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Effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form-stable phase change materials

Author

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  • Cai, Yibing
  • Ke, Huizhen
  • Dong, Ju
  • Wei, Qufu
  • Lin, Jiulong
  • Zhao, Yong
  • Song, Lei
  • Hu, Yuan
  • Huang, Fenglin
  • Gao, Weidong
  • Fong, Hao

Abstract

The ultrafine composite fibers consisting of lauric acid (LA), polyethylene terephthalate (PET), and silica nanoparticles (nano-SiO2) were prepared through the materials processing technique of electrospinning as an innovative type of form-stable phase change materials (PCMs). The effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun LA/PET/SiO2 composite fibers were studied. SEM images revealed that the LA/PET/SiO2 composite fibers with nano-SiO2 possessed desired morphologies with reduced average fiber diameters as compared to the LA/PET fibers without nano-SiO2. DSC measurements indicated that the amount of nano-SiO2 in the fibers had an influence on the crystallization of LA, and played an important role on the heat enthalpies of the composite fibers; while it had no appreciable effect on the phase change temperatures. TGA results suggested that the incorporation of nano-SiO2 increased the onset thermal degradation temperature, maximum weight loss temperature, and charred residue at 700 °C of the composite fibers, indicating the improved thermal stability of the fibers. MCC tests showed that the heat resistance effect and/or barrier property generated by nano-SiO2 resulted in an increase of initial combustion temperature and a decrease of the heat release rate for the electrospun ultrafine composite fibers.

Suggested Citation

  • Cai, Yibing & Ke, Huizhen & Dong, Ju & Wei, Qufu & Lin, Jiulong & Zhao, Yong & Song, Lei & Hu, Yuan & Huang, Fenglin & Gao, Weidong & Fong, Hao, 2011. "Effects of nano-SiO2 on morphology, thermal energy storage, thermal stability, and combustion properties of electrospun lauric acid/PET ultrafine composite fibers as form-stable phase change materials," Applied Energy, Elsevier, vol. 88(6), pages 2106-2112, June.
    • Handle: RePEc:eee:appene:v:88:y:2011:i:6:p:2106-2112
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    References listed on IDEAS

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    5. Golestaneh, S.I. & Mosallanejad, A. & Karimi, G. & Khorram, M. & Khashi, M., 2016. "Fabrication and characterization of phase change material composite fibers with wide phase-transition temperature range by co-electrospinning method," Applied Energy, Elsevier, vol. 182(C), pages 409-417.
    6. Wu, Yang & Chen, Changzhong & Jia, Yifan & Wu, Jie & Huang, Yong & Wang, Linge, 2018. "Review on electrospun ultrafine phase change fibers (PCFs) for thermal energy storage," Applied Energy, Elsevier, vol. 210(C), pages 167-181.
    7. Rashidi, Saman & Esfahani, Javad Abolfazli & Rashidi, Abbas, 2017. "A review on the applications of porous materials in solar energy systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1198-1210.
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    9. Darzi, Mohammad Ebrahimnejad & Golestaneh, Seyyed Iman & Kamali, Marziyeh & Karimi, Gholamreza, 2019. "Thermal and electrical performance analysis of co-electrospun-electrosprayed PCM nanofiber composites in the presence of graphene and carbon fiber powder," Renewable Energy, Elsevier, vol. 135(C), pages 719-728.
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    12. Zhao, Manxiang & Zhang, Xu & Kong, Xiangfei, 2020. "Preparation and characterization of a novel composite phase change material with double phase change points based on nanocapsules," Renewable Energy, Elsevier, vol. 147(P1), pages 374-383.
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