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Hydrogenation of CO 2 or CO 2 Derivatives to Methanol under Molecular Catalysis: A Review

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  • Wenxuan Xue

    (Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China)

  • Conghui Tang

    (Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, 1037 Luoyu Road, Wuhan 430074, China
    State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Beijing 100191, China)

Abstract

The atmospheric CO 2 concentration has been continuously increasing due to fossil fuel combustion. The transformations of CO 2 and CO 2 derivatives into high value-added chemicals such as alcohols are ideal routes to mitigate greenhouse gas emissions. Among alcohol products, methanol is very promising as it fulfills the carbon neutral cycle and can be used for direct methanol fuel cells. Herein, we summarize the recent progress in the hydrogenation of CO 2 or CO 2 derivatives to methanol, and focus on those systems with homogeneous catalysts and molecular hydrogen as the reductant. Discussions on the catalytic systems, efficiencies, and future outlooks will be given.

Suggested Citation

  • Wenxuan Xue & Conghui Tang, 2022. "Hydrogenation of CO 2 or CO 2 Derivatives to Methanol under Molecular Catalysis: A Review," Energies, MDPI, vol. 15(6), pages 1-14, March.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:6:p:2011-:d:767737
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    References listed on IDEAS

    as
    1. Ganesh, Ibram, 2014. "Conversion of carbon dioxide into methanol – a potential liquid fuel: Fundamental challenges and opportunities (a review)," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 221-257.
    2. Martin Nielsen & Elisabetta Alberico & Wolfgang Baumann & Hans-Joachim Drexler & Henrik Junge & Serafino Gladiali & Matthias Beller, 2013. "Low-temperature aqueous-phase methanol dehydrogenation to hydrogen and carbon dioxide," Nature, Nature, vol. 495(7439), pages 85-89, March.
    3. R. D. Cortright & R. R. Davda & J. A. Dumesic, 2002. "Hydrogen from catalytic reforming of biomass-derived hydrocarbons in liquid water," Nature, Nature, vol. 418(6901), pages 964-967, August.
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