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Synthesis and optical properties of electrodeposited crystalline Cu2O in the Vis–NIR range for solar selective absorbers

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  • Alami, Abdul Hai
  • Allagui, Anis
  • Alawadhi, Hussain

Abstract

This paper reports on the thermal oxidation of electrodeposited copper microstructures from a 0.2 M H2SO4 + 0.4 M CuSO4 aqueous solution on a copper substrate for selective solar thermal absorbers applications. A study of the morphological properties and crystalline structure of the deposited/annealed layer through SEM-EDS and powder XRD revealed the formation of self-assembled cubic Cu2O microstructures. The copper oxide layer was optically examined by virtue of a spectrometer in the spectral Vis–NIR range. The surface roughness induced by the existence of the globular microstructure has been seen to enhance the absorptance of the material. Around two to three-fold enhancement of optical surface absorption is achieved in the wavelength range of 400–1000 nm versus an air-grown copper oxide.

Suggested Citation

  • Alami, Abdul Hai & Allagui, Anis & Alawadhi, Hussain, 2015. "Synthesis and optical properties of electrodeposited crystalline Cu2O in the Vis–NIR range for solar selective absorbers," Renewable Energy, Elsevier, vol. 82(C), pages 21-25.
    • Handle: RePEc:eee:renene:v:82:y:2015:i:c:p:21-25
    DOI: 10.1016/j.renene.2014.08.040
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    References listed on IDEAS

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    1. P. Poizot & S. Laruelle & S. Grugeon & L. Dupont & J-M. Tarascon, 2000. "Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries," Nature, Nature, vol. 407(6803), pages 496-499, September.
    2. Alami, Abdul Hai, 2013. "Investigation in utilizing paraboloid concentrators for thermal perforation of metals," Renewable Energy, Elsevier, vol. 56(C), pages 105-109.
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    1. Dan, Atasi & Barshilia, Harish C. & Chattopadhyay, Kamanio & Basu, Bikramjit, 2017. "Solar energy absorption mediated by surface plasma polaritons in spectrally selective dielectric-metal-dielectric coatings: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 79(C), pages 1050-1077.

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