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Enhanced Performance of LiAl 0.1 Mn 1.9 O 4 Cathode for Li-Ion Battery via TiN Coating

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  • Pinelopi Angelopoulou

    (Department of Materials Science, University of Patras, GR-26504 Rio Patras, Greece
    Foundation for Research and Technology-Hellas (FORTH), Institute of Chemical Engineering Sciences (ICE-HT), P.O. Box 1414, GR-26504 Patras, Greece)

  • Spyros Kassavetis

    (Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece)

  • Joan Papavasiliou

    (Department of Materials Science, University of Patras, GR-26504 Rio Patras, Greece
    Foundation for Research and Technology-Hellas (FORTH), Institute of Chemical Engineering Sciences (ICE-HT), P.O. Box 1414, GR-26504 Patras, Greece)

  • Dimitris Karfaridis

    (Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece)

  • Grzegorz Słowik

    (Faculty of Chemistry, University of Maria Curie-Skłodowska, Pl. M. Curie-Skłodowskiej 2, 20-031 Lublin, Poland)

  • Panos Patsalas

    (Department of Physics, Aristotle University of Thessaloniki, GR-54124 Thessaloniki, Greece)

  • George Avgouropoulos

    (Department of Materials Science, University of Patras, GR-26504 Rio Patras, Greece)

Abstract

The present work addresses the issues related to the capacity fading of spinel LiMn 2 O 4 , such as Mn leaching and Jahn–Teller distortion and suggests an advanced TiN-coated LiAl 0.1 Mn 1.9 O 4 (LAMO) cathode material as an electrode for lithium-ion batteries. TiN coating layers with the same thickness but a different porosity cover the LiAl 0.1 Mn 1.9 O 4 electrode via reactive magnetron sputtering, and present promising electrochemical behavior. In contrast with the pristine LiAl 0.1 Mn 1.9 O 4 , the dense TiN-coated LiAl 0.1 Mn 1.9 O 4 electrode demonstrates a remarkable long-term cycling by reducing the contact area of the electrode/electrolyte interface, resulting in structure stabilization.

Suggested Citation

  • Pinelopi Angelopoulou & Spyros Kassavetis & Joan Papavasiliou & Dimitris Karfaridis & Grzegorz Słowik & Panos Patsalas & George Avgouropoulos, 2021. "Enhanced Performance of LiAl 0.1 Mn 1.9 O 4 Cathode for Li-Ion Battery via TiN Coating," Energies, MDPI, vol. 14(4), pages 1-14, February.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:4:p:825-:d:493429
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    References listed on IDEAS

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    1. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
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    Cited by:

    1. C. M. Costa & S. Lanceros-Mendez, 2021. "Smart and Functional Materials for Lithium-Ion Battery," Energies, MDPI, vol. 14(22), pages 1-3, November.

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