IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i12p4729-d1171743.html
   My bibliography  Save this article

Methane Dry Reforming Catalysts Based on Pr-Doped Ceria–Zirconia Synthesized in Supercritical Propanol

Author

Listed:
  • Marina Arapova

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Ekaterina Smal

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Yuliya Bespalko

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Konstantin Valeev

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Valeria Fedorova

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Amir Hassan

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia
    Novosibirsk State University, 630090 Novosibirsk, Russia)

  • Olga Bulavchenko

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Vladislav Sadykov

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

  • Mikhail Simonov

    (Department of Heterogeneous Catalysis, Federal Research Center, Boreskov Institute of Catalysis, Lavrentiev Ave. 5, 630090 Novosibirsk, Russia)

Abstract

This paper is devoted to the study of active and stable nickel catalysts for methane dry reforming based on Pr-doped ceria–zirconia obtained via the solvothermal continuous method. Studies on the physicochemical and catalytic properties of the 5%Ni/Ce 0.75 Zr 0.25−x Pr x O 2 series have showed that Pr introduction leads to an increase in the amount of highly reactive oxygen in the oxide lattice. Praseodymium-based catalysts showed significantly higher reactant conversions. In addition to the nature of support, the method of nickel introduction was also studied; Ni was added both using impregnation and the one-pot procedure with mixed oxide preparation. The method of Ni addition was shown to have significant effect on the morphology of its particles and Ni-support interaction, and, respectively, on catalytic activity and coking stability. The 5%Ni/Ce 0.75 Zr 0.15 Pr 0.1 O 2 catalyst prepared by one-pot method showed stable operation in the MDR reaction for 30 h at CO 2 and CH 4 conversions of ~40% and an H 2 yield of ~18% (T = 700 °C, τ = 10 ms).

Suggested Citation

  • Marina Arapova & Ekaterina Smal & Yuliya Bespalko & Konstantin Valeev & Valeria Fedorova & Amir Hassan & Olga Bulavchenko & Vladislav Sadykov & Mikhail Simonov, 2023. "Methane Dry Reforming Catalysts Based on Pr-Doped Ceria–Zirconia Synthesized in Supercritical Propanol," Energies, MDPI, vol. 16(12), pages 1-17, June.
    • Handle: RePEc:gam:jeners:v:16:y:2023:i:12:p:4729-:d:1171743
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/12/4729/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/16/12/4729/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Abdulrasheed, Abdulrahman & Jalil, Aishah Abdul & Gambo, Yahya & Ibrahim, Maryam & Hambali, Hambali Umar & Shahul Hamid, Muhamed Yusuf, 2019. "A review on catalyst development for dry reforming of methane to syngas: Recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 175-193.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Freida Ozavize Ayodele & Siti Indati Mustapa & Bamidele Victor Ayodele & Norsyahida Mohammad, 2020. "An Overview of Economic Analysis and Environmental Impacts of Natural Gas Conversion Technologies," Sustainability, MDPI, vol. 12(23), pages 1-18, December.
    2. Chengyang Zhang & Renkun Zhang & Hui Liu & Qinhong Wei & Dandan Gong & Liuye Mo & Hengcong Tao & Sha Cui & Luhui Wang, 2020. "One-Step Synthesis of Highly Dispersed and Stable Ni Nanoparticles Confined by CeO 2 on SiO 2 for Dry Reforming of Methane," Energies, MDPI, vol. 13(22), pages 1-12, November.
    3. Baena-Moreno, Francisco M. & Sebastia-Saez, Daniel & Pastor-Pérez, Laura & Reina, Tomas Ramirez, 2021. "Analysis of the potential for biogas upgrading to syngas via catalytic reforming in the United Kingdom," Renewable and Sustainable Energy Reviews, Elsevier, vol. 144(C).
    4. Mattia Boscherini & Alba Storione & Matteo Minelli & Francesco Miccio & Ferruccio Doghieri, 2023. "New Perspectives on Catalytic Hydrogen Production by the Reforming, Partial Oxidation and Decomposition of Methane and Biogas," Energies, MDPI, vol. 16(17), pages 1-33, September.
    5. Arslan Mazhar & Asif Hussain Khoja & Abul Kalam Azad & Faisal Mushtaq & Salman Raza Naqvi & Sehar Shakir & Muhammad Hassan & Rabia Liaquat & Mustafa Anwar, 2021. "Performance Analysis of TiO 2 -Modified Co/MgAl 2 O 4 Catalyst for Dry Reforming of Methane in a Fixed Bed Reactor for Syngas (H 2 , CO) Production," Energies, MDPI, vol. 14(11), pages 1-20, June.
    6. Li, Ziwei & Lin, Qian & Li, Min & Cao, Jianxin & Liu, Fei & Pan, Hongyan & Wang, Zhigang & Kawi, Sibudjing, 2020. "Recent advances in process and catalyst for CO2 reforming of methane," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    7. Lim, Dongjun & Lee, Boreum & Lee, Hyunjun & Byun, Manhee & Lim, Hankwon, 2022. "Projected cost analysis of hybrid methanol production from tri-reforming of methane integrated with various water electrolysis systems: Technical and economic assessment," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    8. Moura, I.P. & Reis, A.C. & Bresciani, A.E. & Alves, R.M.B., 2021. "Carbon dioxide abatement by integration of methane bi-reforming process with ammonia and urea synthesis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    9. Carminati, Hudson Bolsoni & de Medeiros, José Luiz & Araújo, Ofélia de Queiroz F., 2021. "Sustainable Gas-to-Wire via dry reforming of carbonated natural gas: Ionic-liquid pre-combustion capture and thermodynamic efficiency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    10. Fan, Liyuan & Li, Chao'en & van Biert, Lindert & Zhou, Shou-Han & Tabish, Asif Nadeem & Mokhov, Anatoli & Aravind, Purushothaman Vellayani & Cai, Weiwei, 2022. "Advances on methane reforming in solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 166(C).
    11. Guohong Wang & Shunli Zhang & Zhuo Huang & Xin Cui & Zhengchang Song, 2023. "Study of the Structure and Catalytic Activity of B-Site Doping Perovskite for an Inferior Anthracite Coal Combustion," Energies, MDPI, vol. 16(14), pages 1-17, July.
    12. Taherian, Zahra & Khataee, Alireza & Orooji, Yasin, 2020. "Facile synthesis of yttria-promoted nickel catalysts supported on MgO-MCM-41 for syngas production from greenhouse gases," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    13. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).
    14. Carminati, Hudson Bolsoni & de Medeiros, José Luiz & Moure, Gustavo Torres & Barbosa, Lara Costa & Araújo, Ofélia de Queiroz F., 2020. "Low-emission pre-combustion gas-to-wire via ionic-liquid [Bmim][NTf2] absorption with high-pressure stripping," Renewable and Sustainable Energy Reviews, Elsevier, vol. 131(C).
    15. Shuo Liu & Chaochao Dun & Qike Jiang & Zhengxi Xuan & Feipeng Yang & Jinghua Guo & Jeffrey J. Urban & Mark T. Swihart, 2024. "Challenging thermodynamics: combining immiscible elements in a single-phase nano-ceramic," Nature Communications, Nature, vol. 15(1), pages 1-11, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:12:p:4729-:d:1171743. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.