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Furanic biofuels production from biomass using Cu-based heterogeneous catalysts

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  • Viar, Nerea
  • Requies, Jesús M.
  • Agirre, Ion
  • Iriondo, Aitziber
  • Arias, Pedro L.

Abstract

Biorefineries can be a good alternative to cover the current needs of energy, such as transportation fuels and also fine chemicals. 5-hydroxymethylfurfural (HMF) can be obtained directly from biomass, and it is considered one of the most promising intermediate for the synthesis of biofuels. In this work the production of 2,5-dimethylfuran (DMF) and 2,5-dimethyltetrahydrofuran (DMTHF), two particularly attractive compounds to be used as biofuels due to its similar characteristics to gasoline, has been studied. For this purpose, a continuous fixed bed catalytic reactor was employed using HMF as raw material. Zr-supported Cu, CeCu, RuCu and NiCu catalysts were tested. Moreover, the catalysts textural properties were also measured - before and after the activity tesst - in order to get a deeper understanding of the relationships among the measured DMF yields and the catalyst characteristics. Final DMF, DMTHF and butanol separation was also evaluated.

Suggested Citation

  • Viar, Nerea & Requies, Jesús M. & Agirre, Ion & Iriondo, Aitziber & Arias, Pedro L., 2019. "Furanic biofuels production from biomass using Cu-based heterogeneous catalysts," Energy, Elsevier, vol. 172(C), pages 531-544.
    • Handle: RePEc:eee:energy:v:172:y:2019:i:c:p:531-544
    DOI: 10.1016/j.energy.2019.01.109
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    References listed on IDEAS

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    1. Viar, Nerea & Requies, Jesus M. & Agirre, Ion & Iriondo, Aitziber & García-Sancho, Cristina & Arias, Pedro L., 2022. "HMF hydrogenolysis over carbon-supported Ni–Cu catalysts to produce hydrogenated biofuels," Energy, Elsevier, vol. 255(C).
    2. Mourad, M. & Mahmoud, K., 2019. "Investigation into SI engine performance characteristics and emissions fuelled with ethanol/butanol-gasoline blends," Renewable Energy, Elsevier, vol. 143(C), pages 762-771.

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