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Dynamic chloride ion adsorption on single iridium atom boosts seawater oxidation catalysis

Author

Listed:
  • Xinxuan Duan

    (Beijing University of Chemical Technology
    Nanyang Technological University)

  • Qihao Sha

    (Beijing University of Chemical Technology)

  • Pengsong Li

    (Chinese Academy of Sciences)

  • Tianshui Li

    (Beijing University of Chemical Technology)

  • Guotao Yang

    (Beijing University of Chemical Technology)

  • Wei Liu

    (Beijing University of Chemical Technology)

  • Ende Yu

    (Research Institute of Tsinghua University in Shenzhen)

  • Daojin Zhou

    (Beijing University of Chemical Technology)

  • Jinjie Fang

    (Beijing University of Chemical Technology)

  • Wenxing Chen

    (Energy & Catalysis Center, School of Materials Science & Engineering, Beijing Institute of Technology)

  • Yizhen Chen

    (University of Science and Technology of China)

  • Lirong Zheng

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Jiangwen Liao

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Zeyu Wang

    (Tsinghua University)

  • Yaping Li

    (Beijing University of Chemical Technology)

  • Hongbin Yang

    (City University of Hong Kong)

  • Guoxin Zhang

    (Shandong University of Science and Technology)

  • Zhongbin Zhuang

    (Beijing University of Chemical Technology
    Beijing University of Chemical Technology)

  • Sung-Fu Hung

    (National Yang Ming Chiao Tung University)

  • Changfei Jing

    (Tianjin University of Technology)

  • Jun Luo

    (University of Electronic Science and Technology of China)

  • Lu Bai

    (CAS Key Laboratory of Standardization and Measurement for Nanotechnology, National Center for Nanoscience and Technology)

  • Juncai Dong

    (Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Sciences)

  • Hai Xiao

    (Tsinghua University)

  • Wen Liu

    (Beijing University of Chemical Technology)

  • Yun Kuang

    (Beijing University of Chemical Technology
    Research Institute of Tsinghua University in Shenzhen)

  • Bin Liu

    (City University of Hong Kong
    City University of Hong Kong)

  • Xiaoming Sun

    (Beijing University of Chemical Technology)

Abstract

Seawater electrolysis offers a renewable, scalable, and economic means for green hydrogen production. However, anode corrosion by Cl- pose great challenges for its commercialization. Herein, different from conventional catalysts designed to repel Cl- adsorption, we develop an atomic Ir catalyst on cobalt iron layered double hydroxide (Ir/CoFe-LDH) to tailor Cl- adsorption and modulate the electronic structure of the Ir active center, thereby establishing a unique Ir-OH/Cl coordination for alkaline seawater electrolysis. Operando characterizations and theoretical calculations unveil the pivotal role of this coordination state to lower OER activation energy by a factor of 1.93. The Ir/CoFe-LDH exhibits a remarkable oxygen evolution reaction activity (202 mV overpotential and TOF = 7.46 O2 s−1) in 6 M NaOH+2.8 M NaCl, superior over Cl--free 6 M NaOH electrolyte (236 mV overpotential and TOF = 1.05 O2 s−1), with 100% catalytic selectivity and stability at high current densities (400-800 mA cm−2) for more than 1,000 h.

Suggested Citation

  • Xinxuan Duan & Qihao Sha & Pengsong Li & Tianshui Li & Guotao Yang & Wei Liu & Ende Yu & Daojin Zhou & Jinjie Fang & Wenxing Chen & Yizhen Chen & Lirong Zheng & Jiangwen Liao & Zeyu Wang & Yaping Li &, 2024. "Dynamic chloride ion adsorption on single iridium atom boosts seawater oxidation catalysis," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-46140-y
    DOI: 10.1038/s41467-024-46140-y
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    References listed on IDEAS

    as
    1. Pengsong Li & Maoyu Wang & Xinxuan Duan & Lirong Zheng & Xiaopeng Cheng & Yuefei Zhang & Yun Kuang & Yaping Li & Qing Ma & Zhenxing Feng & Wen Liu & Xiaoming Sun, 2019. "Boosting oxygen evolution of single-atomic ruthenium through electronic coupling with cobalt-iron layered double hydroxides," Nature Communications, Nature, vol. 10(1), pages 1-11, December.
    2. Heping Xie & Zhiyu Zhao & Tao Liu & Yifan Wu & Cheng Lan & Wenchuan Jiang & Liangyu Zhu & Yunpeng Wang & Dongsheng Yang & Zongping Shao, 2022. "A membrane-based seawater electrolyser for hydrogen generation," Nature, Nature, vol. 612(7941), pages 673-678, December.
    3. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    4. Junjun Shan & Mengwei Li & Lawrence F. Allard & Sungsik Lee & Maria Flytzani-Stephanopoulos, 2017. "Mild oxidation of methane to methanol or acetic acid on supported isolated rhodium catalysts," Nature, Nature, vol. 551(7682), pages 605-608, November.
    5. J. Tyler Mefford & Andrew R. Akbashev & Minkyung Kang & Cameron L. Bentley & William E. Gent & Haitao D. Deng & Daan Hein Alsem & Young-Sang Yu & Norman J. Salmon & David A. Shapiro & Patrick R. Unwin, 2021. "Correlative operando microscopy of oxygen evolution electrocatalysts," Nature, Nature, vol. 593(7857), pages 67-73, May.
    6. Kang Jiang & Min Luo & Ming Peng & Yaqian Yu & Ying-Rui Lu & Ting-Shan Chan & Pan Liu & Frank M. F. Groot & Yongwen Tan, 2020. "Dynamic active-site generation of atomic iridium stabilized on nanoporous metal phosphides for water oxidation," Nature Communications, Nature, vol. 11(1), pages 1-9, December.
    7. Yong-Tae Kim & Pietro Papa Lopes & Shin-Ae Park & A-Yeong Lee & Jinkyu Lim & Hyunjoo Lee & Seoin Back & Yousung Jung & Nemanja Danilovic & Vojislav Stamenkovic & Jonah Erlebacher & Joshua Snyder & Nen, 2017. "Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
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