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Optimization of Toluidine Blue Biosorption in Aqueous Solutions Using Polyporus Squamosus Fungi as Absorbent by Response Surface Methodology

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  • Liqaa Samir Esmail

    (Duhok Polytechnic University, Duhok, Iraq)

Abstract

Textile wastewater including a large number of dyes and heavy metals can have adverse impacts on human health and surface water. In this work, biosorption Toluidine Blue from aqueous media onto natural Polypourus squamosus fungi as a low-cost biosorbent was investigated. Central Composite Design (CCD) in Response Surface Methodology (RSM) was successfully applied to optimize the biosorption condition. Medium parameters affected the biosorption of Toluidine Blue were determined to be initial pH, initial Toluidine Blue (Tb) concentration, temperature, and absorbent dosage. All experiments were carried out in a batch system using 250 mL flasks containing 100 mL of Toluidine Blue solution with a temperature-controlled magnetic stirrer. The Tb concentrations remaining in filtration solutions after biosorption were analyzed using UV-Spectro. With the obtained quadratic model, the optimal conditions for maximum biosorbed Toluidine blue were calculated to be 7, 27.5 mg/L, 35°C and 0.05 g for pH, C°, T (°C) and adsorbent dosage, respectively. Furthermore, most known isotherm models such as Langmuir and Freundlich were computed to find the best-fitted model.

Suggested Citation

  • Liqaa Samir Esmail, 2021. "Optimization of Toluidine Blue Biosorption in Aqueous Solutions Using Polyporus Squamosus Fungi as Absorbent by Response Surface Methodology," Academic Journal of Chemistry, Academic Research Publishing Group, vol. 6(3), pages 60-68, 09-2021.
  • Handle: RePEc:arp:ajcarp:2021:p:60-68
    DOI: 10.32861/ajc.63.60.68
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    References listed on IDEAS

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    1. Alenka Le Marechal & Simona Vajnhandl & Bostjan Krizanec & Julija Volmajer Valh, 2012. "Textile Finishing Industry as an Important Source of Organic Pollutants," Chapters, in: Tomasz Puzyn & Aleksandra Mostrag (ed.), Organic Pollutants Ten Years After the Stockholm Convention - Environmental and Analytical Update, IntechOpen.
    2. Jack P. C. Kleijnen, 2015. "Response Surface Methodology," International Series in Operations Research & Management Science, in: Michael C Fu (ed.), Handbook of Simulation Optimization, edition 127, chapter 0, pages 81-104, Springer.
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