IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v244y2022ipas0360544221028279.html
   My bibliography  Save this article

The redistribution and migration mechanism of chlorine during hydrothermal carbonization of waste biomass and fuel properties of hydrochars

Author

Listed:
  • Lin, Yousheng
  • Ge, Ya
  • He, Qing
  • Chen, Pengwei
  • Xiao, Hanmin

Abstract

This work investigated the effects of experimental conditions on the chlorine (Cl) behaviour during hydrothermal carbonization (HTC) of three waste biomasses. Temperature was found to be the most critical factor affecting Cl migration. Increasing temperature promoted the conversion of organic Cl to inorganic Cl through nucleophilic substitution and organic C–Cl cleavage reactions. The dechlorination efficiency was approximately 90% at high HTC severity. Specifically, the Cl contents in wheat, straw and eucalyptus hydrochars obtained at 270○C for 120 min drastically declined to 2349 mg/kg, 1943 mg/kg, and 312 mg/kg, respectively. The corresponding dechlorination efficiencies reached 89.93%, 90.81%, and 92.29%, respectively. Based on migration characteristics and theoretical inference, we proposed a Cl migration mechanism in waste biomass during HTC. X-ray photoelectron spectroscopy results revealed abundant oxygen-containing functional groups in the surface of hydrochars obtained at low HTC temperature. In contrast, at severe HTC conditions, the dehydration, decarboxylation, aromatization and polymerization reactions intensely occurred, resulting in lower H/C and O/C atomic ratios and enhanced aromatic C–C and CC. Energy analysis suggested that the natural properties of feedstocks significantly affected the energetic recovery efficiency. This research demonstrated the possibility of converting biomass into low-chlorine and high-energy-grade coal-alternative fuel through the HTC process.

Suggested Citation

  • Lin, Yousheng & Ge, Ya & He, Qing & Chen, Pengwei & Xiao, Hanmin, 2022. "The redistribution and migration mechanism of chlorine during hydrothermal carbonization of waste biomass and fuel properties of hydrochars," Energy, Elsevier, vol. 244(PA).
    • Handle: RePEc:eee:energy:v:244:y:2022:i:pa:s0360544221028279
    DOI: 10.1016/j.energy.2021.122578
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544221028279
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2021.122578?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Lin, Yousheng & Ge, Ya & Xiao, Hanmin & He, Qing & Wang, Wenhao & Chen, Baiman, 2020. "Investigation of hydrothermal co-carbonization of waste textile with waste wood, waste paper and waste food from typical municipal solid wastes," Energy, Elsevier, vol. 210(C).
    2. Huang, Neng & Zhao, Peitao & Ghosh, Sudip & Fedyukhin, Alexander, 2019. "Co-hydrothermal carbonization of polyvinyl chloride and moist biomass to remove chlorine and inorganics for clean fuel production," Applied Energy, Elsevier, vol. 240(C), pages 882-892.
    3. Aragón-Briceño, C.I. & Pozarlik, A.K. & Bramer, E.A. & Niedzwiecki, Lukasz & Pawlak-Kruczek, H. & Brem, G., 2021. "Hydrothermal carbonization of wet biomass from nitrogen and phosphorus approach: A review," Renewable Energy, Elsevier, vol. 171(C), pages 401-415.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ye, Lian & Zhang, Jianliang & Wang, Guangwei & Wang, Chen & Mao, Xiaoming & Ning, Xiaojun & Zhang, Nan & Teng, Haipeng & Li, Jinhua & Wang, Chuan, 2023. "Feasibility analysis of plastic and biomass hydrochar for blast furnace injection," Energy, Elsevier, vol. 263(PD).
    2. Lin, Yousheng & Hu, Zhifeng & Ge, Ya & Xiao, Hanmin & Zhang, Gang & He, Qing, 2023. "Chemical looping with oxygen uncoupling of biomass-derived hydrochar with Cu-based oxygen carriers modified by alkaline earth metals," Energy, Elsevier, vol. 280(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Wei, Yingyuan & Fakudze, Sandile & Zhang, Yiming & Ma, Ru & Shang, Qianqian & Chen, Jianqiang & Liu, Chengguo & Chu, Qiulu, 2022. "Co-hydrothermal carbonization of pomelo peel and PVC for production of hydrochar pellets with enhanced fuel properties and dechlorination," Energy, Elsevier, vol. 239(PD).
    2. Jaime E. Borbolla-Gaxiola & Andrew B. Ross & Valerie Dupont, 2022. "Multi-Variate and Multi-Response Analysis of Hydrothermal Carbonization of Food Waste: Hydrochar Composition and Solid Fuel Characteristics," Energies, MDPI, vol. 15(15), pages 1-19, July.
    3. Md Tahmid Islam & Al Ibtida Sultana & Cadianne Chambers & Swarna Saha & Nepu Saha & Kawnish Kirtania & M. Toufiq Reza, 2022. "Recent Progress on Emerging Applications of Hydrochar," Energies, MDPI, vol. 15(24), pages 1-45, December.
    4. Sharma, Nishesh & Jaiswal, Krishna Kumar & Kumar, Vinod & Vlaskin, Mikhail S. & Nanda, Manisha & Rautela, Indra & Tomar, Mahipal Singh & Ahmad, Waseem, 2021. "Effect of catalyst and temperature on the quality and productivity of HTL bio-oil from microalgae: A review," Renewable Energy, Elsevier, vol. 174(C), pages 810-822.
    5. Yao, Zhongliang & Ma, Xiaoqian & Xiao, Zhiyuan, 2020. "The effect of two pretreatment levels on the pyrolysis characteristics of water hyacinth," Renewable Energy, Elsevier, vol. 151(C), pages 514-527.
    6. Juan Félix González & Carmen María Álvez-Medina & Sergio Nogales-Delgado, 2023. "Biogas Steam Reforming in Wastewater Treatment Plants: Opportunities and Challenges," Energies, MDPI, vol. 16(17), pages 1-35, September.
    7. Eunhye Song & Ho Kim & Kyung Woo Kim & Young-Man Yoon, 2023. "Characteristic Evaluation of Different Carbonization Processes for Hydrochar, Torrefied Char, and Biochar Produced from Cattle Manure," Energies, MDPI, vol. 16(7), pages 1-14, April.
    8. Cheng, Chen & Ding, Lu & Guo, Qinghua & He, Qing & Gong, Yan & Alexander, Kozlov N. & Yu, Guangsuo, 2022. "Process analysis and kinetic modeling of coconut shell hydrothermal carbonization," Applied Energy, Elsevier, vol. 315(C).
    9. Aragon-Briceño, Christian & Pożarlik, Artur & Bramer, Eddy & Brem, Gerrit & Wang, Shule & Wen, Yuming & Yang, Weihong & Pawlak-Kruczek, Halina & Niedźwiecki, Łukasz & Urbanowska, Agnieszka & Mościcki,, 2022. "Integration of hydrothermal carbonization treatment for water and energy recovery from organic fraction of municipal solid waste digestate," Renewable Energy, Elsevier, vol. 184(C), pages 577-591.
    10. Yang, Fangming & Liu, Xin & Li, Mengbin & Uguna, Clement & Wang, Wenlong & Sun, Chenggong, 2023. "Polyvinyl chloride (PVC) derived microporous carbons prepared via hydrothermal dechlorination and potassium hydroxide activation for efficient CO2 capture," Renewable and Sustainable Energy Reviews, Elsevier, vol. 180(C).
    11. Shulun Han & Li Bai & Mingshu Chi & Xiuling Xu & Zhao Chen & Kecheng Yu, 2022. "Conversion of Waste Corn Straw to Value-Added Fuel via Hydrothermal Carbonization after Acid Washing," Energies, MDPI, vol. 15(5), pages 1-14, March.
    12. Liu, Quan & Zhang, Guanyu & Kong, Ge & Liu, Mingyang & Cao, Tianqi & Guo, Zhirui & Zhang, Xuesong & Han, Lujia, 2023. "Valorizing manure waste into green coal-like hydrochar: Parameters study, physicochemical characteristics, combustion behaviors and kinetics," Renewable Energy, Elsevier, vol. 216(C).
    13. Lin, Yousheng & Hu, Zhifeng & Ge, Ya & Xiao, Hanmin & Zhang, Gang & He, Qing, 2023. "Chemical looping with oxygen uncoupling of biomass-derived hydrochar with Cu-based oxygen carriers modified by alkaline earth metals," Energy, Elsevier, vol. 280(C).
    14. Zhao, Kaige & Li, Wanqing & Yu, Yingying & Chen, Guanyi & Yan, Beibei & Cheng, Zhanjun & Zhao, Hai & Fang, Yang, 2023. "Speciation and transformation of nitrogen in the hydrothermal liquefaction of wastewater-treated duckweed for the bio-oil production," Renewable Energy, Elsevier, vol. 204(C), pages 661-670.
    15. Suhartini, Sri & Rohma, Novita Ainur & Elviliana, & Hidayat, Nur & Sunyoto, Nimas Mayang S. & Mardawati, Efri & Kasbawati, & Mascruhin, Nanang & Idrus, Syazwani & Fitria, & Jung, Young Hoon & Melville, 2023. "Comparison of acid and alkaline pre-treatment on methane production from empty palm oil fruit bunches (OPEFB): Effect on characteristics, digester performance, and correlation of kinetic parameters," Renewable Energy, Elsevier, vol. 215(C).
    16. Agnieszka Urbanowska & Małgorzata Kabsch-Korbutowicz & Christian Aragon-Briceño & Mateusz Wnukowski & Artur Pożarlik & Lukasz Niedzwiecki & Marcin Baranowski & Michał Czerep & Przemysław Seruga & Hali, 2021. "Cascade Membrane System for Separation of Water and Organics from Liquid By-Products of HTC of the Agricultural Digestate—Evaluation of Performance," Energies, MDPI, vol. 14(16), pages 1-18, August.
    17. Ning, Xiaojun & Dang, Han & Xu, Runsheng & Wang, Guangwei & Zhang, Jianliang & Zhang, Nan & Wang, Chuan, 2022. "Co-hydrothermal carbonization of biomass and PVC for clean blast furnace injection fuel production: Experiment and DFT calculation," Renewable Energy, Elsevier, vol. 187(C), pages 156-168.
    18. Gabriel Gerner & Luca Meyer & Rahel Wanner & Thomas Keller & Rolf Krebs, 2021. "Sewage Sludge Treatment by Hydrothermal Carbonization: Feasibility Study for Sustainable Nutrient Recovery and Fuel Production," Energies, MDPI, vol. 14(9), pages 1-12, May.
    19. Sarrion, A. & Ipiales, R.P. & de la Rubia, M.A. & Mohedano, A.F. & Diaz, E., 2023. "Chicken meat and bone meal valorization by hydrothermal treatment and anaerobic digestion: Biofuel production and nutrient recovery," Renewable Energy, Elsevier, vol. 204(C), pages 652-660.
    20. Maciej Śliz & Klaudia Czerwińska & Aneta Magdziarz & Lidia Lombardi & Małgorzata Wilk, 2022. "Hydrothermal Carbonization of the Wet Fraction from Mixed Municipal Solid Waste: A Fuel and Structural Analysis of Hydrochars," Energies, MDPI, vol. 15(18), pages 1-15, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:244:y:2022:i:pa:s0360544221028279. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.