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Deoxygenation of oleic acid over Ce(1–x)Zr(x)O2 catalysts in hydrogen environment

Author

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  • Shim, Jae-Oh
  • Jeong, Dae-Woon
  • Jang, Won-Jun
  • Jeon, Kyung-Won
  • Jeon, Byong-Hun
  • Cho, Seung Yeon
  • Roh, Hyun-Seog
  • Na, Jeong-Geol
  • Ko, Chang Hyun
  • Oh, You-Kwan
  • Han, Sang Sub

Abstract

Ce(1–x)Zr(x)O2 catalysts were prepared by co-precipitation method for deoxygenation (DO) of oleic acid. The CeO2/ZrO2 ratio was systematically varied to optimize Ce(1–x)Zr(x)O2 catalysts. Ce0.6Zr0.4O2 exhibited the highest oleic acid conversion as well as high selectivity to C9 ∼ C17 compounds (diesel fuel range) at the reaction temperature of 300 °C. The high activity/selectivity of Ce0.6Zr0.4O2 catalyst was correlated to its reducibility, oxygen storage capacity and crystallite size.

Suggested Citation

  • Shim, Jae-Oh & Jeong, Dae-Woon & Jang, Won-Jun & Jeon, Kyung-Won & Jeon, Byong-Hun & Cho, Seung Yeon & Roh, Hyun-Seog & Na, Jeong-Geol & Ko, Chang Hyun & Oh, You-Kwan & Han, Sang Sub, 2014. "Deoxygenation of oleic acid over Ce(1–x)Zr(x)O2 catalysts in hydrogen environment," Renewable Energy, Elsevier, vol. 65(C), pages 36-40.
  • Handle: RePEc:eee:renene:v:65:y:2014:i:c:p:36-40
    DOI: 10.1016/j.renene.2013.07.008
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    References listed on IDEAS

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    1. Roh, Hyun-Seog & Eum, Ic-Hwan & Jeong, Dae-Woon, 2012. "Low temperature steam reforming of methane over Ni–Ce(1−x)Zr(x)O2 catalysts under severe conditions," Renewable Energy, Elsevier, vol. 42(C), pages 212-216.
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    1. Jeong, Dae-Woon & Jang, Won-Jun & Shim, Jae-Oh & Han, Won-Bi & Kim, Hak-Min & Lee, Yeol-Lim & Bae, Jong Wook & Roh, Hyun-Seog, 2015. "Optimization of a highly active nano-sized Pt/CeO2 catalyst via Ce(OH)CO3 for the water-gas shift reaction," Renewable Energy, Elsevier, vol. 79(C), pages 78-84.
    2. Jeon, Kyung-Won & Shim, Jae-Oh & Jang, Won-Jun & Lee, Da-We & Na, Hyun-Suk & Kim, Hak-Min & Lee, Yeol-Lim & Yoo, Seong-Yeun & Roh, Hyun-Seog & Jeon, Byong-Hun & Bae, Jong Wook & Ko, Chang Hyun, 2019. "Effect of calcination temperature on the association between free NiO species and catalytic activity of Ni−Ce0.6Zr0.4O2 deoxygenation catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 131(C), pages 144-151.

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