IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v393y2025ics0306261925007445.html
   My bibliography  Save this article

Experimental demonstration of dynamic demand response scheduling for PEM-electrolyzers

Author

Listed:
  • Keller, Roger
  • Baader, Florian Joseph
  • Bardow, André
  • Müller, Martin
  • Peters, Ralf

Abstract

The use of renewable energy sources, such as wind power and photovoltaics is expected to produce fluctuating electricity prices. These fluctuations give PEM electrolyzers the opportunity to reduce costs, as they can adapt their production rates rapidly. Moreover, typically slow temperature dynamics of electrolyzers increase their flexibility for effective operational management strategies. With a defined temperature trajectory during scheduling optimization, overload operation of the electrolyzer for a given amount of time is possible. However, the temperature dynamics are typically nonlinear. In conjunction with discrete on/off decisions, temperature dynamics lead to mixed-integer nonlinear optimization problems for scheduling that are highly challenging to solve in real time. In this study, we experimentally validate the dynamic ramping scheduling optimization method that precisely linearizes nonlinear temperature dynamics using a flatness-based coordinate transformation. Utilizing the available information from the dynamic scheduling optimization a 100 kW PEM electrolyzer was operated by studying three stack temperature control methods, rejecting disturbances from load variations. Identifying a suitable control method was essential to guarantee the desired temperature tracking performance of the optimization. Our experiments show a 3.8 % cost reduction compared to the benchmark without overload operation. The designed PEM electrolyzer model also deviated only 0.6 % in costs from the experiment. Simulative scaling of PEM electrolysis to 2 MW demonstrates even higher cost reductions with the dynamic ramping method, as the larger electrolyzer has slower dynamics.

Suggested Citation

  • Keller, Roger & Baader, Florian Joseph & Bardow, André & Müller, Martin & Peters, Ralf, 2025. "Experimental demonstration of dynamic demand response scheduling for PEM-electrolyzers," Applied Energy, Elsevier, vol. 393(C).
  • Handle: RePEc:eee:appene:v:393:y:2025:i:c:s0306261925007445
    DOI: 10.1016/j.apenergy.2025.126014
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261925007445
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2025.126014?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Flamm, Benjamin & Peter, Christian & Büchi, Felix N. & Lygeros, John, 2021. "Electrolyzer modeling and real-time control for optimized production of hydrogen gas," Applied Energy, Elsevier, vol. 281(C).
    2. Hu, Song & Guo, Bin & Ding, Shunliang & Yang, Fuyuan & Dang, Jian & Liu, Biao & Gu, Junjie & Ma, Jugang & Ouyang, Minggao, 2022. "A comprehensive review of alkaline water electrolysis mathematical modeling," Applied Energy, Elsevier, vol. 327(C).
    3. Pantò, Fabiola & Siracusano, Stefania & Briguglio, Nicola & Aricò, Antonino Salvatore, 2020. "Durability of a recombination catalyst-based membrane-electrode assembly for electrolysis operation at high current density," Applied Energy, Elsevier, vol. 279(C).
    4. Zhang, Hong & Yuan, Tiejiang, 2022. "Optimization and economic evaluation of a PEM electrolysis system considering its degradation in variable-power operations," Applied Energy, Elsevier, vol. 324(C).
    5. Qi, Ruomei & Li, Jiarong & Lin, Jin & Song, Yonghua & Wang, Jiepeng & Cui, Qiangqiang & Qiu, Yiwei & Tang, Ming & Wang, Jian, 2023. "Thermal modeling and controller design of an alkaline electrolysis system under dynamic operating conditions," Applied Energy, Elsevier, vol. 332(C).
    6. Rauls, Edward & Hehemann, Michael & Keller, Roger & Scheepers, Fabian & Müller, Martin & Stolten, Detlef, 2023. "Favorable Start-Up behavior of polymer electrolyte membrane water electrolyzers," Applied Energy, Elsevier, vol. 330(PA).
    7. Buttler, Alexander & Spliethoff, Hartmut, 2018. "Current status of water electrolysis for energy storage, grid balancing and sector coupling via power-to-gas and power-to-liquids: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 2440-2454.
    8. Scheepers, Fabian & Stähler, Markus & Stähler, Andrea & Rauls, Edward & Müller, Martin & Carmo, Marcelo & Lehnert, Werner, 2021. "Temperature optimization for improving polymer electrolyte membrane-water electrolysis system efficiency," Applied Energy, Elsevier, vol. 283(C).
    9. Papakonstantinou, Georgios & Algara-Siller, Gerardo & Teschner, Detre & Vidaković-Koch, Tanja & Schlögl, Robert & Sundmacher, Kai, 2020. "Degradation study of a proton exchange membrane water electrolyzer under dynamic operation conditions," Applied Energy, Elsevier, vol. 280(C).
    10. María Villarreal Vives, Ana & Wang, Ruiqi & Roy, Sumit & Smallbone, Andrew, 2023. "Techno-economic analysis of large-scale green hydrogen production and storage," Applied Energy, Elsevier, vol. 346(C).
    11. Baojin Liu & Zhaofeng Song & Bing Yu & Gongde Yang & Jinjun Liu, 2024. "A Feedforward Control-Based Power Decoupling Strategy for Grid-Forming Grid-Connected Inverters," Energies, MDPI, vol. 17(2), pages 1-16, January.
    12. Fischer, David & Kaufmann, Florian & Hollinger, Raphael & Voglstätter, Christopher, 2018. "Real live demonstration of MPC for a power-to-gas plant," Applied Energy, Elsevier, vol. 228(C), pages 833-842.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Superchi, Francesco & Moustakis, Antonis & Pechlivanoglou, George & Bianchini, Alessandro, 2025. "On the importance of degradation modeling for the robust design of hybrid energy systems including renewables and storage," Applied Energy, Elsevier, vol. 377(PD).
    2. Zhang, Hong & Yuan, Tiejiang, 2022. "Optimization and economic evaluation of a PEM electrolysis system considering its degradation in variable-power operations," Applied Energy, Elsevier, vol. 324(C).
    3. Sayed-Ahmed, H. & Toldy, Á.I. & Santasalo-Aarnio, A., 2024. "Dynamic operation of proton exchange membrane electrolyzers—Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    4. Kang, Zhenye & Wang, Hao & Liu, Yanrong & Mo, Jingke & Wang, Min & Li, Jing & Tian, Xinlong, 2022. "Exploring and understanding the internal voltage losses through catalyst layers in proton exchange membrane water electrolysis devices," Applied Energy, Elsevier, vol. 317(C).
    5. Bak, Youngseok & Ryu, Hyuncheol & Choi, Gobong & Lee, Dongwoo & Lee, Jong Min, 2025. "Optimization of operational strategies for industrial applications of solar-based green hydrogen," Applied Energy, Elsevier, vol. 377(PD).
    6. Qiu, Xiaoyan & Zhang, Hang & Qiu, Yiwei & Zhou, Yi & Zang, Tianlei & Zhou, Buxiang & Qi, Ruomei & Lin, Jin & Wang, Jiepeng, 2023. "Dynamic parameter estimation of the alkaline electrolysis system combining Bayesian inference and adaptive polynomial surrogate models," Applied Energy, Elsevier, vol. 348(C).
    7. Lu, Xinyu & Chang, Huawei & Tu, Zhengkai & Xie, Changjun, 2025. "Performance evaluation of a novel off-grid CCHP system based on a semi-closed-loop PEMEC-PEMFC," Energy, Elsevier, vol. 321(C).
    8. Janke, Leandro & McDonagh, Shane & Weinrich, Sören & Murphy, Jerry & Nilsson, Daniel & Hansson, Per-Anders & Nordberg, Åke, 2020. "Optimizing power-to-H2 participation in the Nord Pool electricity market: Effects of different bidding strategies on plant operation," Renewable Energy, Elsevier, vol. 156(C), pages 820-836.
    9. María Villarreal Vives, Ana & Wang, Ruiqi & Roy, Sumit & Smallbone, Andrew, 2023. "Techno-economic analysis of large-scale green hydrogen production and storage," Applied Energy, Elsevier, vol. 346(C).
    10. Gorre, Jachin & Ruoss, Fabian & Karjunen, Hannu & Schaffert, Johannes & Tynjälä, Tero, 2020. "Cost benefits of optimizing hydrogen storage and methanation capacities for Power-to-Gas plants in dynamic operation," Applied Energy, Elsevier, vol. 257(C).
    11. Wang, Jingyi & Yang, Jinbin & Feng, Yu & Hua, Jing & Chen, Zhengjian & Liao, Mei & Zhang, Jingran & Qin, Jiang, 2025. "Comparative experimental study of alkaline and proton exchange membrane water electrolysis for green hydrogen production," Applied Energy, Elsevier, vol. 379(C).
    12. Tang, Yuzhen & Zheng, Zhuoqun & Min, Fanqi & Xie, Jingying & Yang, Hengzhao, 2025. "An optimization framework for component sizing and energy management of hybrid electrolyzer systems considering physical characteristics of alkaline electrolyzers and proton exchange membrane electrol," Renewable Energy, Elsevier, vol. 243(C).
    13. Han, Li & Wang, Shiqi & Cheng, Yingjie & Chen, Shuo & Wang, Xiaojing, 2024. "Multi-timescale scheduling of an integrated electric-hydrogen energy system with multiple types of electrolysis cells operating in concert with fuel cells," Energy, Elsevier, vol. 307(C).
    14. Yi-Chong Jiang & Shi-Meng Dong & Zheng Liang & Xiao-Li Wang & Lei Shi & Bing Yan & Tian Zhao, 2024. "Holistic Dynamic Modeling and Simulation of Alkaline Water Electrolysis Systems Based on Heat Current Method," Energies, MDPI, vol. 17(23), pages 1-24, December.
    15. Chi, Yingtian & Lin, Jin & Li, Peiyang & Yu, Zhipeng & Mu, Shujun & Li, Xi & Song, Yonghua, 2024. "Elevating the acceptable cost threshold for solid oxide cells: A case study on refinery decarbonization," Applied Energy, Elsevier, vol. 373(C).
    16. Qi, Meng & Park, Jinwoo & Landon, Robert Stephen & Kim, Jeongdong & Liu, Yi & Moon, Il, 2022. "Continuous and flexible Renewable-Power-to-Methane via liquid CO2 energy storage: Revisiting the techno-economic potential," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    17. Lv, Hong & Sun, Yongwen & Wang, Sen & Chen, Jingxian & Gao, Yuanfeng & Hu, Ding & Yao, Han & Zhang, Cunman, 2024. "Synergistic gradient distribution of IrO2/TiNX ratio and ionomer content reduces the internal voltage loss of the anode catalytic layer in PEM water electrolysis," Applied Energy, Elsevier, vol. 363(C).
    18. Förster, Robert & Eiser, Niklas & Kaiser, Matthias & Buhl, Hans Ulrich, 2025. "Leveraging synergies for energy-flexible operated electrolysis: A techno-economic analysis of power purchase agreement procurement with battery energy storage systems for renewable hydrogen production," Applied Energy, Elsevier, vol. 393(C).
    19. Li, Jiarong & Yang, Bosen & Lin, Jin & Liu, Feng & Qiu, Yiwei & Xu, Yanhui & Qi, Ruomei & Song, Yonghua, 2024. "Two-layer energy management strategy for grid-integrated multi-stack power-to-hydrogen station," Applied Energy, Elsevier, vol. 367(C).
    20. Sun, Jing & Xia, Yanghong & Peng, Yonggang & Wang, Anqi & Xiong, Jia & Wei, Wei, 2024. "Optimal operation for P2H system with 100% renewable energy concerning thermal-electric properties," Energy, Elsevier, vol. 308(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:393:y:2025:i:c:s0306261925007445. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.