IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v162y2016icp1024-1033.html
   My bibliography  Save this article

The influence of chain extender on properties of polyurethane-based phase change materials modified with graphene

Author

Listed:
  • Pielichowska, Kinga
  • Nowak, Michał
  • Szatkowski, Piotr
  • Macherzyńska, Beata

Abstract

In this paper polyurethane-based phase change materials (PCMs) modified with graphene for thermal energy storage were obtained in situ using a one-step bulk polymerization method. Polyurethanes (PUs) have been synthesized with 1,4-butanediol as a chain extender or without a chain extender. FTIR-ATR, DSC, TGA, SEM, OM and ultrasonic techniques were used for characterization of the obtained composites containing up to 4wt.% of graphene. FTIR-ATR analysis confirmed PU structure and proved that there was no chemical reaction between polyurethane and graphene. The highest heat of phase transition and crystallinity were found for PU system synthesized without the chain extender and modified with 1.0wt.% of graphene. Microscopic observation results indicated spherulite structures typical for poly(ethylene glycol) (PEG) which was used to form soft segments, with regions of lamellar crystal bundles radiating from the center of a spherulite. Thermal cycling tests were done by 50 and 100 heating/cooling cyclings in air and nitrogen atmosphere for verification of the thermal reliability and chemical stability – it has been found the heat of phase transition was generally not diminished. Importantly, the thermal conductivity of the PCMs was improved after modification with graphene. Generally, PUPEG without chain extender exhibited higher heat of phase transition, higher thermal stability and better thermal reliability.

Suggested Citation

  • Pielichowska, Kinga & Nowak, Michał & Szatkowski, Piotr & Macherzyńska, Beata, 2016. "The influence of chain extender on properties of polyurethane-based phase change materials modified with graphene," Applied Energy, Elsevier, vol. 162(C), pages 1024-1033.
    • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1024-1033
    DOI: 10.1016/j.apenergy.2015.10.174
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261915014166
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2015.10.174?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ascione, Fabrizio & Bianco, Nicola & De Masi, Rosa Francesca & de’ Rossi, Filippo & Vanoli, Giuseppe Peter, 2014. "Energy refurbishment of existing buildings through the use of phase change materials: Energy savings and indoor comfort in the cooling season," Applied Energy, Elsevier, vol. 113(C), pages 990-1007.
    2. Xu, Ben & Li, Peiwen & Chan, Cholik, 2015. "Application of phase change materials for thermal energy storage in concentrated solar thermal power plants: A review to recent developments," Applied Energy, Elsevier, vol. 160(C), pages 286-307.
    3. Sun, Xiaoqin & Zhang, Quan & Medina, Mario A. & Liao, Shuguang, 2015. "Performance of a free-air cooling system for telecommunications base stations using phase change materials (PCMs): In-situ tests," Applied Energy, Elsevier, vol. 147(C), pages 325-334.
    4. Hawlader, M. N. A. & Uddin, M. S. & Khin, Mya Mya, 2003. "Microencapsulated PCM thermal-energy storage system," Applied Energy, Elsevier, vol. 74(1-2), pages 195-202, January.
    5. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Preparation and thermal properties of polyethylene glycol/expanded graphite blends for energy storage," Applied Energy, Elsevier, vol. 86(9), pages 1479-1483, September.
    6. Ling, Ziye & Wang, Fangxian & Fang, Xiaoming & Gao, Xuenong & Zhang, Zhengguo, 2015. "A hybrid thermal management system for lithium ion batteries combining phase change materials with forced-air cooling," Applied Energy, Elsevier, vol. 148(C), pages 403-409.
    7. Jankowski, Nicholas R. & McCluskey, F. Patrick, 2014. "A review of phase change materials for vehicle component thermal buffering," Applied Energy, Elsevier, vol. 113(C), pages 1525-1561.
    8. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing, 2009. "Preparation and performance of form-stable polyethylene glycol/silicon dioxide composites as solid-liquid phase change materials," Applied Energy, Elsevier, vol. 86(2), pages 170-174, February.
    9. Fan, Li-Wu & Fang, Xin & Wang, Xiao & Zeng, Yi & Xiao, Yu-Qi & Yu, Zi-Tao & Xu, Xu & Hu, Ya-Cai & Cen, Ke-Fa, 2013. "Effects of various carbon nanofillers on the thermal conductivity and energy storage properties of paraffin-based nanocomposite phase change materials," Applied Energy, Elsevier, vol. 110(C), pages 163-172.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    2. Li, Min & Mu, Boyuan, 2019. "Effect of different dimensional carbon materials on the properties and application of phase change materials: A review," Applied Energy, Elsevier, vol. 242(C), pages 695-715.
    3. Liu, Lu & Fan, Xiaoqiao & Zhang, Yuang & Zhang, Shufen & Wang, Wentao & Jin, Xin & Tang, Bingtao, 2020. "Novel bio-based phase change materials with high enthalpy for thermal energy storage," Applied Energy, Elsevier, vol. 268(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Aiqin & An, Jinliang & Yang, Jinglei & Yang, En-Hua, 2018. "Microencapsulated phase change materials with composite titania-polyurea (TiO2-PUA) shell," Applied Energy, Elsevier, vol. 215(C), pages 468-478.
    2. Sarı, Ahmet & Alkan, Cemil & Bilgin, Cahit, 2014. "Micro/nano encapsulation of some paraffin eutectic mixtures with poly(methyl methacrylate) shell: Preparation, characterization and latent heat thermal energy storage properties," Applied Energy, Elsevier, vol. 136(C), pages 217-227.
    3. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    4. SarI, Ahmet & Alkan, Cemil & Karaipekli, Ali, 2010. "Preparation, characterization and thermal properties of PMMA/n-heptadecane microcapsules as novel solid-liquid microPCM for thermal energy storage," Applied Energy, Elsevier, vol. 87(5), pages 1529-1534, May.
    5. Dubey, Abhayjeet kumar & Sun, Jingyi & Choudhary, Tushar & Dash, Madhusmita & Rakshit, Dibakar & Ansari, M Zahid & Ramakrishna, Seeram & Liu, Yong & Nanda, Himansu Sekhar, 2023. "Emerging phase change materials with improved thermal efficiency for a clean and sustainable environment: An approach towards net zero," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    6. Kahwaji, Samer & Johnson, Michel B. & Kheirabadi, Ali C. & Groulx, Dominic & White, Mary Anne, 2018. "A comprehensive study of properties of paraffin phase change materials for solar thermal energy storage and thermal management applications," Energy, Elsevier, vol. 162(C), pages 1169-1182.
    7. Wang, Weilong & Li, Hailong & Guo, Shaopeng & He, Shiquan & Ding, Jing & Yan, Jinyue & Yang, Jianping, 2015. "Numerical simulation study on discharging process of the direct-contact phase change energy storage system," Applied Energy, Elsevier, vol. 150(C), pages 61-68.
    8. Umair, Malik Muhammad & Zhang, Yuang & Iqbal, Kashif & Zhang, Shufen & Tang, Bingtao, 2019. "Novel strategies and supporting materials applied to shape-stabilize organic phase change materials for thermal energy storage–A review," Applied Energy, Elsevier, vol. 235(C), pages 846-873.
    9. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Investigation on the thermal performance of a high temperature packed bed thermal energy storage system containing carbonate salt based composite phase change materials," Applied Energy, Elsevier, vol. 247(C), pages 374-388.
    10. Zhang, Long & Zhou, Kechao & Wei, Quiping & Ma, Li & Ye, Wentao & Li, Haichao & Zhou, Bo & Yu, Zhiming & Lin, Cheng-Te & Luo, Jingting & Gan, Xueping, 2019. "Thermal conductivity enhancement of phase change materials with 3D porous diamond foam for thermal energy storage," Applied Energy, Elsevier, vol. 233, pages 208-219.
    11. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    12. Ahmed Hassan & Mohammad Shakeel Laghari & Yasir Rashid, 2016. "Micro-Encapsulated Phase Change Materials: A Review of Encapsulation, Safety and Thermal Characteristics," Sustainability, MDPI, vol. 8(10), pages 1-32, October.
    13. Chen, Changzhong & Wang, Linge & Huang, Yong, 2011. "Electrospun phase change fibers based on polyethylene glycol/cellulose acetate blends," Applied Energy, Elsevier, vol. 88(9), pages 3133-3139.
    14. Costa, Sol Carolina & Kenisarin, Murat, 2022. "A review of metallic materials for latent heat thermal energy storage: Thermophysical properties, applications, and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 154(C).
    15. Han, Rui & Gao, Jihui & Wei, Siyu & Su, Yanlin & Sun, Fei & Zhao, Guangbo & Qin, Yukun, 2018. "Strongly coupled calcium carbonate/antioxidative graphite nanosheets composites with high cycling stability for thermochemical energy storage," Applied Energy, Elsevier, vol. 231(C), pages 412-422.
    16. Wu, Chang-Bo & Wu, Gang & Yang, Xi & Liu, Yu-Jing & Liang, Tao & Fu, Wei-Fei & Wang, Mang & Chen, Hong-Zheng, 2015. "Preparation of microencapsulated medium temperature phase change material of Tris(hydroxymethyl)methyl aminomethane@SiO2 with excellent cycling performance," Applied Energy, Elsevier, vol. 154(C), pages 361-368.
    17. Pelay, Ugo & Luo, Lingai & Fan, Yilin & Stitou, Driss & Rood, Mark, 2017. "Thermal energy storage systems for concentrated solar power plants," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 82-100.
    18. Han, Lipeng & Xie, Shaolei & Liu, Shang & Sun, Jinhe & Jia, Yongzhong & Jing, Yan, 2017. "Effects of sodium chloride on the thermal behavior of oxalic acid dihydrate for thermal energy storage," Applied Energy, Elsevier, vol. 185(P1), pages 762-767.
    19. Joulin, Annabelle & Younsi, Zohir & Zalewski, Laurent & Lassue, Stéphane & Rousse, Daniel R. & Cavrot, Jean-Paul, 2011. "Experimental and numerical investigation of a phase change material: Thermal-energy storage and release," Applied Energy, Elsevier, vol. 88(7), pages 2454-2462, July.
    20. Gutierrez, Andrea & Ushak, Svetlana & Galleguillos, Hector & Fernandez, Angel & Cabeza, Luisa F. & Grágeda, Mario, 2015. "Use of polyethylene glycol for the improvement of the cycling stability of bischofite as thermal energy storage material," Applied Energy, Elsevier, vol. 154(C), pages 616-621.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1024-1033. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.