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Influence of ultrasonic pretreatment on the co-pyrolysis characteristics and kinetic parameters of municipal solid waste and paper mill sludge

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  • Fang, Shiwen
  • Lin, Yousheng
  • Lin, Yan
  • Chen, Shu
  • Shen, Xiangyang
  • Zhong, Tianming
  • Ding, Lixing
  • Ma, Xiaoqian

Abstract

In this study, through orthogonal experiments design, the influences of ultrasonic pretreatment (frequency, power and treatment time) on co-pyrolysis and catalytic pyrolysis of municipal solid waste and paper mill sludge were explored. The differential thermogravimetry curves became steeper and the peak values were larger after pretreatment, which made the pyrolysis reaction rapidly and the volatile separated out timely. However, the change of pyrolysis characteristics was not obvious after adding MgO. The catalytic effect of MgO increased with the increase of sludge ratio. After pretreatment, the average activation energy of the samples had an overall increasing trend, but the change was small. MgO had a decreasing effect on activation energy, and with the increasing proportion of sludge the degree of reduction became significant. In addition, high ultrasonic frequency had a negative effect on reducing activation energy.

Suggested Citation

  • Fang, Shiwen & Lin, Yousheng & Lin, Yan & Chen, Shu & Shen, Xiangyang & Zhong, Tianming & Ding, Lixing & Ma, Xiaoqian, 2020. "Influence of ultrasonic pretreatment on the co-pyrolysis characteristics and kinetic parameters of municipal solid waste and paper mill sludge," Energy, Elsevier, vol. 190(C).
  • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219320055
    DOI: 10.1016/j.energy.2019.116310
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    References listed on IDEAS

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    1. Zhou, Hui & Meng, AiHong & Long, YanQiu & Li, QingHai & Zhang, YanGuo, 2014. "An overview of characteristics of municipal solid waste fuel in China: Physical, chemical composition and heating value," Renewable and Sustainable Energy Reviews, Elsevier, vol. 36(C), pages 107-122.
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    3. Xuemeng Zhang & Chao Liu & Yuexi Chen & Guanghong Zheng & Yinguang Chen, 2022. "Source separation, transportation, pretreatment, and valorization of municipal solid waste: a critical review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 24(10), pages 11471-11513, October.
    4. Kang, Kang & Klinghoffer, Naomi B. & ElGhamrawy, Islam & Berruti, Franco, 2021. "Thermochemical conversion of agroforestry biomass and solid waste using decentralized and mobile systems for renewable energy and products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    5. Ma, Junfang & Liu, Jiaxun & Jiang, Xiumin & Zhang, Hai, 2021. "A two-dimensional distributed activation energy model for pyrolysis of solid fuels," Energy, Elsevier, vol. 230(C).

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