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Construction of Zn-doped RuO2 nanowires for efficient and stable water oxidation in acidic media

Author

Listed:
  • Dafeng Zhang

    (Henan Polytechnic University)

  • Mengnan Li

    (Henan Polytechnic University)

  • Xue Yong

    (Zhengzhou University
    The University of Sheffield)

  • Haoqiang Song

    (Zhengzhou University)

  • Geoffrey I. N. Waterhouse

    (The University of Auckland)

  • Yunfei Yi

    (Henan Polytechnic University)

  • Bingjie Xue

    (Henan Polytechnic University)

  • Dongliang Zhang

    (Henan Polytechnic University)

  • Baozhong Liu

    (Henan Polytechnic University)

  • Siyu Lu

    (Zhengzhou University)

Abstract

Oxygen evolution reaction catalysts capable of working efficiently in acidic media are highly demanded for the commercialization of proton exchange membrane water electrolysis. Herein, we report a Zn-doped RuO2 nanowire array electrocatalyst with outstanding catalytic performance for the oxygen evolution reaction under acidic conditions. Overpotentials as low as 173, 304, and 373 mV are achieved at 10, 500, and 1000 mA cm−2, respectively, with robust stability reaching to 1000 h at 10 mA cm−2. Experimental and theoretical investigations establish a clear synergistic effect of Zn dopants and oxygen vacancies on regulating the binding configurations of oxygenated adsorbates on the active centers, which then enables an alternative Ru−Zn dual-site oxide path of the reaction. Due to the change of reaction pathways, the energy barrier of rate-determining step is reduced, and the over-oxidation of Ru active sites is alleviated. As a result, the catalytic activity and stability are significantly enhanced.

Suggested Citation

  • Dafeng Zhang & Mengnan Li & Xue Yong & Haoqiang Song & Geoffrey I. N. Waterhouse & Yunfei Yi & Bingjie Xue & Dongliang Zhang & Baozhong Liu & Siyu Lu, 2023. "Construction of Zn-doped RuO2 nanowires for efficient and stable water oxidation in acidic media," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38213-1
    DOI: 10.1038/s41467-023-38213-1
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    References listed on IDEAS

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    Cited by:

    1. Yu Shen & Xiao-Long Zhang & Ming-Rong Qu & Jie Ma & Sheng Zhu & Yu-Lin Min & Min-Rui Gao & Shu-Hong Yu, 2024. "Cr dopant mediates hydroxyl spillover on RuO2 for high-efficiency proton exchange membrane electrolysis," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    2. Lu Li & Gengwei Zhang & Chenhui Zhou & Fan Lv & Yingjun Tan & Ying Han & Heng Luo & Dawei Wang & Youxing Liu & Changshuai Shang & Lingyou Zeng & Qizheng Huang & Ruijin Zeng & Na Ye & Mingchuan Luo & S, 2024. "Lanthanide-regulating Ru-O covalency optimizes acidic oxygen evolution electrocatalysis," Nature Communications, Nature, vol. 15(1), pages 1-9, December.

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