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Experimental investigation and assessment of direct ammonia fuel cells utilizing alkaline molten and solid electrolytes

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  • Siddiqui, O.
  • Dincer, I.

Abstract

In the present study, the solid anion exchange membrane and molten electrolyte entailing direct type ammonia fuel cells are uniquely developed, and their performances are investigated through energy and exergy efficiencies at varying operating conditions and state properties, based on the presently conducted experiments and datasets obtained. Both energy and exergy efficiencies are determined to be 12.1 ± 0.4% and 13.8 ± 0.4% respectively at the maximum power density value of 6.4 ± 0.2 W m−2 for the membrane based cell. Higher humidifier temperatures are observed to improve the performance of the fuel cell. The energy and exergy efficiencies of the molten alkaline electrolyte based cell are found to be 20.6 ± 0.6% and 23.3 ± 0.7% respectively at a temperature of 220 °C. The open circuit voltages are found as 278 ± 8 mV and 520 ± 16 mV for the anion exchange membrane and molten alkaline electrolyte based cells respectively. The open circuit voltage decreases and the short circuit current density increases with increasing electrolyte temperatures.

Suggested Citation

  • Siddiqui, O. & Dincer, I., 2019. "Experimental investigation and assessment of direct ammonia fuel cells utilizing alkaline molten and solid electrolytes," Energy, Elsevier, vol. 169(C), pages 914-923.
    • Handle: RePEc:eee:energy:v:169:y:2019:i:c:p:914-923
    DOI: 10.1016/j.energy.2018.12.096
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    References listed on IDEAS

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    1. Khani, Leyla & Mahmoudi, S. Mohammad S. & Chitsaz, Ata & Rosen, Marc A., 2016. "Energy and exergoeconomic evaluation of a new power/cooling cogeneration system based on a solid oxide fuel cell," Energy, Elsevier, vol. 94(C), pages 64-77.
    2. Miura, Daisuke & Tezuka, Tetsuo, 2014. "A comparative study of ammonia energy systems as a future energy carrier, with particular reference to vehicle use in Japan," Energy, Elsevier, vol. 68(C), pages 428-436.
    3. Li, Yanchao & Bi, Mingshu & Li, Bei & Zhou, Yonghao & Huang, Lei & Gao, Wei, 2018. "Explosion hazard evaluation of renewable hydrogen/ammonia/air fuels," Energy, Elsevier, vol. 159(C), pages 252-263.
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    Cited by:

    1. Blanco, Elena C. & Sánchez, Antonio & Martín, Mariano & Vega, Pastora, 2023. "Methanol and ammonia as emerging green fuels: Evaluation of a new power generation paradigm," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    2. Al-Hamed, Khaled H.M. & Dincer, Ibrahim, 2021. "A novel ammonia solid oxide fuel cell-based powering system with on-board hydrogen production for clean locomotives," Energy, Elsevier, vol. 220(C).
    3. Marco Osvaldo Vigueras-Zúñiga & Maria Elena Tejeda-del-Cueto & Syed Mashruk & Marina Kovaleva & Cesar Leonardo Ordóñez-Romero & Agustin Valera-Medina, 2021. "Methane/Ammonia Radical Formation during High Temperature Reactions in Swirl Burners," Energies, MDPI, vol. 14(20), pages 1-13, October.
    4. Al-Hamed, K.H.M. & Dincer, Ibrahim, 2020. "A novel ammonia molten alkaline fuel cell based integrated powering system for clean rail transportation," Energy, Elsevier, vol. 201(C).

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