IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-34674-y.html
   My bibliography  Save this article

Fully-exposed Pt-Fe cluster for efficient preferential oxidation of CO towards hydrogen purification

Author

Listed:
  • Zhimin Jia

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Xuetao Qin

    (Peking University)

  • Yunlei Chen

    (University of Chinese Academy of Science
    Chinese Academy of Sciences)

  • Xiangbin Cai

    (Hong Kong University of Science and Technology)

  • Zirui Gao

    (Peking University)

  • Mi Peng

    (Peking University)

  • Fei Huang

    (Chinese Academy of Sciences)

  • Dequan Xiao

    (University of New Haven)

  • Xiaodong Wen

    (University of Chinese Academy of Science
    Chinese Academy of Sciences)

  • Ning Wang

    (Hong Kong University of Science and Technology)

  • Zheng Jiang

    (Chinese Academy of Sciences)

  • Wu Zhou

    (University of Chinese Academy of Sciences)

  • Hongyang Liu

    (Chinese Academy of Sciences
    University of Science and Technology of China)

  • Ding Ma

    (Peking University)

Abstract

Hydrogen is increasingly being discussed as clean energy for the goal of net-zero carbon emissions, applied in the proton-exchange-membrane fuel cells (PEMFC). The preferential oxidation of CO (PROX) in hydrogen is a promising solution for hydrogen purification to avoid catalysts from being poisoned by the trace amount of CO in hydrogen-rich fuel gas. Here, we report the fabrication of a novel bimetallic Pt-Fe catalyst with ultralow metal loading, in which fully-exposed Pt clusters bonded with neighbor atomically dispersed Fe atoms on the defective graphene surface. The fully-exposed PtFe cluster catalyst could achieve complete elimination of CO through PROX reaction and almost 100% CO selectivity, while maintaining good stability for a long period. It has the mass-specific activity of 6.19 (molCO)*(gPt)−1*h−1 at room temperature, which surpasses those reported in literatures. The exhaustive experimental results and theoretical calculations reveal that the construction of fully-exposed bimetallic Pt-Fe cluster catalysts with maximized atomic efficiency and abundant interfacial sites could facilitate oxygen activation on unsaturated Fe species and CO adsorption on electron-rich Pt clusters to hence the probability of CO oxidation, leading to excellent reactivity in practical applications.

Suggested Citation

  • Zhimin Jia & Xuetao Qin & Yunlei Chen & Xiangbin Cai & Zirui Gao & Mi Peng & Fei Huang & Dequan Xiao & Xiaodong Wen & Ning Wang & Zheng Jiang & Wu Zhou & Hongyang Liu & Ding Ma, 2022. "Fully-exposed Pt-Fe cluster for efficient preferential oxidation of CO towards hydrogen purification," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34674-y
    DOI: 10.1038/s41467-022-34674-y
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-34674-y
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-34674-y?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Fei Huang & Yuchen Deng & Yunlei Chen & Xiangbin Cai & Mi Peng & Zhimin Jia & Jinglin Xie & Dequan Xiao & Xiaodong Wen & Ning Wang & Zheng Jiang & Hongyang Liu & Ding Ma, 2019. "Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation of acetylene," Nature Communications, Nature, vol. 10(1), pages 1-7, December.
    2. Lina Cao & Wei Liu & Qiquan Luo & Ruoting Yin & Bing Wang & Jonas Weissenrieder & Markus Soldemo & Huan Yan & Yue Lin & Zhihu Sun & Chao Ma & Wenhua Zhang & Si Chen & Hengwei Wang & Qiaoqiao Guan & Ta, 2019. "Atomically dispersed iron hydroxide anchored on Pt for preferential oxidation of CO in H2," Nature, Nature, vol. 565(7741), pages 631-635, January.
    3. Lili Lin & Wu Zhou & Rui Gao & Siyu Yao & Xiao Zhang & Wenqian Xu & Shijian Zheng & Zheng Jiang & Qiaolin Yu & Yong-Wang Li & Chuan Shi & Xiao-Dong Wen & Ding Ma, 2017. "Low-temperature hydrogen production from water and methanol using Pt/α-MoC catalysts," Nature, Nature, vol. 544(7648), pages 80-83, April.
    4. Xi Zhang & Guoqing Cui & Haisong Feng & Lifang Chen & Hui Wang & Bin Wang & Xin Zhang & Lirong Zheng & Song Hong & Min Wei, 2019. "Platinum–copper single atom alloy catalysts with high performance towards glycerol hydrogenolysis," Nature Communications, Nature, vol. 10(1), pages 1-12, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhongzhe Wei & Zijiang Zhao & Chenglong Qiu & Songtao Huang & Zihao Yao & Mingxuan Wang & Yi Chen & Yue Lin & Xing Zhong & Xiaonian Li & Jianguo Wang, 2023. "Tripodal Pd metallenes mediated by Nb2C MXenes for boosting alkynes semihydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhang, Yong & He, Shirong & Jiang, Xiaohui & Xiong, Mu & Ye, Yuntao & Yang, Xi, 2023. "Three-dimensional multi-phase simulation of proton exchange membrane fuel cell performance considering constriction straight channel," Energy, Elsevier, vol. 267(C).
    2. Sethu Sundar Pethaiah & Kishor Kumar Sadasivuni & Arunkumar Jayakumar & Deepalekshmi Ponnamma & Chandra Sekhar Tiwary & Gangadharan Sasikumar, 2020. "Methanol Electrolysis for Hydrogen Production Using Polymer Electrolyte Membrane: A Mini-Review," Energies, MDPI, vol. 13(22), pages 1-17, November.
    3. Li, Wenjia & Hao, Yong, 2017. "Efficient solar power generation combining photovoltaics and mid-/low-temperature methanol thermochemistry," Applied Energy, Elsevier, vol. 202(C), pages 377-385.
    4. Liu-Chun Wang & Li-Chan Chang & Wen-Qi Chen & Yi-Hsin Chien & Po-Ya Chang & Chih-Wen Pao & Yin-Fen Liu & Hwo-Shuenn Sheu & Wen-Pin Su & Chen-Hao Yeh & Chen-Sheng Yeh, 2022. "Atomically dispersed golds on degradable zero-valent copper nanocubes augment oxygen driven Fenton-like reaction for effective orthotopic tumor therapy," Nature Communications, Nature, vol. 13(1), pages 1-17, December.
    5. Zhidong An & Piaoping Yang & Delong Duan & Jiang Li & Tong Wan & Yue Kong & Stavros Caratzoulas & Shuting Xiang & Jiaxing Liu & Lei Huang & Anatoly I. Frenkel & Yuan-Ye Jiang & Ran Long & Zhenxing Li , 2023. "Highly active, ultra-low loading single-atom iron catalysts for catalytic transfer hydrogenation," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    6. Evgeniy Yurevich Titov & Ivan Vasilevich Bodrikov & Anton Igorevich Serov & Yuriy Alekseevich Kurskii & Dmitry Yurievich Titov & Evgenia Ruslanovna Bodrikova, 2022. "Liquid-Phase Non-Thermal Plasma Discharge for Fuel Oil Processing," Energies, MDPI, vol. 15(9), pages 1-9, May.
    7. Konstantinos Kappis & Joan Papavasiliou & George Avgouropoulos, 2021. "Methanol Reforming Processes for Fuel Cell Applications," Energies, MDPI, vol. 14(24), pages 1-30, December.
    8. Zhe An & Zilong Zhang & Zeyu Huang & Hongbo Han & Binbin Song & Jian Zhang & Qi Ping & Yanru Zhu & Hongyan Song & Bin Wang & Lirong Zheng & Jing He, 2022. "Pt1 enhanced C-H activation synergistic with Ptn catalysis for glycerol cascade oxidation to glyceric acid," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    9. Xiaohu Ge & Mingying Dou & Yueqiang Cao & Xi Liu & Qiang Yuwen & Jing Zhang & Gang Qian & Xueqing Gong & Xinggui Zhou & Liwei Chen & Weikang Yuan & Xuezhi Duan, 2022. "Mechanism driven design of trimer Ni1Sb2 site delivering superior hydrogenation selectivity to ethylene," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    10. Wang, Yancheng & Liu, Haiyu & Mei, Deqing & Yu, Shizheng, 2022. "Direct ink writing of 3D SiC scaffold as catalyst support for thermally autonomous methanol steam reforming microreactor," Renewable Energy, Elsevier, vol. 187(C), pages 923-932.
    11. Rongkui Su & Hongguo Zhang & Feng Chen & Zhenxing Wang & Lei Huang, 2022. "Applications of Single Atom Catalysts for Environmental Management," IJERPH, MDPI, vol. 19(18), pages 1-6, September.
    12. Jiaqi Zhao & Jinjia Liu & Zhenhua Li & Kaiwen Wang & Run Shi & Pu Wang & Qing Wang & Geoffrey I. N. Waterhouse & Xiaodong Wen & Tierui Zhang, 2023. "Ruthenium-cobalt single atom alloy for CO photo-hydrogenation to liquid fuels at ambient pressures," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    13. Hao Tan & Bing Tang & Ying Lu & Qianqian Ji & Liyang Lv & Hengli Duan & Na Li & Yao Wang & Sihua Feng & Zhi Li & Chao Wang & Fengchun Hu & Zhihu Sun & Wensheng Yan, 2022. "Engineering a local acid-like environment in alkaline medium for efficient hydrogen evolution reaction," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    14. Xin, Yanbin & Sun, Bing & Zhu, Xiaomei & Yan, Zhiyu & Zhao, Xiaotong & Sun, Xiaohang, 2017. "Hydrogen production from ethanol decomposition by pulsed discharge with needle-net configurations," Applied Energy, Elsevier, vol. 206(C), pages 126-133.
    15. Hao Meng & Yusen Yang & Tianyao Shen & Wei Liu & Lei Wang & Pan Yin & Zhen Ren & Yiming Niu & Bingsen Zhang & Lirong Zheng & Hong Yan & Jian Zhang & Feng-Shou Xiao & Min Wei & Xue Duan, 2023. "A strong bimetal-support interaction in ethanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-13, December.
    16. Jun Qi & Yadong Du & Qi Yang & Na Jiang & Jiachun Li & Yi Ma & Yangjun Ma & Xin Zhao & Jieshan Qiu, 2023. "Energy-saving and product-oriented hydrogen peroxide electrosynthesis enabled by electrochemistry pairing and product engineering," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    17. Hao Meng & Yusen Yang & Tianyao Shen & Zhiming Yin & Lei Wang & Wei Liu & Pan Yin & Zhen Ren & Lirong Zheng & Jian Zhang & Feng-Shou Xiao & Min Wei, 2023. "Designing Cu0−Cu+ dual sites for improved C−H bond fracture towards methanol steam reforming," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    18. Xin, Yanbin & Sun, Bing & Liu, Jingyu & Wang, Quanli & Zhu, Xiaomei & Yan, Zhiyu, 2021. "Effects of electrode configurations, solution pH, TiO2 addition on hydrogen production by in-liquid discharge plasma," Renewable Energy, Elsevier, vol. 171(C), pages 728-734.
    19. Jing-Wen Hsueh & Lai-Hsiang Kuo & Po-Han Chen & Wan-Hsin Chen & Chi-Yao Chuang & Chia-Nung Kuo & Chin-Shan Lue & Yu-Ling Lai & Bo-Hong Liu & Chia-Hsin Wang & Yao-Jane Hsu & Chun-Liang Lin & Jyh-Pin Ch, 2024. "Investigating the role of undercoordinated Pt sites at the surface of layered PtTe2 for methanol decomposition," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    20. Haifeng Qi & Yurou Li & Zhitong Zhou & Yueqiang Cao & Fei Liu & Weixiang Guan & Leilei Zhang & Xiaoyan Liu & Lin Li & Yang Su & Kathrin Junge & Xuezhi Duan & Matthias Beller & Aiqin Wang & Tao Zhang, 2023. "Synthesis of piperidines and pyridine from furfural over a surface single-atom alloy Ru1CoNP catalyst," Nature Communications, Nature, vol. 14(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-34674-y. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.