capric acid (CA) and Octadecanol (OD) by a melt blending method. The theoretical calculation and hot melt-step cooling were carried out to generate an optimal molar ratio, followed by DSC thermal characterization. ATR-FTIR and XRD were performed to determine the phase transformation and chemical and structure changes. The results showed the binary CA-OD binary composite PCMs has a high latent heat of fusion, a melting temperature Tm = 26.48 °C and △H = 181.06 J/g at optimal mass ratio of 85.15:14.86 (CA:OD), which is higher than the theoretically predicted latent heat of phase transition, indicating a good synergistic effect beneficial to energy storage. Solid CA exists in the form of dimer and –OH in solid OD exists in form of association, and intermolecular hydrogen bonds weakens in liquid. There are hydrogen bonds in the CA-OD binary composite PCMs, and the molecular structure changes before and after the phase transformation were similar to that of a single component CA or OD. The crystal structures of the two compounds also change and the latent heat of phase transformation is improved. Finally, through TG and high and low temperature cycle test, CA-OD binary PCMs demonstrates good thermal stability and practicability in the field of building energy conservation.

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  • Zuo, Peixian & Liu, Zhong & Zhang, Hua & Dai, Dasong & Fu, Ziyan & Corker, Jorge & Fan, Mizi, 2023. "Formulation and phase change mechanism of Capric acid/Octadecanol binary composite phase change materials," Energy, Elsevier, vol. 270(C).
  • Handle: RePEc:eee:energy:v:270:y:2023:i:c:s0360544223003377
    DOI: 10.1016/j.energy.2023.126943
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    References listed on IDEAS

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    1. Duquesne, M. & Mailhé, C. & Ruiz-Onofre, K. & Achchaq, F., 2019. "Biosourced organic materials for latent heat storage: An economic and eco-friendly alternative," Energy, Elsevier, vol. 188(C).
    2. Feng, Guohui & Huang, Kailiang & Xie, Hailun & Li, Huixing & Liu, Xin & Liu, Shibo & Cao, Chihong, 2016. "DSC test error of phase change material (PCM) and its influence on the simulation of the PCM floor," Renewable Energy, Elsevier, vol. 87(P3), pages 1148-1153.
    3. Lizana, Jesús & Chacartegui, Ricardo & Barrios-Padura, Angela & Ortiz, Carlos, 2018. "Advanced low-carbon energy measures based on thermal energy storage in buildings: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3705-3749.
    4. Tian, Yuanyuan & Liu, Anbang & Wang, Junli & Zhou, Yajie & Bao, Chengpeng & Xie, Huaqing & Wu, Zihua & Wang, Yuanyuan, 2021. "Optimized output electricity of thermoelectric generators by matching phase change material and thermoelectric material for intermittent heat sources," Energy, Elsevier, vol. 233(C).
    5. Song, Shaokun & Zhao, Tingting & Qiu, Feng & Zhu, Wanting & Chen, Taorui & Guo, Yi & Zhang, Yang & Wang, Yuqi & Feng, Rui & Liu, Yang & Xiong, Chuanxi & Zhou, Jian & Dong, Lijie, 2019. "Natural microtubule encapsulated phase change material with high thermal energy storage capacity," Energy, Elsevier, vol. 172(C), pages 1144-1150.
    6. El-Raheim, D. Abd & Mohamed, A. & Abou-Ziyan, H. & Fatouh, M., 2023. "The essential properties governing the appropriate selection of phase change materials integrated into heavy structure buildings," Energy, Elsevier, vol. 266(C).
    7. Ikutegbe, Charles A. & Farid, Mohammed M., 2020. "Application of phase change material foam composites in the built environment: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    8. Liu, Changyu & Sun, Yongxiang & Li, Dong & Bian, Ji & Wu, Yangyang & Li, Pengfei & Sun, Yong, 2022. "Influence of enclosure filled with phase change material on photo-thermal regulation of direct absorption anaerobic reactor: Numerical and experimental study," Applied Energy, Elsevier, vol. 313(C).
    9. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    10. Ke, Wei & Ji, Jie & Zhang, Chengyan & Xie, Hao & Tang, Yayun & Wang, Chuyao, 2023. "Effects of the PCM layer position on the comprehensive performance of a built-middle PV-Trombe wall system for building application in the heating season," Energy, Elsevier, vol. 267(C).
    11. Zhang, H.L. & Baeyens, J. & Degrève, J. & Cáceres, G. & Segal, R. & Pitié, F., 2014. "Latent heat storage with tubular-encapsulated phase change materials (PCMs)," Energy, Elsevier, vol. 76(C), pages 66-72.
    12. Chinnasamy, Veerakumar & Heo, Jaehyeok & Jung, Sungyong & Lee, Hoseong & Cho, Honghyun, 2023. "Shape stabilized phase change materials based on different support structures for thermal energy storage applications–A review," Energy, Elsevier, vol. 262(PB).
    13. Cárdenas-Ramírez, Carolina & Gómez, Maryory A. & Jaramillo, Franklin & Cardona, Andrés F. & Fernández, Angel G. & Cabeza, Luisa F., 2022. "Experimental steady-state and transient thermal performance of materials for thermal energy storage in building applications: From powder SS-PCMs to SS-PCM-based acrylic plaster," Energy, Elsevier, vol. 250(C).
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    2. Yin, Qianqian & Zhu, Ge & Wang, Ruikun & Zhao, Zhenghui, 2024. "Enhancing the thermal storage performance of biochar/paraffin composite phase change materials: Effect of oleophobic modification of biochar," Energy, Elsevier, vol. 293(C).

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