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Chemical Weathering Rates of Soils Developed on Eocene Marls and Sandstones in a Mediterranean Catchment (Istria, Croatia)

Author

Listed:
  • Ozren Hasan

    (Croatian Geological Survey, Sachsova 2, 10000 Zagreb, Croatia)

  • Slobodan Miko

    (Croatian Geological Survey, Sachsova 2, 10000 Zagreb, Croatia)

  • Saša Mesić

    (Croatian Geological Survey, Sachsova 2, 10000 Zagreb, Croatia)

  • Zoran Peh

    (Croatian Geological Survey, Sachsova 2, 10000 Zagreb, Croatia)

Abstract

Physical and chemical weathering, together with biological and biochemical processes, form soil from bedrock and strongly influence the chemical composition of natural waters. Erosive processes, primarily through the agents of running water and wind, remove the products of weathering from catchments. The aim was to determine the chemical weathering of minerals because of changes in land-use and natural forestation in two small neighboring catchments of the rivers Argilla and Bazuja. Agricultural land-use practice is very intense in the Argilla catchment, while the Bazuja catchment’s arable land is mostly abandoned, with progressive forestation. Chemical weathering in soils and sediments was evaluated with the aid of bulk chemistry analysis focused on major elements, trace elements, and zirconium. Weathering indices, mass balance, and strain were calculated. The abandonment of arable land and intense forestation in the Bazuja catchment caused increased chemical weathering with the loss of base cations (Ca and Mg) and enrichment of conservative elements (Zr and Ti) in surface horizons. EIC and MTF values are positive (enrichment) in areas with agricultural activities, while forested areas show negative values (loss). A comparison of the oldest and youngest parts of the overbank sediment profiles in the swallow hole zone and stream sediments shows that chemical and mechanical weathering in the Bazuja catchment was similar to present weathering in the Argilla catchment, while agriculture was active in the Bazuja catchment. The integrated knowledge gained in small catchment studies can be broadly applicable to larger systems.

Suggested Citation

  • Ozren Hasan & Slobodan Miko & Saša Mesić & Zoran Peh, 2023. "Chemical Weathering Rates of Soils Developed on Eocene Marls and Sandstones in a Mediterranean Catchment (Istria, Croatia)," Land, MDPI, vol. 12(4), pages 1-18, April.
    • Handle: RePEc:gam:jlands:v:12:y:2023:i:4:p:913-:d:1127061
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    References listed on IDEAS

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    1. Pasquale Borrelli & David A. Robinson & Larissa R. Fleischer & Emanuele Lugato & Cristiano Ballabio & Christine Alewell & Katrin Meusburger & Sirio Modugno & Brigitta Schütt & Vito Ferro & Vincenzo Ba, 2017. "An assessment of the global impact of 21st century land use change on soil erosion," Nature Communications, Nature, vol. 8(1), pages 1-13, December.
    2. Sanja Dugonjić Jovančević & Josip Rubinić & Igor Ružić & Maja Radišić, 2021. "Influence of Carbonate-Flysch Contact and Groundwater Dynamics on the Occurrence of Geohazards in Istria, Croatia," Land, MDPI, vol. 10(5), pages 1-14, April.
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