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Boron Monochalcogenides; Stable and Strong Two-Dimensional Wide Band-Gap Semiconductors

Author

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  • Bohayra Mortazavi

    (Institute of Structural Mechanics, Bauhaus-Universität Weimar, Marienstr. 15, D-99423 Weimar, Germany
    Institute for Materials Science and Max Bergman Center of Biomaterials, TU Dresden, 01062 Dresden, Germany)

  • Timon Rabczuk

    (College of Civil Engineering, Department of Geotechnical Engineering, Tongji University, Shanghai 200092, China)

Abstract

In this short communication, we conducted first-principles calculations to explore the stability of boron monochalcogenides (BX, X = S, Se or Te), as a new class of two-dimensional (2D) materials. We predicted BX monolayers with two different atomic stacking sequences of ABBA and ABBC, referred in this work to 2H and 1T, respectively. Analysis of phonon dispersions confirm the dynamical stability of BX nanosheets with both 2H and 1T atomic lattices. Ab initio molecular dynamics simulations reveal the outstanding thermal stability of all predicted monolayers at high temperatures over 1500 K. BX structures were found to exhibit high elastic modulus and tensile strengths. It was found that BS and BTe nanosheets can show high stretchability, comparable to that of graphene. It was found that all predicted monolayers exhibit semiconducting electronic character, in which 2H structures present lower band gaps as compared with 1T lattices. The band-gap values were found to decrease from BS to BTe. According to the HSE06 results, 1T-BS and 2H-BTe show, respectively, the maximum (4.0 eV) and minimum (2.06 eV) electronic band gaps. This investigation introduces boron monochalcogenides as a class of 2D semiconductors with remarkable thermal, dynamical, and mechanical stability.

Suggested Citation

  • Bohayra Mortazavi & Timon Rabczuk, 2018. "Boron Monochalcogenides; Stable and Strong Two-Dimensional Wide Band-Gap Semiconductors," Energies, MDPI, vol. 11(6), pages 1-10, June.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:6:p:1573-:d:152696
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    References listed on IDEAS

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    1. A. K. Geim & I. V. Grigorieva, 2013. "Van der Waals heterostructures," Nature, Nature, vol. 499(7459), pages 419-425, July.
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