IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v183y2016icp659-673.html
   My bibliography  Save this article

Experimental and modeling analysis of thermal runaway propagation over the large format energy storage battery module with Li4Ti5O12 anode

Author

Listed:
  • Huang, Peifeng
  • Ping, Ping
  • Li, Ke
  • Chen, Haodong
  • Wang, Qingsong
  • Wen, Jennifer
  • Sun, Jinhua

Abstract

Insight of the thermal characteristics and potential flame spread over lithium-ion battery (LIB) modules is important for designing battery thermal management system and fire protection measures. Such thermal characteristics and potential flame spread are also dependent on the different anode and cathode materials as well as the electrolyte. In the present study, thermal behavior and flame propagation over seven 50Ah Li(Ni1/3Mn1/3Co1/3)O2/Li4Ti5O12 large format LIBs arranged in rhombus and parallel layouts were investigated by directly heating one of the battery units. Such batteries have already been used commercially for energy storage while relatively little is known about its safety features in connection with potential runaway caused fire and explosion hazards. It was found in the present heating tests that fire-impingement resulted in elevated temperatures in the immediate vicinity of the LIBs that were in the range of between 200°C and 900°C. Such temperature aggravated thermal runaway (TR) propagation, resulting in rapid temperature rise within the battery module and even explosions after 20min of “smoldering period”. The thermal runaway and subsequent fire and explosion observed in the heating test was attributed to the violent reduction of the cathode material which coexisted with the electrolyte when the temperature exceeded 260°C. Separate laboratory tests, which measured the heat and gases generation from samples of the anode and cathode materials using C80 calorimeter, provided insight of the physical-chemistry processes inside the battery when the temperature reaches between 30°C and 300°C. The self-accelerating decomposition temperature of the cell, regarded as the critical temperature to trigger TR propagation, was calculated as 126.1 and 139.2°C using the classical Semenov and Frank-Kamenetskii models and the measurements of the calorimeter with the samples. These are consistent with the measured values in the heating tests in which TR propagated. The events leading to the explosions in the test for the rhombus layout was further analyzed and two possible explanations were postulated and analyzed based on either internal catalytic reactions or Boiling Liquid Expansion Vapor Explosion (BLEVE).

Suggested Citation

  • Huang, Peifeng & Ping, Ping & Li, Ke & Chen, Haodong & Wang, Qingsong & Wen, Jennifer & Sun, Jinhua, 2016. "Experimental and modeling analysis of thermal runaway propagation over the large format energy storage battery module with Li4Ti5O12 anode," Applied Energy, Elsevier, vol. 183(C), pages 659-673.
    • Handle: RePEc:eee:appene:v:183:y:2016:i:c:p:659-673
    DOI: 10.1016/j.apenergy.2016.08.160
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261916312697
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2016.08.160?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ping, Ping & Wang, Qingsong & Huang, Peifeng & Sun, Jinhua & Chen, Chunhua, 2014. "Thermal behaviour analysis of lithium-ion battery at elevated temperature using deconvolution method," Applied Energy, Elsevier, vol. 129(C), pages 261-273.
    2. Jhu, Can-Yong & Wang, Yih-Wen & Wen, Chia-Yuan & Shu, Chi-Min, 2012. "Thermal runaway potential of LiCoO2 and Li(Ni1/3Co1/3Mn1/3)O2 batteries determined with adiabatic calorimetry methodology," Applied Energy, Elsevier, vol. 100(C), pages 127-131.
    3. Donal P. Finegan & Mario Scheel & James B. Robinson & Bernhard Tjaden & Ian Hunt & Thomas J. Mason & Jason Millichamp & Marco Di Michiel & Gregory J. Offer & Gareth Hinds & Dan J.L. Brett & Paul R. Sh, 2015. "In-operando high-speed tomography of lithium-ion batteries during thermal runaway," Nature Communications, Nature, vol. 6(1), pages 1-10, November.
    4. Feng, Xuning & Weng, Caihao & Ouyang, Minggao & Sun, Jing, 2016. "Online internal short circuit detection for a large format lithium ion battery," Applied Energy, Elsevier, vol. 161(C), pages 168-180.
    5. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    6. Zhao, Rui & Liu, Jie & Gu, Junjie, 2016. "Simulation and experimental study on lithium ion battery short circuit," Applied Energy, Elsevier, vol. 173(C), pages 29-39.
    7. Beelen, H.P.G.J. & Raijmakers, L.H.J. & Donkers, M.C.F. & Notten, P.H.L. & Bergveld, H.J., 2016. "A comparison and accuracy analysis of impedance-based temperature estimation methods for Li-ion batteries," Applied Energy, Elsevier, vol. 175(C), pages 128-140.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mohammadmahdi Ghiji & Vasily Novozhilov & Khalid Moinuddin & Paul Joseph & Ian Burch & Brigitta Suendermann & Grant Gamble, 2020. "A Review of Lithium-Ion Battery Fire Suppression," Energies, MDPI, vol. 13(19), pages 1-30, October.
    2. Wang, Bin & Wang, Shifeng & Tang, Yuanyuan & Tsang, Chi-Wing & Dai, Jinchuan & Leung, Michael K.H. & Lu, Xiao-Ying, 2019. "Micro/nanostructured MnCo2O4.5 anodes with high reversible capacity and excellent rate capability for next generation lithium-ion batteries," Applied Energy, Elsevier, vol. 252(C), pages 1-1.
    3. Huang, Zonghou & Zhao, Chunpeng & Li, Huang & Peng, Wen & Zhang, Zheng & Wang, Qingsong, 2020. "Experimental study on thermal runaway and its propagation in the large format lithium ion battery module with two electrical connection modes," Energy, Elsevier, vol. 205(C).
    4. Zhou, Zhizuan & Zhou, Xiaodong & Ju, Xiaoyu & Li, Maoyu & Cao, Bei & Yang, Lizhong, 2023. "Experimental study of thermal runaway propagation along horizontal and vertical directions for LiFePO4 electrical energy storage modules," Renewable Energy, Elsevier, vol. 207(C), pages 13-26.
    5. Jiang, Z.Y. & Qu, Z.G. & Zhang, J.F. & Rao, Z.H., 2020. "Rapid prediction method for thermal runaway propagation in battery pack based on lumped thermal resistance network and electric circuit analogy," Applied Energy, Elsevier, vol. 268(C).
    6. Huang, Zonghou & Shen, Ting & Jin, Kaiqiang & Sun, Jinhua & Wang, Qingsong, 2022. "Heating power effect on the thermal runaway characteristics of large-format lithium ion battery with Li(Ni1/3Co1/3Mn1/3)O2 as cathode," Energy, Elsevier, vol. 239(PA).
    7. Huang, Peifeng & Yao, Caixia & Mao, Binbin & Wang, Qingsong & Sun, Jinhua & Bai, Zhonghao, 2020. "The critical characteristics and transition process of lithium-ion battery thermal runaway," Energy, Elsevier, vol. 213(C).
    8. Ren, Dongsheng & Feng, Xuning & Lu, Languang & He, Xiangming & Ouyang, Minggao, 2019. "Overcharge behaviors and failure mechanism of lithium-ion batteries under different test conditions," Applied Energy, Elsevier, vol. 250(C), pages 323-332.
    9. Wang, Gongquan & Kong, Depeng & Ping, Ping & He, Xiaoqin & Lv, Hongpeng & Zhao, Hengle & Hong, Wanru, 2023. "Modeling venting behavior of lithium-ion batteries during thermal runaway propagation by coupling CFD and thermal resistance network," Applied Energy, Elsevier, vol. 334(C).
    10. Meng, Lingyu & See, K.W. & Wang, Guofa & Wang, Yunpeng & Zhang, Yong & Zang, Caiyun & Xie, Bin, 2022. "Explosion-proof lithium-ion battery pack – In-depth investigation and experimental study on the design criteria," Energy, Elsevier, vol. 249(C).
    11. Zhou, Zhizuan & Zhou, Xiaodong & Li, Maoyu & Cao, Bei & Liew, K.M. & Yang, Lizhong, 2022. "Experimentally exploring prevention of thermal runaway propagation of large-format prismatic lithium-ion battery module," Applied Energy, Elsevier, vol. 327(C).
    12. Said, Ahmed O. & Lee, Christopher & Stoliarov, Stanislav I. & Marshall, André W., 2019. "Comprehensive analysis of dynamics and hazards associated with cascading failure in 18650 lithium ion cell arrays," Applied Energy, Elsevier, vol. 248(C), pages 415-428.
    13. Mao, Binbin & Zhao, Chunpeng & Chen, Haodong & Wang, Qingsong & Sun, Jinhua, 2021. "Experimental and modeling analysis of jet flow and fire dynamics of 18650-type lithium-ion battery," Applied Energy, Elsevier, vol. 281(C).
    14. Huang, Zonghou & Yu, Yin & Duan, Qiangling & Qin, Peng & Sun, Jinhua & Wang, Qingsong, 2022. "Heating position effect on internal thermal runaway propagation in large-format lithium iron phosphate battery," Applied Energy, Elsevier, vol. 325(C).
    15. Ren, Dongsheng & Liu, Xiang & Feng, Xuning & Lu, Languang & Ouyang, Minggao & Li, Jianqiu & He, Xiangming, 2018. "Model-based thermal runaway prediction of lithium-ion batteries from kinetics analysis of cell components," Applied Energy, Elsevier, vol. 228(C), pages 633-644.
    16. Wang, Zhi & Wang, Jian, 2020. "Investigation of external heating-induced failure propagation behaviors in large-size cell modules with different phase change materials," Energy, Elsevier, vol. 204(C).
    17. Hongxu Li & Qing Gao & Yan Wang, 2023. "Experimental Investigation of the Thermal Runaway Propagation Characteristics and Thermal Failure Prediction Parameters of Six-Cell Lithium-Ion Battery Modules," Energies, MDPI, vol. 16(13), pages 1-14, July.
    18. Mao, Binbin & Liu, Chaoqun & Yang, Kai & Li, Shi & Liu, Pengjie & Zhang, Mingjie & Meng, Xiangdong & Gao, Fei & Duan, Qiangling & Wang, Qingsong & Sun, Jinhua, 2021. "Thermal runaway and fire behaviors of a 300 Ah lithium ion battery with LiFePO4 as cathode," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Minhwan Seo & Taedong Goh & Minjun Park & Sang Woo Kim, 2018. "Detection Method for Soft Internal Short Circuit in Lithium-Ion Battery Pack by Extracting Open Circuit Voltage of Faulted Cell," Energies, MDPI, vol. 11(7), pages 1-18, June.
    2. Ren, Dongsheng & Liu, Xiang & Feng, Xuning & Lu, Languang & Ouyang, Minggao & Li, Jianqiu & He, Xiangming, 2018. "Model-based thermal runaway prediction of lithium-ion batteries from kinetics analysis of cell components," Applied Energy, Elsevier, vol. 228(C), pages 633-644.
    3. Liu, Binghe & Yin, Sha & Xu, Jun, 2016. "Integrated computation model of lithium-ion battery subject to nail penetration," Applied Energy, Elsevier, vol. 183(C), pages 278-289.
    4. Noelle, Daniel J. & Wang, Meng & Le, Anh V. & Shi, Yang & Qiao, Yu, 2018. "Internal resistance and polarization dynamics of lithium-ion batteries upon internal shorting," Applied Energy, Elsevier, vol. 212(C), pages 796-808.
    5. Feng, Xuning & Lu, Languang & Ouyang, Minggao & Li, Jiangqiu & He, Xiangming, 2016. "A 3D thermal runaway propagation model for a large format lithium ion battery module," Energy, Elsevier, vol. 115(P1), pages 194-208.
    6. Ren, Dongsheng & Feng, Xuning & Lu, Languang & He, Xiangming & Ouyang, Minggao, 2019. "Overcharge behaviors and failure mechanism of lithium-ion batteries under different test conditions," Applied Energy, Elsevier, vol. 250(C), pages 323-332.
    7. Qiao, Dongdong & Wang, Xueyuan & Lai, Xin & Zheng, Yuejiu & Wei, Xuezhe & Dai, Haifeng, 2022. "Online quantitative diagnosis of internal short circuit for lithium-ion batteries using incremental capacity method," Energy, Elsevier, vol. 243(C).
    8. Mao, Ning & Zhang, Teng & Wang, Zhirong & Gadkari, Siddharth & Wang, Junling & He, Tengfei & Gao, Tianfeng & Cai, Qiong, 2023. "Revealing the thermal stability and component heat contribution ratio of overcharged lithium-ion batteries during thermal runaway," Energy, Elsevier, vol. 263(PD).
    9. Chen, Zeyu & Xiong, Rui & Tian, Jinpeng & Shang, Xiong & Lu, Jiahuan, 2016. "Model-based fault diagnosis approach on external short circuit of lithium-ion battery used in electric vehicles," Applied Energy, Elsevier, vol. 184(C), pages 365-374.
    10. Minhwan Seo & Taedong Goh & Minjun Park & Gyogwon Koo & Sang Woo Kim, 2017. "Detection of Internal Short Circuit in Lithium Ion Battery Using Model-Based Switching Model Method," Energies, MDPI, vol. 10(1), pages 1-13, January.
    11. Mohammadmahdi Ghiji & Vasily Novozhilov & Khalid Moinuddin & Paul Joseph & Ian Burch & Brigitta Suendermann & Grant Gamble, 2020. "A Review of Lithium-Ion Battery Fire Suppression," Energies, MDPI, vol. 13(19), pages 1-30, October.
    12. Xu, Jun & Liu, Binghe & Wang, Xinyi & Hu, Dayong, 2016. "Computational model of 18650 lithium-ion battery with coupled strain rate and SOC dependencies," Applied Energy, Elsevier, vol. 172(C), pages 180-189.
    13. Yang, Ruixin & Xiong, Rui & Ma, Suxiao & Lin, Xinfan, 2020. "Characterization of external short circuit faults in electric vehicle Li-ion battery packs and prediction using artificial neural networks," Applied Energy, Elsevier, vol. 260(C).
    14. Xinwei Cong & Caiping Zhang & Jiuchun Jiang & Weige Zhang & Yan Jiang & Linjing Zhang, 2021. "A Comprehensive Signal-Based Fault Diagnosis Method for Lithium-Ion Batteries in Electric Vehicles," Energies, MDPI, vol. 14(5), pages 1-21, February.
    15. Liu, Tong & Tao, Changfa & Wang, Xishi, 2020. "Cooling control effect of water mist on thermal runaway propagation in lithium ion battery modules," Applied Energy, Elsevier, vol. 267(C).
    16. Yi Wu & Saurabh Saxena & Yinjiao Xing & Youren Wang & Chuan Li & Winco K. C. Yung & Michael Pecht, 2018. "Analysis of Manufacturing-Induced Defects and Structural Deformations in Lithium-Ion Batteries Using Computed Tomography," Energies, MDPI, vol. 11(4), pages 1-22, April.
    17. Chen, Zeyu & Zhang, Bo & Xiong, Rui & Shen, Weixiang & Yu, Quanqing, 2021. "Electro-thermal coupling model of lithium-ion batteries under external short circuit," Applied Energy, Elsevier, vol. 293(C).
    18. Zhang, Guangxu & Wei, Xuezhe & Tang, Xuan & Zhu, Jiangong & Chen, Siqi & Dai, Haifeng, 2021. "Internal short circuit mechanisms, experimental approaches and detection methods of lithium-ion batteries for electric vehicles: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    19. Troy, Stefanie & Schreiber, Andrea & Reppert, Thorsten & Gehrke, Hans-Gregor & Finsterbusch, Martin & Uhlenbruck, Sven & Stenzel, Peter, 2016. "Life Cycle Assessment and resource analysis of all-solid-state batteries," Applied Energy, Elsevier, vol. 169(C), pages 757-767.
    20. Xiong, Rui & Sun, Wanzhou & Yu, Quanqing & Sun, Fengchun, 2020. "Research progress, challenges and prospects of fault diagnosis on battery system of electric vehicles," Applied Energy, Elsevier, vol. 279(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:183:y:2016:i:c:p:659-673. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.