IDEAS home Printed from https://ideas.repec.org/a/gam/jjopen/v4y2021i4p49-726d670960.html
   My bibliography  Save this article

Structure and Properties of Supercritical Water: Experimental and Theoretical Characterizations

Author

Listed:
  • Norio Yoshida

    (Department of Chemistry, Graduate School of Science, Kyushu University, Fukuoka 819-0052, Japan)

  • Masaru Matsugami

    (Faculty of Liberal Arts, National Institute of Technology (KOSEN), Kumamoto College, Kumamoto 861-1102, Japan)

  • Yuichi Harano

    (Department of Pharmaceutical Sciences, Himeji Dokkyo University, Himeji 670-8521, Japan)

  • Keiko Nishikawa

    (Toyota Physical and Chemical Research Institute, Nagakute 480-1192, Japan)

  • Fumio Hirata

    (Institute for Molecular Science, National Institute of Natural Sciences, Okazaki 444-8585, Japan)

Abstract

Water in the supercritical region of the phase diagram exhibits a markedly different structure and properties from that at ambient conditions, which is useful in controlling chemical reactions. Nonetheless, the experimental, as well as theoretical, characterization of the substance is not easy because the region is next to the critical point. This article reviews the experimental as well as theoretical studies on water in the supercritical region and its properties as a solvent for chemical reactions, as carried out by the authors and based on small-angle X-ray scattering and the statistical mechanics theory of molecular liquids, also known as reference interaction-site model (RISM) theory.

Suggested Citation

  • Norio Yoshida & Masaru Matsugami & Yuichi Harano & Keiko Nishikawa & Fumio Hirata, 2021. "Structure and Properties of Supercritical Water: Experimental and Theoretical Characterizations," J, MDPI, vol. 4(4), pages 1-29, November.
    • Handle: RePEc:gam:jjopen:v:4:y:2021:i:4:p:49-726:d:670960
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2571-8800/4/4/49/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/2571-8800/4/4/49/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Padilla, Ricardo Vasquez & Soo Too, Yen Chean & Benito, Regano & Stein, Wes, 2015. "Exergetic analysis of supercritical CO2 Brayton cycles integrated with solar central receivers," Applied Energy, Elsevier, vol. 148(C), pages 348-365.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Guo, Jiangfeng, 2016. "Design analysis of supercritical carbon dioxide recuperator," Applied Energy, Elsevier, vol. 164(C), pages 21-27.
    2. Sedighi, Mohammadreza & Padilla, Ricardo Vasquez & Alamdari, Pedram & Lake, Maree & Rose, Andrew & Izadgoshasb, Iman & Taylor, Robert A., 2020. "A novel high-temperature (>700 °C), volumetric receiver with a packed bed of transparent and absorbing spheres," Applied Energy, Elsevier, vol. 264(C).
    3. Xiao, Gang & Zheng, Guanghua & Ni, Dong & Li, Qiang & Qiu, Min & Ni, Mingjiang, 2018. "Thermodynamic assessment of solar photon-enhanced thermionic conversion," Applied Energy, Elsevier, vol. 223(C), pages 134-145.
    4. Ma, Ning & Meng, Fugui & Hong, Wenpeng & Li, Haoran & Niu, Xiaojuan, 2023. "Thermodynamic assessment of the dry-cooling supercritical Brayton cycle in a direct-heated solar power tower plant enabled by CO2-propane mixture," Renewable Energy, Elsevier, vol. 203(C), pages 649-663.
    5. Bai, Wengang & Li, Hongzhi & Zhang, Xuwei & Qiao, Yongqiang & Zhang, Chun & Gao, Wei & Yao, Mingyu, 2022. "Thermodynamic analysis of CO2–SF6 mixture working fluid supercritical Brayton cycle used for solar power plants," Energy, Elsevier, vol. 261(PB).
    6. Wang, Kun & He, Ya-Ling & Zhu, Han-Hui, 2017. "Integration between supercritical CO2 Brayton cycles and molten salt solar power towers: A review and a comprehensive comparison of different cycle layouts," Applied Energy, Elsevier, vol. 195(C), pages 819-836.
    7. Cheng, Kunlin & Qin, Jiang & Zhang, Duo & Bao, Wen & Jing, Wuxing, 2022. "Performance evaluation for a combined power generation system of closed-Brayton-cycle and thermoelectric generator with finite cold source at room temperature on hypersonic vehicles," Energy, Elsevier, vol. 254(PC).
    8. Son, Seongmin & Jeong, Yongju & Cho, Seong Kuk & Lee, Jeong Ik, 2020. "Development of supercritical CO2 turbomachinery off-design model using 1D mean-line method and Deep Neural Network," Applied Energy, Elsevier, vol. 263(C).
    9. Liu, Zhan & Zhang, Yilun & Lv, Xinyu & Zhang, Yao & Liu, Junwei & Su, Chuanqi & Liu, Xianglei, 2023. "An electricity supply system by recovering the waste heat of commercial aeroengine," Energy, Elsevier, vol. 283(C).
    10. Crespi, Francesco & Gavagnin, Giacomo & Sánchez, David & Martínez, Gonzalo S., 2017. "Supercritical carbon dioxide cycles for power generation: A review," Applied Energy, Elsevier, vol. 195(C), pages 152-183.
    11. Cheng, Kunlin & Li, Jiahui & Yu, Jianchi & Fu, Chuanjie & Qin, Jiang & Jing, Wuxing, 2023. "Novel thermoelectric generator enhanced supercritical carbon dioxide closed-Brayton-cycle power generation systems: Performance comparison and configuration optimization," Energy, Elsevier, vol. 284(C).
    12. Calderón, Alejandro & Palacios, Anabel & Barreneche, Camila & Segarra, Mercè & Prieto, Cristina & Rodriguez-Sanchez, Alfonso & Fernández, A. Inés, 2018. "High temperature systems using solid particles as TES and HTF material: A review," Applied Energy, Elsevier, vol. 213(C), pages 100-111.
    13. Hanak, Dawid P. & Manovic, Vasilije, 2016. "Calcium looping with supercritical CO2 cycle for decarbonisation of coal-fired power plant," Energy, Elsevier, vol. 102(C), pages 343-353.
    14. Santini, Lorenzo & Accornero, Carlo & Cioncolini, Andrea, 2016. "On the adoption of carbon dioxide thermodynamic cycles for nuclear power conversion: A case study applied to Mochovce 3 Nuclear Power Plant," Applied Energy, Elsevier, vol. 181(C), pages 446-463.
    15. Chintala, Venkateswarlu & Kumar, Suresh & Pandey, Jitendra K., 2018. "A technical review on waste heat recovery from compression ignition engines using organic Rankine cycle," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P1), pages 493-509.
    16. Fallah, M. & Mohammadi, Z. & Mahmoudi, S.M. Seyed, 2022. "Advanced exergy analysis of the combined S–CO2/ORC system," Energy, Elsevier, vol. 241(C).
    17. Padilla, Ricardo Vasquez & Too, Yen Chean Soo & Benito, Regano & McNaughton, Robbie & Stein, Wes, 2016. "Thermodynamic feasibility of alternative supercritical CO2 Brayton cycles integrated with an ejector," Applied Energy, Elsevier, vol. 169(C), pages 49-62.
    18. Olumayegun, Olumide & Wang, Meihong & Kelsall, Greg, 2017. "Thermodynamic analysis and preliminary design of closed Brayton cycle using nitrogen as working fluid and coupled to small modular Sodium-cooled fast reactor (SM-SFR)," Applied Energy, Elsevier, vol. 191(C), pages 436-453.
    19. Wang, Xurong & Dai, Yiping, 2016. "Exergoeconomic analysis of utilizing the transcritical CO2 cycle and the ORC for a recompression supercritical CO2 cycle waste heat recovery: A comparative study," Applied Energy, Elsevier, vol. 170(C), pages 193-207.
    20. Ehsan, M. Monjurul & Guan, Zhiqiang & Gurgenci, Hal & Klimenko, Alexander, 2020. "Feasibility of dry cooling in supercritical CO2 power cycle in concentrated solar power application: Review and a case study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 132(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jjopen:v:4:y:2021:i:4:p:49-726:d:670960. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.