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Synergetic enhancement of heat storage density and heat transport ability of phase change materials inlaid in 3D hierarchical ceramics

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  • Luo, Qingyang
  • Liu, Xianglei
  • Wang, Haolei
  • Xu, Qiao
  • Tian, Yang
  • Liang, Ting
  • Liu, Qibin
  • Liu, Zhan
  • Yang, Xiaohu
  • Xuan, Yimin
  • Li, Yongliang
  • Ding, Yulong

Abstract

Phase change materials (PCMs) based thermal energy storage techniques are promising to bridge the gap between thermal energy demand and intermittent supply. However, the low specific heat capacity (Cp) and thermal conductivity of PCMs preclude the simultaneous realization of high energy density and high power density thermal charging/discharging. Here, concurrent enhancement of Cp and thermal conductivity are demonstrated to be possible based on SiO2 nanoparticles decorated LiNO3/NaCl eutectics inlaid in three-dimensional (3D) hierarchical ultralight silicon carbide (SiC) foams. The average Cp is 4.86% higher than that of pure PCMs due to the high surface energy and interfacial thermal resistance induced by weak interaction between SiO2 nanoparticles and eutectics, as confirmed by molecular dynamics (MD) simulations. The thermal conductivity of composites achieves an ultrahigh value of 2.78 W·m−1·K−1, which is 259% of LiNO3/NaCl, accompanied with a large phase change enthalpy of 331.9 kJ/kg. Continuous heat transport paths provided by ultralight SiC foams have dominant contributions to the enhancement of thermal conductivity, although the presence of SiO2 nanoparticles deteriorates it slightly. In addition, the full-spectrum solar absorptance is enhanced from 25.2% to 76.3%. Rapid thermal transport and enhanced solar absorptance of composites enable heat charging rate to rise by 150% compared with SiO2 nanoparticles decorated eutectics. This work provides a strategy for the realization of high energy density and power density compatible thermal energy storage technology.

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  • Luo, Qingyang & Liu, Xianglei & Wang, Haolei & Xu, Qiao & Tian, Yang & Liang, Ting & Liu, Qibin & Liu, Zhan & Yang, Xiaohu & Xuan, Yimin & Li, Yongliang & Ding, Yulong, 2022. "Synergetic enhancement of heat storage density and heat transport ability of phase change materials inlaid in 3D hierarchical ceramics," Applied Energy, Elsevier, vol. 306(PA).
    • Handle: RePEc:eee:appene:v:306:y:2022:i:pa:s0306261921012976
    DOI: 10.1016/j.apenergy.2021.117995
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    3. Luo, Qingyang & Liu, Xianglei & Xu, Qiao & Tian, Yang & Yao, Haichen & Wang, Jianguo & Lv, Shushan & Dang, Chunzhuo & Xuan, Yimin, 2023. "Ceramic nanoparticles enhancement of latent heat thermal energy storage properties for LiNO3/NaCl: Evaluation from material to system level," Applied Energy, Elsevier, vol. 331(C).
    4. Yao, Haichen & Liu, Xianglei & Luo, Qingyang & Xu, Qiao & Tian, Yang & Ren, Tianze & Zheng, Hangbin & Gao, Ke & Dang, Chunzhuo & Xuan, Yimin & Liu, Zhan & Yang, Xiaohu & Ding, Yulong, 2022. "Experimental and numerical investigations of solar charging performances of 3D porous skeleton based latent heat storage devices," Applied Energy, Elsevier, vol. 320(C).
    5. Zhang, Shuai & Yan, Yuying, 2023. "Energy, exergy and economic analysis of ceramic foam-enhanced molten salt as phase change material for medium- and high-temperature thermal energy storage," Energy, Elsevier, vol. 262(PA).
    6. Liu, Jinjin & Xiao, Xin, 2023. "Molecular dynamics investigation of thermo-physical properties of molten salt with nanoparticles for solar energy application," Energy, Elsevier, vol. 282(C).

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