IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v124y2014icp73-81.html
   My bibliography  Save this article

A comprehensive experimental procedure for CO2 coal gasification: Is there really a maximum reaction rate?

Author

Listed:
  • Gomez, Arturo
  • Silbermann, Rico
  • Mahinpey, Nader

Abstract

A novel procedure to perform carbon dioxide (CO2) gasification studies was tested with two different Alberta coals and compared to the most common procedures using thermogravimetric analysis (TGA). The designed experiments indicate that maximum reaction rates reported in the literature were probably a consequence of the increasing CO2 concentration in the gas mixture when the inert gas was switched to CO2. It has been proven that, independent of feedstocks, the time to observe this maximum reaction rate was constant, indicating the reported maximum reaction rate depends only on the gas dispersion when the gasifying agent is fed and not on the surface properties of the char.

Suggested Citation

  • Gomez, Arturo & Silbermann, Rico & Mahinpey, Nader, 2014. "A comprehensive experimental procedure for CO2 coal gasification: Is there really a maximum reaction rate?," Applied Energy, Elsevier, vol. 124(C), pages 73-81.
    • Handle: RePEc:eee:appene:v:124:y:2014:i:c:p:73-81
    DOI: 10.1016/j.apenergy.2014.02.077
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261914002220
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2014.02.077?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ahmed, I.I. & Gupta, A.K., 2011. "Kinetics of woodchips char gasification with steam and carbon dioxide," Applied Energy, Elsevier, vol. 88(5), pages 1613-1619, May.
    2. Prabowo, Bayu & Umeki, Kentaro & Yan, Mi & Nakamura, Masato R. & Castaldi, Marco J. & Yoshikawa, Kunio, 2014. "CO2–steam mixture for direct and indirect gasification of rice straw in a downdraft gasifier: Laboratory-scale experiments and performance prediction," Applied Energy, Elsevier, vol. 113(C), pages 670-679.
    3. Irfan, Muhammad F. & Usman, Muhammad R. & Kusakabe, K., 2011. "Coal gasification in CO2 atmosphere and its kinetics since 1948: A brief review," Energy, Elsevier, vol. 36(1), pages 12-40.
    4. Tremel, Alexander & Haselsteiner, Thomas & Kunze, Christian & Spliethoff, Hartmut, 2012. "Experimental investigation of high temperature and high pressure coal gasification," Applied Energy, Elsevier, vol. 92(C), pages 279-285.
    5. Nipattummakul, Nimit & Ahmed, Islam & Kerdsuwan, Somrat & Gupta, Ashwani K., 2010. "High temperature steam gasification of wastewater sludge," Applied Energy, Elsevier, vol. 87(12), pages 3729-3734, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Gomez, Arturo & Mahinpey, Nader, 2015. "A new model to estimate CO2 coal gasification kinetics based only on parent coal characterization properties," Applied Energy, Elsevier, vol. 137(C), pages 126-133.
    2. Jayakumar, Abhimanyu & Gomez, Arturo & Mahinpey, Nader, 2016. "Post-combustion CO2 capture using solid K2CO3: Discovering the carbonation reaction mechanism," Applied Energy, Elsevier, vol. 179(C), pages 531-543.
    3. Li, Yu & Fan, Weidong, 2016. "Effect of char gasification on NOx formation process in the deep air-staged combustion in a 20kW down flame furnace," Applied Energy, Elsevier, vol. 164(C), pages 258-267.
    4. Lee, Jechan & Yang, Xiao & Cho, Seong-Heon & Kim, Jae-Kon & Lee, Sang Soo & Tsang, Daniel C.W. & Ok, Yong Sik & Kwon, Eilhann E., 2017. "Pyrolysis process of agricultural waste using CO2 for waste management, energy recovery, and biochar fabrication," Applied Energy, Elsevier, vol. 185(P1), pages 214-222.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Prabowo, Bayu & Aziz, Muhammad & Umeki, Kentaro & Susanto, Herri & Yan, Mi & Yoshikawa, Kunio, 2015. "CO2-recycling biomass gasification system for highly efficient and carbon-negative power generation," Applied Energy, Elsevier, vol. 158(C), pages 97-106.
    2. Ahmed, I.I. & Gupta, A.K., 2013. "Experiments and stochastic simulations of lignite coal during pyrolysis and gasification," Applied Energy, Elsevier, vol. 102(C), pages 355-363.
    3. Chaiwatanodom, Paphonwit & Vivanpatarakij, Supawat & Assabumrungrat, Suttichai, 2014. "Thermodynamic analysis of biomass gasification with CO2 recycle for synthesis gas production," Applied Energy, Elsevier, vol. 114(C), pages 10-17.
    4. Rizkiana, Jenny & Guan, Guoqing & Widayatno, Wahyu Bambang & Hao, Xiaogang & Li, Xiumin & Huang, Wei & Abudula, Abuliti, 2014. "Promoting effect of various biomass ashes on the steam gasification of low-rank coal," Applied Energy, Elsevier, vol. 133(C), pages 282-288.
    5. Gomez, Arturo & Mahinpey, Nader, 2015. "A new model to estimate CO2 coal gasification kinetics based only on parent coal characterization properties," Applied Energy, Elsevier, vol. 137(C), pages 126-133.
    6. Emami Taba, Leila & Irfan, Muhammad Faisal & Wan Daud, Wan Ashri Mohd & Chakrabarti, Mohammed Harun, 2012. "The effect of temperature on various parameters in coal, biomass and CO-gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(8), pages 5584-5596.
    7. Botero, Cristina & Field, Randall P. & Herzog, Howard J. & Ghoniem, Ahmed F., 2013. "Impact of finite-rate kinetics on carbon conversion in a high-pressure, single-stage entrained flow gasifier with coal–CO2 slurry feed," Applied Energy, Elsevier, vol. 104(C), pages 408-417.
    8. Lopez, Gartzen & Alvarez, Jon & Amutio, Maider & Arregi, Aitor & Bilbao, Javier & Olazar, Martin, 2016. "Assessment of steam gasification kinetics of the char from lignocellulosic biomass in a conical spouted bed reactor," Energy, Elsevier, vol. 107(C), pages 493-501.
    9. Lee, Sung-Wook & Park, Jong-Soo & Lee, Chun-Boo & Lee, Dong-Wook & Kim, Hakjoo & Ra, Ho Won & Kim, Sung-Hyun & Ryi, Shin-Kun, 2014. "H2 recovery and CO2 capture after water–gas shift reactor using synthesis gas from coal gasification," Energy, Elsevier, vol. 66(C), pages 635-642.
    10. Ján Kačur & Marek Laciak & Milan Durdán & Patrik Flegner, 2023. "Investigation of Underground Coal Gasification in Laboratory Conditions: A Review of Recent Research," Energies, MDPI, vol. 16(17), pages 1-55, August.
    11. Im-orb, Karittha & Simasatitkul, Lida & Arpornwichanop, Amornchai, 2016. "Techno-economic analysis of the biomass gasification and Fischer–Tropsch integrated process with off-gas recirculation," Energy, Elsevier, vol. 94(C), pages 483-496.
    12. Zhang, Ziyin & Pang, Shusheng & Levi, Tana, 2017. "Influence of AAEM species in coal and biomass on steam co-gasification of chars of blended coal and biomass," Renewable Energy, Elsevier, vol. 101(C), pages 356-363.
    13. Duan, Zhengxiao & Zhang, Yanni & Deng, Jun & Shu, Pan & Yao, Di, 2023. "A systematic exploration of mapping knowledge domains for free radical research related to coal," Energy, Elsevier, vol. 282(C).
    14. Zhang, Xiaoyu & Zhu, Shujun & Zhu, Jianguo & Liu, Yuhua & Zhang, Jiahang & Hui, Jicheng & Ding, Hongliang & Cao, Xiaoyang & Lyu, Qinggang, 2023. "Preheating and combustion characteristics of anthracite under O2/N2, O2/CO2 and O2/CO2/H2O atmospheres," Energy, Elsevier, vol. 274(C).
    15. Prabu, V. & Geeta, K., 2015. "CO2 enhanced in-situ oxy-coal gasification based carbon-neutral conventional power generating systems," Energy, Elsevier, vol. 84(C), pages 672-683.
    16. Zhao, Jingyu & Deng, Jun & Wang, Tao & Song, Jiajia & Zhang, Yanni & Shu, Chi-Min & Zeng, Qiang, 2019. "Assessing the effectiveness of a high-temperature-programmed experimental system for simulating the spontaneous combustion properties of bituminous coal through thermokinetic analysis of four oxidatio," Energy, Elsevier, vol. 169(C), pages 587-596.
    17. Samuel C. Bayham & Andrew Tong & Mandar Kathe & Liang-Shih Fan, 2016. "Chemical looping technology for energy and chemical production," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 5(2), pages 216-241, March.
    18. Ma, Jing & Chen, Mengjun & Yang, Tianxue & Liu, Zhengang & Jiao, Wentao & Li, Dong & Gai, Chao, 2019. "Gasification performance of the hydrochar derived from co-hydrothermal carbonization of sewage sludge and sawdust," Energy, Elsevier, vol. 173(C), pages 732-739.
    19. Zhang, Jingxin & Hu, Qiang & Qu, Yiyuan & Dai, Yanjun & He, Yiliang & Wang, Chi-Hwa & Tong, Yen Wah, 2020. "Integrating food waste sorting system with anaerobic digestion and gasification for hydrogen and methane co-production," Applied Energy, Elsevier, vol. 257(C).
    20. Syed-Hassan, Syed Shatir A. & Wang, Yi & Hu, Song & Su, Sheng & Xiang, Jun, 2017. "Thermochemical processing of sewage sludge to energy and fuel: Fundamentals, challenges and considerations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 888-913.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:124:y:2014:i:c:p:73-81. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.