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Performance assessment and evaluation of SOC stacks designed for application in a reversible operated 150 kW rSOC power plant

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  • Königshofer, Benjamin
  • Boškoski, Pavle
  • Nusev, Gjorgji
  • Koroschetz, Markus
  • Hochfellner, Martin
  • Schwaiger, Marcel
  • Juričić, Đani
  • Hochenauer, Christoph
  • Subotić, Vanja

Abstract

The coupling of renewable energy sources with reversible operated high temperature solid oxide cells (rSOC) seems to be a promising option to store and supply clean energy in the future. This work provides the results of experimental investigations on the performance of a rSOC stack as a main unit of a large-scale module installed at a real industrial power plant. In order to determine the requirements as well as to propose strategies for safe and stable operation of the large-scale module the stack was tested under system relevant gas mixtures and operational conditions. Hereby, the focus was on steam electrolysis (EC) and fuel cell (FC) operation utilizing a H2/H2O/CO/CO2/N2 gas mixture, predefined by the reformer installed within the module at the power plant. Furthermore, the alternating operation between EC and FC mode was analyzed. The comprehensive analysis of the performance of the stack includes polarization curves, electrochemical impedance spectroscopy (EIS), distribution of relaxation times (DRT), gas analysis and temperature measurements. Thus, numerous combinations of operational parameters are linked to the individual processes within the stack. During EC operation higher hydrogen partial pressures presented significantly lower diffusion losses especially at low current densities, whereby in FC mode low fuel flows presented increased concentration losses. During alternating operation, prolonged voltage stabilization periods with increasing operation time were observed. Additionally, the processes represented by the peaks calculated from the DRT showed enhanced unstable behavior and presented a significant shift towards higher frequencies compared to constant mode operation.

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  • Königshofer, Benjamin & Boškoski, Pavle & Nusev, Gjorgji & Koroschetz, Markus & Hochfellner, Martin & Schwaiger, Marcel & Juričić, Đani & Hochenauer, Christoph & Subotić, Vanja, 2021. "Performance assessment and evaluation of SOC stacks designed for application in a reversible operated 150 kW rSOC power plant," Applied Energy, Elsevier, vol. 283(C).
  • Handle: RePEc:eee:appene:v:283:y:2021:i:c:s0306261920317487
    DOI: 10.1016/j.apenergy.2020.116372
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    References listed on IDEAS

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    1. Preininger, Michael & Stoeckl, Bernhard & Subotić, Vanja & Mittmann, Frank & Hochenauer, Christoph, 2019. "Performance of a ten-layer reversible Solid Oxide Cell stack (rSOC) under transient operation for autonomous application," Applied Energy, Elsevier, vol. 254(C).
    2. Kupecki, Jakub & Papurello, Davide & Lanzini, Andrea & Naumovich, Yevgeniy & Motylinski, Konrad & Blesznowski, Marcin & Santarelli, Massimo, 2018. "Numerical model of planar anode supported solid oxide fuel cell fed with fuel containing H2S operated in direct internal reforming mode (DIR-SOFC)," Applied Energy, Elsevier, vol. 230(C), pages 1573-1584.
    3. Subotić, Vanja & Stoeckl, Bernhard & Lawlor, Vincent & Strasser, Johannes & Schroettner, Hartmuth & Hochenauer, Christoph, 2018. "Towards a practical tool for online monitoring of solid oxide fuel cell operation: An experimental study and application of advanced data analysis approaches," Applied Energy, Elsevier, vol. 222(C), pages 748-761.
    4. Guk, Erdogan & Kim, Jung-Sik & Ranaweera, Manoj & Venkatesan, Vijay & Jackson, Lisa, 2018. "In-situ monitoring of temperature distribution in operating solid oxide fuel cell cathode using proprietary sensory techniques versus commercial thermocouples," Applied Energy, Elsevier, vol. 230(C), pages 551-562.
    5. Srikanth, S. & Heddrich, M.P. & Gupta, S. & Friedrich, K.A., 2018. "Transient reversible solid oxide cell reactor operation – Experimentally validated modeling and analysis," Applied Energy, Elsevier, vol. 232(C), pages 473-488.
    6. Subotić, Vanja & Baldinelli, Arianna & Barelli, Linda & Scharler, Robert & Pongratz, Gernot & Hochenauer, Christoph & Anca-Couce, Andrés, 2019. "Applicability of the SOFC technology for coupling with biomass-gasifier systems: Short- and long-term experimental study on SOFC performance and degradation behaviour," Applied Energy, Elsevier, vol. 256(C).
    7. Al-Masri, A. & Peksen, M. & Blum, L. & Stolten, D., 2014. "A 3D CFD model for predicting the temperature distribution in a full scale APU SOFC short stack under transient operating conditions," Applied Energy, Elsevier, vol. 135(C), pages 539-547.
    8. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
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