IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v141y2017icp1810-1818.html
   My bibliography  Save this article

Biodiesel synthesis from Saussurea heteromalla (D.Don) Hand-Mazz integrating ethanol production using biorefinery approach

Author

Listed:
  • Rozina,
  • Ahmad, Mushtaq
  • Zafar, Muhammad
  • Ali, Nasir
  • Lu, Houfang

Abstract

Biodiesel is a renewable and substitute fuel to diesel engines. The main limit for adoption of biodiesel on industrial scale as an alternative fuel is the high cost of its synthesis process using raw methanol during transesterification reaction. Using bio-refinery approach and inexpensive high-quality oil feedstock is an effective means to produce low-cost biodiesel. In this study Saussurea heteromalla a novel non-edible seed with high oil contents (30 wt%) was subjected first time to integrated synthesis of biodiesel and ethanol. Transesterification and simultaneous saccharification along with fermentation process was applied to produce biodiesel and ethanol respectively. Alkaline pretreatment with sodium hydroxide (8% w/v) at 100 °C was used to enhance ethanol yield from 30% to 80%. A highest biodiesel yield of 99% was achieved via optimized parameters of 6:1 alcohol to oil ratio with 0.26 wt% catalyst in 55 min time at 65 °C temperature using Response Surface Methodology. It was observed that 112.2 ± 1.6 g of biodiesel and 42.0 ± 0.5 g of ethanol were produced using 1 kg of Saussurea heteromalla seed oil. In addition, the fuel properties of prepared biodiesel were in accordance to ASTM D 6751 and EN 14214 standards.

Suggested Citation

  • Rozina, & Ahmad, Mushtaq & Zafar, Muhammad & Ali, Nasir & Lu, Houfang, 2017. "Biodiesel synthesis from Saussurea heteromalla (D.Don) Hand-Mazz integrating ethanol production using biorefinery approach," Energy, Elsevier, vol. 141(C), pages 1810-1818.
    • Handle: RePEc:eee:energy:v:141:y:2017:i:c:p:1810-1818
    DOI: 10.1016/j.energy.2017.11.074
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217319321
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.11.074?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Zhu, Qing-li & Shao, Rong & Dong, Rui & Yun, Zhi, 2014. "An integrated approach for obtaining biodiesel, sterols, gossypol, and raffinose from cottonseed on a biorefinery concept," Energy, Elsevier, vol. 70(C), pages 149-158.
    2. Noraini, M.Y. & Ong, Hwai Chyuan & Badrul, Mohamed Jan & Chong, W.T., 2014. "A review on potential enzymatic reaction for biofuel production from algae," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 24-34.
    3. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    4. Shafiei, Marzieh & Zilouei, Hamid & Zamani, Akram & Taherzadeh, Mohammad J. & Karimi, Keikhosro, 2013. "Enhancement of ethanol production from spruce wood chips by ionic liquid pretreatment," Applied Energy, Elsevier, vol. 102(C), pages 163-169.
    5. Montefrio, Marvin Joseph & Xinwen, Tai & Obbard, Jeffrey Philip, 2010. "Recovery and pre-treatment of fats, oil and grease from grease interceptors for biodiesel production," Applied Energy, Elsevier, vol. 87(10), pages 3155-3161, October.
    6. Atabani, A.E. & Silitonga, A.S. & Ong, H.C. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Fayaz, H., 2013. "Non-edible vegetable oils: A critical evaluation of oil extraction, fatty acid compositions, biodiesel production, characteristics, engine performance and emissions production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 18(C), pages 211-245.
    7. Anwar, Farooq & Rashid, Umer & Ashraf, Muhammad & Nadeem, Muhammad, 2010. "Okra (Hibiscus esculentus) seed oil for biodiesel production," Applied Energy, Elsevier, vol. 87(3), pages 779-785, March.
    8. No, Soo-Young, 2011. "Inedible vegetable oils and their derivatives for alternative diesel fuels in CI engines: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(1), pages 131-149, January.
    9. Popp, J. & Lakner, Z. & Harangi-Rákos, M. & Fári, M., 2014. "The effect of bioenergy expansion: Food, energy, and environment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 559-578.
    10. Eevera, T. & Rajendran, K. & Saradha, S., 2009. "Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental conditions," Renewable Energy, Elsevier, vol. 34(3), pages 762-765.
    11. Leung, Dennis Y.C. & Wu, Xuan & Leung, M.K.H., 2010. "A review on biodiesel production using catalyzed transesterification," Applied Energy, Elsevier, vol. 87(4), pages 1083-1095, April.
    12. Atadashi, I.M. & Aroua, M.K. & Aziz, A. Abdul, 2011. "Biodiesel separation and purification: A review," Renewable Energy, Elsevier, vol. 36(2), pages 437-443.
    13. Rozina, & Asif, Saira & Ahmad, Mushtaq & Zafar, Muhammad & Ali, Nsir, 2017. "Prospects and potential of fatty acid methyl esters of some non-edible seed oils for use as biodiesel in Pakistan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 687-702.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kumar, Dilip & Das, Tapas & Giri, Balendu Shekher & Verma, Bhawna, 2020. "Preparation and characterization of novel hybrid bio-support material immobilized from Pseudomonas cepacia lipase and its application to enhance biodiesel production," Renewable Energy, Elsevier, vol. 147(P1), pages 11-24.
    2. Nordmeier, Akira & Chidambaram, Dev, 2018. "Use of Zymomonas mobilis immobilized in doped calcium alginate threads for ethanol production," Energy, Elsevier, vol. 165(PB), pages 603-609.
    3. Gülüm, Mert & Onay, Funda Kutlu & Bilgin, Atilla, 2018. "Comparison of viscosity prediction capabilities of regression models and artificial neural networks," Energy, Elsevier, vol. 161(C), pages 361-369.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Tamilselvan, P. & Nallusamy, N. & Rajkumar, S., 2017. "A comprehensive review on performance, combustion and emission characteristics of biodiesel fuelled diesel engines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1134-1159.
    2. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel—Part: 1 selection of feedstocks, oil extraction techniques and conversion technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1109-1128.
    3. Rozina, & Asif, Saira & Ahmad, Mushtaq & Zafar, Muhammad & Ali, Nsir, 2017. "Prospects and potential of fatty acid methyl esters of some non-edible seed oils for use as biodiesel in Pakistan," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 687-702.
    4. Silitonga, A.S. & Masjuki, H.H. & Mahlia, T.M.I. & Ong, H.C. & Atabani, A.E. & Chong, W.T., 2013. "A global comparative review of biodiesel production from jatropha curcas using different homogeneous acid and alkaline catalysts: Study of physical and chemical properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 514-533.
    5. Aksoy, Laçine, 2011. "Opium poppy (Papaver somniferum L.) oil for preparation of biodiesel: Optimization of conditions," Applied Energy, Elsevier, vol. 88(12), pages 4713-4718.
    6. Yesilyurt, Murat Kadir & Cesur, Cüneyt & Aslan, Volkan & Yilbasi, Zeki, 2020. "The production of biodiesel from safflower (Carthamus tinctorius L.) oil as a potential feedstock and its usage in compression ignition engine: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    7. Moosavi, Seyed Amir & Aghaalikhani, Majid & Ghobadian, Barat & Fayyazi, Ebrahim, 2018. "Okra: A potential future bioenergy crop in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 93(C), pages 517-524.
    8. Bateni, Hamed & Karimi, Keikhosro & Zamani, Akram & Benakashani, Fatemeh, 2014. "Castor plant for biodiesel, biogas, and ethanol production with a biorefinery processing perspective," Applied Energy, Elsevier, vol. 136(C), pages 14-22.
    9. Lin, Lin & Cunshan, Zhou & Vittayapadung, Saritporn & Xiangqian, Shen & Mingdong, Dong, 2011. "Opportunities and challenges for biodiesel fuel," Applied Energy, Elsevier, vol. 88(4), pages 1020-1031, April.
    10. Atadashi, I.M. & Aroua, M.K. & Aziz, A.R. Abdul & Sulaiman, N.M.N., 2011. "Refining technologies for the purification of crude biodiesel," Applied Energy, Elsevier, vol. 88(12), pages 4239-4251.
    11. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    12. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Taufiq-Yap, Yun Hin, 2015. "Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance," Applied Energy, Elsevier, vol. 160(C), pages 58-70.
    13. Tang, Ying & Meng, Mei & Zhang, Jie & Lu, Yong, 2011. "Efficient preparation of biodiesel from rapeseed oil over modified CaO," Applied Energy, Elsevier, vol. 88(8), pages 2735-2739, August.
    14. Wu, Xuan & Leung, Dennis Y.C., 2011. "Optimization of biodiesel production from camelina oil using orthogonal experiment," Applied Energy, Elsevier, vol. 88(11), pages 3615-3624.
    15. Bhuiya, M.M.K. & Rasul, M.G. & Khan, M.M.K. & Ashwath, N. & Azad, A.K. & Hazrat, M.A., 2016. "Prospects of 2nd generation biodiesel as a sustainable fuel – Part 2: Properties, performance and emission characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 1129-1146.
    16. Shelare, Sagar D. & Belkhode, Pramod N. & Nikam, Keval Chandrakant & Jathar, Laxmikant D. & Shahapurkar, Kiran & Soudagar, Manzoore Elahi M. & Veza, Ibham & Khan, T.M. Yunus & Kalam, M.A. & Nizami, Ab, 2023. "Biofuels for a sustainable future: Examining the role of nano-additives, economics, policy, internet of things, artificial intelligence and machine learning technology in biodiesel production," Energy, Elsevier, vol. 282(C).
    17. Ewunie, Gebresilassie Asnake & Morken, John & Lekang, Odd Ivar & Yigezu, Zerihun Demrew, 2021. "Factors affecting the potential of Jatropha curcas for sustainable biodiesel production: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 137(C).
    18. Azad, A.K. & Rasul, M.G. & Khan, M.M.K. & Sharma, Subhash C. & Hazrat, M.A., 2015. "Prospect of biofuels as an alternative transport fuel in Australia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 331-351.
    19. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    20. Takase, Mohammed & Zhao, Ting & Zhang, Min & Chen, Yao & Liu, Hongyang & Yang, Liuqing & Wu, Xiangyang, 2015. "An expatiate review of neem, jatropha, rubber and karanja as multipurpose non-edible biodiesel resources and comparison of their fuel, engine and emission properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 495-520.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:141:y:2017:i:c:p:1810-1818. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.