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Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization

Author

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  • Wei-Wei Fang

    (Hefei University of Technology)

  • Gui-Yu Yang

    (Hefei University of Technology)

  • Zi-Hui Fan

    (Hefei University of Technology)

  • Zi-Chao Chen

    (Hefei University of Technology)

  • Xun-Liang Hu

    (Huazhong University of Science and Technology)

  • Zhen Zhan

    (Huazhong University of Science and Technology)

  • Irshad Hussain

    (Lahore University of Management Sciences (LUMS), Lahore Cantt)

  • Yang Lu

    (Hefei University of Technology)

  • Tao He

    (Hefei University of Technology)

  • Bi-En Tan

    (Huazhong University of Science and Technology)

Abstract

The use of light to regulate photocatalyzed reversible deactivation radical polymerization (RDRP) under mild conditions, especially driven by broadband light or sunlight directly, is highly desired. But the development of a suitable photocatalyzed polymerization system for large-scale production of polymers, especially block copolymers, has remained a big challenge. Herein, we report the development of a phosphine-based conjugated hypercrosslinked polymer (PPh3-CHCP) photocatalyst for an efficient large-scale photoinduced copper-catalyzed atom transfer radical polymerization (Cu-ATRP). Monomers including acrylates and methyl acrylates can achieve near-quantitative conversions under a wide range (450–940 nm) of radiations or sunlight directly. The photocatalyst could be easily recycled and reused. The sunlight-driven Cu-ATRP allowed the synthesis of homopolymers at 200 mL from various monomers, and monomer conversions approached 99% in clouds intermittency with good control over polydispersity. In addition, block copolymers at 400 mL scale can also be obtained, which demonstrates its great potential for industrial applications.

Suggested Citation

  • Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38402-y
    DOI: 10.1038/s41467-023-38402-y
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    1. Mohammadreza Esmaeilirad & Artem Baskin & Alireza Kondori & Ana Sanz-Matias & Jin Qian & Boao Song & Mahmoud Tamadoni Saray & Kamil Kucuk & Andres Ruiz Belmonte & Pablo Navarro Munoz Delgado & Junwon , 2021. "Gold-like activity copper-like selectivity of heteroatomic transition metal carbides for electrocatalytic carbon dioxide reduction reaction," Nature Communications, Nature, vol. 12(1), pages 1-10, December.
    2. Qiang Ma & Jinshuai Song & Xun Zhang & Yu Jiang & Li Ji & Saihu Liao, 2021. "Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    3. Hiroshi Nishiyama & Taro Yamada & Mamiko Nakabayashi & Yoshiki Maehara & Masaharu Yamaguchi & Yasuko Kuromiya & Yoshie Nagatsuma & Hiromasa Tokudome & Seiji Akiyama & Tomoaki Watanabe & Ryoichi Narush, 2021. "Photocatalytic solar hydrogen production from water on a 100-m2 scale," Nature, Nature, vol. 598(7880), pages 304-307, October.
    4. Yiou Wang & Anastasia Vogel & Michael Sachs & Reiner Sebastian Sprick & Liam Wilbraham & Savio J. A. Moniz & Robert Godin & Martijn A. Zwijnenburg & James R. Durrant & Andrew I. Cooper & Junwang Tang, 2019. "Current understanding and challenges of solar-driven hydrogen generation using polymeric photocatalysts," Nature Energy, Nature, vol. 4(9), pages 746-760, September.
    5. Chenyu Wu & Kenward Jung & Yongtao Ma & Wenjian Liu & Cyrille Boyer, 2021. "Unravelling an oxygen-mediated reductive quenching pathway for photopolymerisation under long wavelengths," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    6. Yubao Zhao & Peng Zhang & Zhenchun Yang & Lina Li & Jingyu Gao & Sheng Chen & Tengfeng Xie & Caozheng Diao & Shibo Xi & Beibei Xiao & Chun Hu & Wonyong Choi, 2021. "Mechanistic analysis of multiple processes controlling solar-driven H2O2 synthesis using engineered polymeric carbon nitride," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    7. Zeyu Liu & Youshi Lan & Jianfeng Jia & Yiyun Geng & Xiaobin Dai & Litang Yan & Tongyang Hu & Jing Chen & Krzysztof Matyjaszewski & Gang Ye, 2022. "Multi-scale computer-aided design and photo-controlled macromolecular synthesis boosting uranium harvesting from seawater," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    8. Joel Y. Y. Loh & Nazir P. Kherani & Geoffrey A. Ozin, 2021. "Persistent CO2 photocatalysis for solar fuels in the dark," Nature Sustainability, Nature, vol. 4(6), pages 466-473, June.
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    1. Woojin Jeon & Yonghwan Kwon & Min Sang Kwon, 2024. "Highly efficient dual photoredox/copper catalyzed atom transfer radical polymerization achieved through mechanism-driven photocatalyst design," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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