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Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization

Author

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  • Wei-Wei Fang

    (Hefei University of Technology)

  • Gui-Yu Yang

    (Hefei University of Technology)

  • Zi-Hui Fan

    (Hefei University of Technology)

  • Zi-Chao Chen

    (Hefei University of Technology)

  • Xun-Liang Hu

    (Huazhong University of Science and Technology)

  • Zhen Zhan

    (Huazhong University of Science and Technology)

  • Irshad Hussain

    (Lahore University of Management Sciences (LUMS), Lahore Cantt)

  • Yang Lu

    (Hefei University of Technology)

  • Tao He

    (Hefei University of Technology)

  • Bi-En Tan

    (Huazhong University of Science and Technology)

Abstract

The use of light to regulate photocatalyzed reversible deactivation radical polymerization (RDRP) under mild conditions, especially driven by broadband light or sunlight directly, is highly desired. But the development of a suitable photocatalyzed polymerization system for large-scale production of polymers, especially block copolymers, has remained a big challenge. Herein, we report the development of a phosphine-based conjugated hypercrosslinked polymer (PPh3-CHCP) photocatalyst for an efficient large-scale photoinduced copper-catalyzed atom transfer radical polymerization (Cu-ATRP). Monomers including acrylates and methyl acrylates can achieve near-quantitative conversions under a wide range (450–940 nm) of radiations or sunlight directly. The photocatalyst could be easily recycled and reused. The sunlight-driven Cu-ATRP allowed the synthesis of homopolymers at 200 mL from various monomers, and monomer conversions approached 99% in clouds intermittency with good control over polydispersity. In addition, block copolymers at 400 mL scale can also be obtained, which demonstrates its great potential for industrial applications.

Suggested Citation

  • Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38402-y
    DOI: 10.1038/s41467-023-38402-y
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    1. Woojin Jeon & Yonghwan Kwon & Min Sang Kwon, 2024. "Highly efficient dual photoredox/copper catalyzed atom transfer radical polymerization achieved through mechanism-driven photocatalyst design," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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