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Experimental investigation and thermodynamic modeling of an innovative molten salt for thermal energy storage (TES)

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  • Li, Xiang
  • Wu, Shuang
  • Wang, Yang
  • Xie, Leidong

Abstract

A novel computational thermodynamic approach based on thermodynamic principles was applied to design and develop innovative molten salt mixtures for thermal energy storage. In this work, the eutectic composition of the NaCl-NaF-Na2CO3 ternary system was predicted based on experimental data via computational thermodynamic approach. Substitutional solution model (SSM) was used to describe the Gibbs energies for all liquid phases. Thus, a set of self-consistent thermodynamic model parameters was obtained for three subsystems and the parameters were used to predict the eutectic composition of the NaF-NaCl-Na2CO3 ternary system. Results manifested that the predicted eutectic point of the ternary system were located at T = 849 K and XNaF = 21.66 mol%, XNaCl = 41.87 mol% and XNa2CO3 = 36.47 mol%. By means of Differential Scanning Calorimetry method, the predicted results were verified experimentally and the agreement between the measured and predicted values was satisfactory. Thermal-physical properties for eutectic salt mixtures, such as enthalpies of fusion, heat capacity, density and thermal stability, were also determined experimentally via thermal analysis methods in this work. Through computational thermodynamics approach, an innovative eutectic salt was designed and developed as thermal energy storage (TES) materials at high temperatures, especially it can be serve as candidate thermal energy storage materials for next generation concentrated solar power (CSP) plants.

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  • Li, Xiang & Wu, Shuang & Wang, Yang & Xie, Leidong, 2018. "Experimental investigation and thermodynamic modeling of an innovative molten salt for thermal energy storage (TES)," Applied Energy, Elsevier, vol. 212(C), pages 516-526.
    • Handle: RePEc:eee:appene:v:212:y:2018:i:c:p:516-526
    DOI: 10.1016/j.apenergy.2017.12.069
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    1. Merlin, Kevin & Soto, Jérôme & Delaunay, Didier & Traonvouez, Luc, 2016. "Industrial waste heat recovery using an enhanced conductivity latent heat thermal energy storage," Applied Energy, Elsevier, vol. 183(C), pages 491-503.
    2. Xu, Ben & Li, Peiwen & Chan, Cholik, 2015. "Application of phase change materials for thermal energy storage in concentrated solar thermal power plants: A review to recent developments," Applied Energy, Elsevier, vol. 160(C), pages 286-307.
    3. Aneke, Mathew & Wang, Meihong, 2016. "Energy storage technologies and real life applications – A state of the art review," Applied Energy, Elsevier, vol. 179(C), pages 350-377.
    4. Zhao, Haoran & Wu, Qiuwei & Hu, Shuju & Xu, Honghua & Rasmussen, Claus Nygaard, 2015. "Review of energy storage system for wind power integration support," Applied Energy, Elsevier, vol. 137(C), pages 545-553.
    5. Wang, Kun & He, Ya-Ling & Zhu, Han-Hui, 2017. "Integration between supercritical CO2 Brayton cycles and molten salt solar power towers: A review and a comprehensive comparison of different cycle layouts," Applied Energy, Elsevier, vol. 195(C), pages 819-836.
    6. Myers, Philip D. & Alam, Tanvir E. & Kamal, Rajeev & Goswami, D.Y. & Stefanakos, E., 2016. "Nitrate salts doped with CuO nanoparticles for thermal energy storage with improved heat transfer," Applied Energy, Elsevier, vol. 165(C), pages 225-233.
    7. Iverson, Brian D. & Conboy, Thomas M. & Pasch, James J. & Kruizenga, Alan M., 2013. "Supercritical CO2 Brayton cycles for solar-thermal energy," Applied Energy, Elsevier, vol. 111(C), pages 957-970.
    8. Wang, Tao & Mantha, Divakar & Reddy, Ramana G., 2013. "Novel low melting point quaternary eutectic system for solar thermal energy storage," Applied Energy, Elsevier, vol. 102(C), pages 1422-1429.
    9. Xu, Haoxin & Romagnoli, Alessandro & Sze, Jia Yin & Py, Xavier, 2017. "Application of material assessment methodology in latent heat thermal energy storage for waste heat recovery," Applied Energy, Elsevier, vol. 187(C), pages 281-290.
    10. Fernández, A.G. & Ushak, S. & Galleguillos, H. & Pérez, F.J., 2014. "Development of new molten salts with LiNO3 and Ca(NO3)2 for energy storage in CSP plants," Applied Energy, Elsevier, vol. 119(C), pages 131-140.
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    3. Kondaiah, P. & Pitchumani, R., 2022. "Novel textured surfaces for superior corrosion mitigation in molten carbonate salts for concentrating solar power," Renewable and Sustainable Energy Reviews, Elsevier, vol. 170(C).
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    5. Skrbek, Kryštof & Bartůněk, Vilém & Sedmidubský, David, 2022. "Molten salt-based nanocomposites for thermal energy storage: Materials, preparation techniques and properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 164(C).
    6. Zhang, Zhaoli & Alelyani, Sami M. & Zhang, Nan & Zeng, Chao & Yuan, Yanping & Phelan, Patrick E., 2018. "Thermodynamic analysis of a novel sodium hydroxide-water solution absorption refrigeration, heating and power system for low-temperature heat sources," Applied Energy, Elsevier, vol. 222(C), pages 1-12.
    7. Mostafavi Tehrani, S. Saeed & Shoraka, Yashar & Nithyanandam, Karthik & Taylor, Robert A., 2019. "Shell-and-tube or packed bed thermal energy storage systems integrated with a concentrated solar power: A techno-economic comparison of sensible and latent heat systems," Applied Energy, Elsevier, vol. 238(C), pages 887-910.
    8. Han, Dongmei & Guene Lougou, Bachirou & Xu, Yantao & Shuai, Yong & Huang, Xing, 2020. "Thermal properties characterization of chloride salts/nanoparticles composite phase change material for high-temperature thermal energy storage," Applied Energy, Elsevier, vol. 264(C).
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