IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v113y2014icp78-85.html
   My bibliography  Save this article

Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide

Author

Listed:
  • Xiao, Jing
  • Wu, Luoming
  • Wu, Ying
  • Liu, Bing
  • Dai, Lu
  • Li, Zhong
  • Xia, Qibin
  • Xi, Hongxia

Abstract

This work is concerned with the question of why oxidative desulfurization (ODS) catalyst that show good catalytic performance for ODS of model gasoline thiophenic compounds is not effective for real gasoline. For the first time, the effects of gasoline composition on ODS using a phosphotungstic acid/activated carbon (HPW/AC) catalyst with H2O2 were investigated. ODS of thiophene, one of the most difficult thiophenic compounds to be oxidized, was studied in a model fuel system, where a high thiophene conversion rate of 90% could be reached in 2h at 90°C. However, when applying the ODS to a real gasoline, the ODS conversion rate decreased to only 32%, suggesting a strong inhibiting effect of gasoline composition on ODS. The ODS studies in different model fuels suggested that the inhibiting effect can be ascribed to the competitive adsorption and oxidation with the presence of the alkenes and alkylated aromatic hydrocarbons in real gasoline. The active pi-electrons in alkenes and alkyl groups in alkylated aromatic hydrocarbons may react with polyoxoperoxo species or peroxo-metallate complexes formed by phosphotungstic acid–H2O2 interaction. Additionally, it was indicated that the ODS selectivity followed the order of benzothiophene>trimethylthiophene>dimethylthiophene∼methylthiophene>thiophene, suggesting the partial charge on the electron-rich sulfur atom may play a decisive role for its oxidation reactivity. To mitigate the inhibiting effect of gasoline composition on ODS, we propose (a) implementation of selective separation–oxidation processes; (b) choice of suitable selective oxidants; (c) optimization of selective ODS reaction temperature, etc. to improve ODS selectivity for real gasoline desulfurization applications.

Suggested Citation

  • Xiao, Jing & Wu, Luoming & Wu, Ying & Liu, Bing & Dai, Lu & Li, Zhong & Xia, Qibin & Xi, Hongxia, 2014. "Effect of gasoline composition on oxidative desulfurization using a phosphotungstic acid/activated carbon catalyst with hydrogen peroxide," Applied Energy, Elsevier, vol. 113(C), pages 78-85.
    • Handle: RePEc:eee:appene:v:113:y:2014:i:c:p:78-85
    DOI: 10.1016/j.apenergy.2013.06.047
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261913005540
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2013.06.047?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Zarei, Alireza & Noshadi, Iman, 2013. "Transesterification of waste cooking oil by heteropoly acid (HPA) catalyst: Optimization and kinetic model," Applied Energy, Elsevier, vol. 102(C), pages 283-292.
    2. Ridha, Firas N. & Manovic, Vasilije & Macchi, Arturo & Anthony, Edward J., 2012. "The effect of SO2 on CO2 capture by CaO-based pellets prepared with a kaolin derived Al(OH)3 binder," Applied Energy, Elsevier, vol. 92(C), pages 415-420.
    3. Nurrohim, Agus & Sakugawa, Hiroshi, 2005. "Fuel-based inventory of NOx and SO2 emissions from motor vehicles in the Hiroshima Prefecture, Japan," Applied Energy, Elsevier, vol. 80(3), pages 291-305, March.
    4. Yang, Yu & Abu-Omar, Mahdi M. & Hu, Changwei, 2012. "Heteropolyacid catalyzed conversion of fructose, sucrose, and inulin to 5-ethoxymethylfurfural, a liquid biofuel candidate," Applied Energy, Elsevier, vol. 99(C), pages 80-84.
    5. Guo, Wei & Wang, Chengyong & Lin, Peng & Lu, Xiaoping, 2011. "Oxidative desulfurization of diesel with TBHP/isobutyl aldehyde/air oxidation system," Applied Energy, Elsevier, vol. 88(1), pages 175-179, January.
    6. Lv, Yuexia & Yu, Xinhai & Tu, Shan-Tung & Yan, Jinyue & Dahlquist, Erik, 2012. "Experimental studies on simultaneous removal of CO2 and SO2 in a polypropylene hollow fiber membrane contactor," Applied Energy, Elsevier, vol. 97(C), pages 283-288.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Ibrahim, Muna Hassan & Hayyan, Maan & Hashim, Mohd Ali & Hayyan, Adeeb, 2017. "The role of ionic liquids in desulfurization of fuels: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1534-1549.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Bingyun & Duan, Yuhua & Luebke, David & Morreale, Bryan, 2013. "Advances in CO2 capture technology: A patent review," Applied Energy, Elsevier, vol. 102(C), pages 1439-1447.
    2. Gupta, Anilkumar R. & Rathod, Virendra K., 2018. "Calcium diglyceroxide catalyzed biodiesel production from waste cooking oil in the presence of microwave: Optimization and kinetic studies," Renewable Energy, Elsevier, vol. 121(C), pages 757-767.
    3. Qin, Changlei & Yin, Junjun & Feng, Bo & Ran, Jingyu & Zhang, Li & Manovic, Vasilije, 2016. "Modelling of the calcination behaviour of a uniformly-distributed CuO/CaCO3 particle in Ca–Cu chemical looping," Applied Energy, Elsevier, vol. 164(C), pages 400-410.
    4. Ganapathy, Harish & Steinmayer, Sascha & Shooshtari, Amir & Dessiatoun, Serguei & Ohadi, Michael M. & Alshehhi, Mohamed, 2016. "Process intensification characteristics of a microreactor absorber for enhanced CO2 capture," Applied Energy, Elsevier, vol. 162(C), pages 416-427.
    5. Lin, Yi-Feng & Ko, Chia-Chieh & Chen, Chien-Hua & Tung, Kuo-Lun & Chang, Kai-Shiun & Chung, Tsair-Wang, 2014. "Sol–gel preparation of polymethylsilsesquioxane aerogel membranes for CO2 absorption fluxes in membrane contactors," Applied Energy, Elsevier, vol. 129(C), pages 25-31.
    6. Verma, Puneet & Sharma, M.P., 2016. "Review of process parameters for biodiesel production from different feedstocks," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 1063-1071.
    7. Zhao Xue & Jun Fu & Qiankun Fu & Xiaokang Li & Zhi Chen, 2023. "Modeling and Optimizing the Performance of Green Forage Maize Harvester Header Using a Combined Response Surface Methodology–Artificial Neural Network Approach," Agriculture, MDPI, vol. 13(10), pages 1-16, September.
    8. Yimin Deng & Renaud Ansart & Jan Baeyens & Huili Zhang, 2019. "Flue Gas Desulphurization in Circulating Fluidized Beds," Energies, MDPI, vol. 12(20), pages 1-19, October.
    9. Pan, Zehua & Shen, Jian & Wang, Jingyi & Xu, Xinhai & Chan, Wei Ping & Liu, Siyu & Zhou, Yexin & Yan, Zilin & Jiao, Zhenjun & Lim, Teik-Thye & Zhong, Zheng, 2022. "Thermodynamic analyses of a standalone diesel-fueled distributed power generation system based on solid oxide fuel cells," Applied Energy, Elsevier, vol. 308(C).
    10. Noushabadi, Abolfazl Sajadi & Dashti, Amir & Raji, Mojtaba & Zarei, Alireza & Mohammadi, Amir H., 2020. "Estimation of cetane numbers of biodiesel and diesel oils using regression and PSO-ANFIS models," Renewable Energy, Elsevier, vol. 158(C), pages 465-473.
    11. Itskos, Grigorios & Grammelis, Panagiotis & Scala, Fabrizio & Pawlak-Kruczek, Halina & Coppola, Antonio & Salatino, Piero & Kakaras, Emmanuel, 2013. "A comparative characterization study of Ca-looping natural sorbents," Applied Energy, Elsevier, vol. 108(C), pages 373-382.
    12. Ganapathy, H. & Shooshtari, A. & Dessiatoun, S. & Alshehhi, M. & Ohadi, M., 2014. "Fluid flow and mass transfer characteristics of enhanced CO2 capture in a minichannel reactor," Applied Energy, Elsevier, vol. 119(C), pages 43-56.
    13. Wang, Weilong & Xiao, Jing & Wei, Xiaolan & Ding, Jing & Wang, Xiaoxing & Song, Chunshan, 2014. "Development of a new clay supported polyethylenimine composite for CO2 capture," Applied Energy, Elsevier, vol. 113(C), pages 334-341.
    14. Peng Yang & Zhao Sun & Lunbo Duan & Hongjian Tang, 2020. "Mechanism of steam‐declined sulfation and steam‐enhanced carbonation by DFT calculations," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 10(2), pages 472-483, April.
    15. Torres-Olea, Benjamín & Fúnez-Núñez, Inmaculada & García-Sancho, Cristina & Cecilia, Juan Antonio & Moreno-Tost, Ramón & Maireles-Torres, Pedro, 2023. "Influence of Lewis and Brønsted acid catalysts in the transformation of hexoses into 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 207(C), pages 588-600.
    16. Lin, Yi-Feng & Chang, Jun-Min & Ye, Qian & Tung, Kuo-Lun, 2015. "Hydrophobic fluorocarbon-modified silica aerogel tubular membranes with excellent CO2 recovery ability in membrane contactors," Applied Energy, Elsevier, vol. 154(C), pages 21-25.
    17. Liang, Xuezheng, 2013. "Synthesis of biodiesel from waste oil under mild conditions using novel acidic ionic liquid immobilization on poly divinylbenzene," Energy, Elsevier, vol. 63(C), pages 103-108.
    18. Yan Shao & Donglin He & Changlei Qin & Jingyu Ran & Li Zhang, 2017. "SO 2 removal characteristics using waste CaO from calcium looping CO 2 capture process," Greenhouse Gases: Science and Technology, Blackwell Publishing, vol. 7(4), pages 637-648, August.
    19. Wang, Fu & Zhao, Jun & Miao, He & Zhao, Jiapei & Zhang, Houcheng & Yuan, Jinliang & Yan, Jinyue, 2018. "Current status and challenges of the ammonia escape inhibition technologies in ammonia-based CO2 capture process," Applied Energy, Elsevier, vol. 230(C), pages 734-749.
    20. Hu, Lei & Lin, Lu & Wu, Zhen & Zhou, Shouyong & Liu, Shijie, 2017. "Recent advances in catalytic transformation of biomass-derived 5-hydroxymethylfurfural into the innovative fuels and chemicals," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 230-257.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:113:y:2014:i:c:p:78-85. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.