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Hydrogen production from biomass

Author

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  • N. Florin

    (University of Sydney)

  • A. Harris

    (University of Sydney)

Abstract

The ‘hydrogen economy’ has received considerable attention in academic, industrial and political contexts. There are opportunities for vast reductions in greenhouse gas emissions, increased energy security and greater overall efficiency. However, if hydrogen is to become a fundamental energy source for electrical power generation, as well as a transportation fuel, novel generation pathways will be necessary to meet the increase in demand. A promising means for generating hydrogen is the thermochemical conversion of biomass to a synthesis gas, composed of a mixture of hydrogen, carbon monoxide, carbon dioxide and methane. In order to manipulate the composition and maximise the hydrogen output, a calcium-based carbon dioxide sorbent can be utilised in situ. The removal of carbon dioxide alters the reaction chemistry to preferentially produce hydrogen. In this work we report on the characterisation of a likely Ca-based carbon dioxide sorbent and demonstrate the merits of hydrogen production from biomass, with in situ carbon dioxide capture, on the basis of a thermodynamic study. Using this model we show that hydrogen output from biomass gasification can be increased from 40%-vol to 80%-vol (dry basis) when a carbon dioxide sorbent is used.

Suggested Citation

  • N. Florin & A. Harris, 2007. "Hydrogen production from biomass," Environment Systems and Decisions, Springer, vol. 27(1), pages 207-215, March.
    • Handle: RePEc:spr:envsyd:v:27:y:2007:i:1:d:10.1007_s10669-007-9027-6
    DOI: 10.1007/s10669-007-9027-6
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    References listed on IDEAS

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    1. Ruggiero, M. & Manfrida, G., 1999. "An equilibrium model for biomass gasification processes," Renewable Energy, Elsevier, vol. 16(1), pages 1106-1109.
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    1. Vera Marcantonio & Danilo Monarca & Mauro Villarini & Andrea Di Carlo & Luca Del Zotto & Enrico Bocci, 2020. "Biomass Steam Gasification, High-Temperature Gas Cleaning, and SOFC Model: A Parametric Analysis," Energies, MDPI, vol. 13(22), pages 1-13, November.
    2. García, R. & Gil, M.V. & Rubiera, F. & Chen, D. & Pevida, C., 2021. "Renewable hydrogen production from biogas by sorption enhanced steam reforming (SESR): A parametric study," Energy, Elsevier, vol. 218(C).
    3. Masnadi, Mohammad S. & Grace, John R. & Bi, Xiaotao T. & Ellis, Naoko & Lim, C. Jim & Butler, James W., 2015. "Biomass/coal steam co-gasification integrated with in-situ CO2 capture," Energy, Elsevier, vol. 83(C), pages 326-336.
    4. Vera Marcantonio & Enrico Bocci & Danilo Monarca, 2019. "Development of a Chemical Quasi-Equilibrium Model of Biomass Waste Gasification in a Fluidized-Bed Reactor by Using Aspen Plus," Energies, MDPI, vol. 13(1), pages 1-15, December.
    5. Panwar, N.L. & Kothari, Richa & Tyagi, V.V., 2012. "Thermo chemical conversion of biomass – Eco friendly energy routes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 1801-1816.
    6. Nguyen, Nhut M. & Alobaid, Falah & Epple, Bernd, 2021. "Chemical looping gasification of torrefied woodchips in a bubbling fluidized bed test rig using iron-based oxygen carriers," Renewable Energy, Elsevier, vol. 172(C), pages 34-45.
    7. Hu, Mian & Guo, Dabin & Ma, Caifeng & Hu, Zhiquan & Zhang, Beiping & Xiao, Bo & Luo, Siyi & Wang, Jingbo, 2015. "Hydrogen-rich gas production by the gasification of wet MSW (municipal solid waste) coupled with carbon dioxide capture," Energy, Elsevier, vol. 90(P1), pages 857-863.
    8. Sun, Yongqi & Seetharaman, Seshadri & Liu, Qianyi & Zhang, Zuotai & Liu, Lili & Wang, Xidong, 2016. "Integrated biomass gasification using the waste heat from hot slags: Control of syngas and polluting gas releases," Energy, Elsevier, vol. 114(C), pages 165-176.
    9. Sreejith, C.C. & Haridasan, Navaneeth & Muraleedharan, C. & Arun, P., 2014. "Allothermal air–steam gasification of biomass with CO2 (carbon dioxide) sorption: Performance prediction based on a chemical kinetic model," Energy, Elsevier, vol. 69(C), pages 399-408.
    10. Situmorang, Yohanes Andre & Zhao, Zhongkai & An, Ping & Yu, Tao & Rizkiana, Jenny & Abudula, Abuliti & Guan, Guoqing, 2020. "A novel system of biomass-based hydrogen production by combining steam bio-oil reforming and chemical looping process," Applied Energy, Elsevier, vol. 268(C).
    11. Han, Long & Wang, Qinhui & Luo, Zhongyang & Rong, Nai & Deng, Guangyi, 2013. "H2 rich gas production via pressurized fluidized bed gasification of sawdust with in situ CO2 capture," Applied Energy, Elsevier, vol. 109(C), pages 36-43.
    12. Li, Bin & Wei, Liangyuan & Yang, Haiping & Wang, Xianhua & Chen, Hanping, 2014. "The enhancing mechanism of calcium oxide on water gas shift reaction for hydrogen production," Energy, Elsevier, vol. 68(C), pages 248-254.
    13. Gao, Ningbo & Śliz, Maciej & Quan, Cui & Bieniek, Artur & Magdziarz, Aneta, 2021. "Biomass CO2 gasification with CaO looping for syngas production in a fixed-bed reactor," Renewable Energy, Elsevier, vol. 167(C), pages 652-661.
    14. Shahbaz, Muhammad & yusup, Suzana & Inayat, Abrar & Patrick, David Onoja & Ammar, Muhammad, 2017. "The influence of catalysts in biomass steam gasification and catalytic potential of coal bottom ash in biomass steam gasification: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 468-476.
    15. Udomsirichakorn, Jakkapong & Salam, P. Abdul, 2014. "Review of hydrogen-enriched gas production from steam gasification of biomass: The prospect of CaO-based chemical looping gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 565-579.
    16. Nguyen, Nhut M. & Alobaid, Falah & May, Jan & Peters, Jens & Epple, Bernd, 2020. "Experimental study on steam gasification of torrefied woodchips in a bubbling fluidized bed reactor," Energy, Elsevier, vol. 202(C).
    17. Shahbaz, Muhammad & Al-Ansari, Tareq & Inayat, Muddasser & Sulaiman, Shaharin A. & Parthasarathy, Prakash & McKay, Gordon, 2020. "A critical review on the influence of process parameters in catalytic co-gasification: Current performance and challenges for a future prospectus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    18. Taufiq-Yap, Y.H. & Sivasangar, S. & Salmiaton, A., 2012. "Enhancement of hydrogen production by secondary metal oxide dopants on NiO/CaO material for catalytic gasification of empty palm fruit bunches," Energy, Elsevier, vol. 47(1), pages 158-165.
    19. Capa, A. & García, R. & Chen, D. & Rubiera, F. & Pevida, C. & Gil, M.V., 2020. "On the effect of biogas composition on the H2 production by sorption enhanced steam reforming (SESR)," Renewable Energy, Elsevier, vol. 160(C), pages 575-583.
    20. Wang, Jinsheng & Manovic, Vasilije & Wu, Yinghai & Anthony, Edward J., 2010. "A study on the activity of CaO-based sorbents for capturing CO2 in clean energy processes," Applied Energy, Elsevier, vol. 87(4), pages 1453-1458, April.
    21. Pala, Laxmi Prasad Rao & Wang, Qi & Kolb, Gunther & Hessel, Volker, 2017. "Steam gasification of biomass with subsequent syngas adjustment using shift reaction for syngas production: An Aspen Plus model," Renewable Energy, Elsevier, vol. 101(C), pages 484-492.
    22. Xuan, Jin & Leung, Michael K.H. & Leung, Dennis Y.C. & Ni, Meng, 2009. "A review of biomass-derived fuel processors for fuel cell systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1301-1313, August.
    23. Parthasarathy, Prakash & Narayanan, K. Sheeba, 2014. "Hydrogen production from steam gasification of biomass: Influence of process parameters on hydrogen yield – A review," Renewable Energy, Elsevier, vol. 66(C), pages 570-579.
    24. Abrar Inayat & Murni M. Ahmad & Suzana Yusup & Mohamed Ibrahim Abdul Mutalib, 2010. "Biomass Steam Gasification with In-Situ CO2 Capture for Enriched Hydrogen Gas Production: A Reaction Kinetics Modelling Approach," Energies, MDPI, vol. 3(8), pages 1-13, August.
    25. Ahmed, Tigabwa Y. & Ahmad, Murni M. & Yusup, Suzana & Inayat, Abrar & Khan, Zakir, 2012. "Mathematical and computational approaches for design of biomass gasification for hydrogen production: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2304-2315.

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