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Carbon dioxide and acetone mixtures as refrigerants for industry heat pumps to supply temperature in the range 150–220 oC

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  • Gómez-Hernández, J.
  • Grimes, R.
  • Briongos, J.V.
  • Marugán-Cruz, C.
  • Santana, D.

Abstract

Industry decarbonization is a key a challenge towards the transition to climate neutrality. Indeed, there is a need to satisfy heat at temperatures higher than 150 °C in relevant industrial sectors by upgrading lower temperature heat flows, such as heat from renewable heat sources, ambient heat or industrial waste heat. High temperature heat pumps (HTHP) can upgrade such heat flows enabling great savings in carbon emissions. New refrigerants are needed to develop HTHPs achieving high performances at high temperatures. This paper proposes the use of a new zeotropic mixture composed of carbon dioxide and acetone as the refrigerant of HTHPs working in the temperature range of 150–220 °C. The new fluid is compared with existing pure refrigerants currently used. The thermodynamic characterization of the CO2/acetone mixtures shows temperature glides below 50 K for CO2 mass fractions up to 10%. The best HTHP performance is shown for the mixture 5% CO2/95% acetone in mass fraction. For instance, such a mixture obtains a COP of 5.63 when the target outlet sink temperature is 200 °C and the temperature difference between the outlet heat sink and the inlet heat source is 70 K, showing an improvement of 46% compared to pure acetone.

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  • Gómez-Hernández, J. & Grimes, R. & Briongos, J.V. & Marugán-Cruz, C. & Santana, D., 2023. "Carbon dioxide and acetone mixtures as refrigerants for industry heat pumps to supply temperature in the range 150–220 oC," Energy, Elsevier, vol. 269(C).
    • Handle: RePEc:eee:energy:v:269:y:2023:i:c:s0360544223002153
    DOI: 10.1016/j.energy.2023.126821
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    1. Heberle, Florian & Preißinger, Markus & Brüggemann, Dieter, 2012. "Zeotropic mixtures as working fluids in Organic Rankine Cycles for low-enthalpy geothermal resources," Renewable Energy, Elsevier, vol. 37(1), pages 364-370.
    2. Jiang, Jiatong & Hu, Bin & Wang, R.Z. & Deng, Na & Cao, Feng & Wang, Chi-Chuan, 2022. "A review and perspective on industry high-temperature heat pumps," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    3. Arpagaus, Cordin & Bless, Frédéric & Uhlmann, Michael & Schiffmann, Jürg & Bertsch, Stefan S., 2018. "High temperature heat pumps: Market overview, state of the art, research status, refrigerants, and application potentials," Energy, Elsevier, vol. 152(C), pages 985-1010.
    4. Wang, Y. & Wang, J. & He, W., 2022. "Development of efficient, flexible and affordable heat pumps for supporting heat and power decarbonisation in the UK and beyond: Review and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    5. Zühlsdorf, Benjamin & Jensen, Jonas Kjær & Cignitti, Stefano & Madsen, Claus & Elmegaard, Brian, 2018. "Analysis of temperature glide matching of heat pumps with zeotropic working fluid mixtures for different temperature glides," Energy, Elsevier, vol. 153(C), pages 650-660.
    6. Men, Yiyu & Liu, Xiaohua & Zhang, Tao, 2021. "A review of boiler waste heat recovery technologies in the medium-low temperature range," Energy, Elsevier, vol. 237(C).
    7. Schlosser, F. & Jesper, M. & Vogelsang, J. & Walmsley, T.G. & Arpagaus, C. & Hesselbach, J., 2020. "Large-scale heat pumps: Applications, performance, economic feasibility and industrial integration," Renewable and Sustainable Energy Reviews, Elsevier, vol. 133(C).
    8. Zühlsdorf, B. & Meesenburg, W. & Ommen, T.S. & Thorsen, J.E. & Markussen, W.B. & Elmegaard, B., 2018. "Improving the performance of booster heat pumps using zeotropic mixtures," Energy, Elsevier, vol. 154(C), pages 390-402.
    9. Crespi, F. & Rodríguez de Arriba, P. & Sánchez, D. & Ayub, A. & Di Marcoberardino, G. & Invernizzi, C.M. & Martínez, G.S. & Iora, P. & Di Bona, D. & Binotti, M. & Manzolini, G., 2022. "Thermal efficiency gains enabled by using CO2 mixtures in supercritical power cycles," Energy, Elsevier, vol. 238(PC).
    10. Bamigbetan, Opeyemi & Eikevik, Trygve Magne & Nekså, Petter & Bantle, Michael & Schlemminger, Christian, 2019. "Experimental investigation of a prototype R-600 compressor for high temperature heat pump," Energy, Elsevier, vol. 169(C), pages 730-738.
    11. Chua, K.J. & Chou, S.K. & Yang, W.M., 2010. "Advances in heat pump systems: A review," Applied Energy, Elsevier, vol. 87(12), pages 3611-3624, December.
    12. Adamson, Keri-Marie & Walmsley, Timothy Gordon & Carson, James K. & Chen, Qun & Schlosser, Florian & Kong, Lana & Cleland, Donald John, 2022. "High-temperature and transcritical heat pump cycles and advancements: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 167(C).
    Full references (including those not matched with items on IDEAS)

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