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Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries

Author

Listed:
  • Davood Sabaghi

    (Technische Universität Dresden)

  • Zhiyong Wang

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Preeti Bhauriyal

    (Technische Universität Dresden)

  • Qiongqiong Lu

    (Leibniz Institute for Solid State and Materials Research (IFW))

  • Ahiud Morag

    (Technische Universität Dresden)

  • Daria Mikhailovia

    (Leibniz Institute for Solid State and Materials Research (IFW))

  • Payam Hashemi

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Dongqi Li

    (Technische Universität Dresden)

  • Christof Neumann

    (Friedrich Schiller University Jena)

  • Zhongquan Liao

    (Fraunhofer Institute for Ceramic Technologies and Systems (IKTS))

  • Anna Maria Dominic

    (Technische Universität Dresden)

  • Ali Shaygan Nia

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

  • Renhao Dong

    (Technische Universität Dresden
    Shandong University)

  • Ehrenfried Zschech

    (University of Warsaw)

  • Andrey Turchanin

    (Friedrich Schiller University Jena)

  • Thomas Heine

    (Technische Universität Dresden
    Leipzig Research Branch
    Yonsei University)

  • Minghao Yu

    (Technische Universität Dresden)

  • Xinliang Feng

    (Technische Universität Dresden
    Max Planck Institute of Microstructure Physics)

Abstract

The anion-intercalation chemistries of graphite have the potential to construct batteries with promising energy and power breakthroughs. Here, we report the use of an ultrathin, positively charged two-dimensional poly(pyridinium salt) membrane (C2DP) as the graphite electrode skin to overcome the critical durability problem. Large-area C2DP enables the conformal coating on the graphite electrode, remarkably alleviating the electrolyte. Meanwhile, the dense face-on oriented single crystals with ultrathin thickness and cationic backbones allow C2DP with high anion-transport capability and selectivity. Such desirable anion-transport properties of C2DP prevent the cation/solvent co-intercalation into the graphite electrode and suppress the consequent structure collapse. An impressive PF6−-intercalation durability is demonstrated for the C2DP-covered graphite electrode, with capacity retention of 92.8% after 1000 cycles at 1 C and Coulombic efficiencies of > 99%. The feasibility of constructing artificial ion-regulating electrode skins with precisely customized two-dimensional polymers offers viable means to promote problematic battery chemistries.

Suggested Citation

  • Davood Sabaghi & Zhiyong Wang & Preeti Bhauriyal & Qiongqiong Lu & Ahiud Morag & Daria Mikhailovia & Payam Hashemi & Dongqi Li & Christof Neumann & Zhongquan Liao & Anna Maria Dominic & Ali Shaygan Ni, 2023. "Ultrathin positively charged electrode skin for durable anion-intercalation battery chemistries," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-36384-5
    DOI: 10.1038/s41467-023-36384-5
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